| 1. |
- Sarfraz, Amina, et al.
(författare)
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Catalytic Effect of Silicon Carbide on the Composite Anode of Fuel Cells
- 2021
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Ingår i: ACS Applied Energy Materials. - : AMER CHEMICAL SOC. - 2574-0962. ; 4:7, s. 6436-6444
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Tidskriftsartikel (refereegranskat)abstract
- High efficiency, fuel flexibility, and sustainable energy conversion make fuel cells attractive compared to conventional energy systems. The direct ethanol fuel cells have attracted much attention because of the direct utilization of ethanol fuel. Anode materials are required to enhance the catalytic activity of the liquid fuel, which oxidize the fuel at lower operating temperature. Therefore, the catalytic effect using silicon carbide has been investigated in the LiNiO2-delta anode. The material has been characterized, and it is found that SiC shows a cubic structure and LiNiO2-delta exhibits a hexagonal structure, while the LiNiO2-delta-SiC composite exhibits a mixed cubic and hexagonal phase. Scanning electron microscopy depicts that the material is porous. The Fourier transform infrared spectroscopy analysis shows the presence of Si-O-Si, Si-C, C=O, and Si-OH bonding. The LiNiO2-delta-SiC composite (1:0.3) exhibited a maximum electrical conductivity of 1.34 S cm(-1) at 650 degrees C with an electrical band gap of 0.84 eV. The fabricated cell with the LiNiO2-delta-SiC anode exhibits a power density of 0.20 W cm(-2) at 650 degrees C with liquid ethanol fuel. The results show that there is a promising catalytic activity of SiC in the fuel cell anode.
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| 2. |
- Rafique, Asia, et al.
(författare)
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Design and Modeling of a Fuel Cell System Using Biomass Feedstock as a Biofuel
- 2020
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Ingår i: Fuel Cells. - : Wiley. - 1615-6846 .- 1615-6854. ; 20:1, s. 89-97
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Tidskriftsartikel (refereegranskat)abstract
- This paper aims to model ceramic fuel cell system based on low-temperature planar solid oxide fuel cell (SOFC) different biogases fuels from multiple biomasses, that is, animal waste, redwood, rice husk and sugar cane. Biomass is a better choice for the generation of energy globally. Therefore, there is a focus on the most available biomass resources in the country that can be used as clean energy sources. This developed model is designed by thermodynamic analysis and electrochemical calculations using MATLAB. The designed model is a lumped parameter model based on the steady-state one-dimensional flow. In this model, all calculated power and flow rate values were kept as positive values. Also, the system is considered to be free of leaks, and heat loss is neglected. The operating temperature and pressure are assumed to be 500–700 °C and the partial pressure is set at three different pressures; P1 (1 bar), P2 (2 bar), and P3 (3 bar), respectively, and fuel utilization factor is 80%. It is observed that the best performance is obtained with animal-waste based biogas at 700 °C and P3 (3 bar).
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| 3. |
- Hu, Enyi, et al.
(författare)
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Junction and energy band on novel semiconductor-based fuel cells
- 2021
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Ingår i: iScience. - : Elsevier BV. - 2589-0042. ; 24:3
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Forskningsöversikt (refereegranskat)abstract
- Fuel cells are highly efficient and green power sources. The typical membrane electrode assembly is necessary for common electrochemical devices. Recent research and development in solid oxide fuel cells have opened up many new opportunities based on the semiconductor or its heterostructure materials. Semiconductor-based fuel cells (SBFCs) realize the fuel cell functionality in a much more straightforward way. This work aims to discuss new strategies and scientific principles of SBFCs by reviewing various novel junction types/interfaces, i.e., bulk and planar p-n junction, Schottky junction, and n-i type interface contact. New designing methodologies of SBFCs from energy band/alignment and built-in electric field (BIEF), which block the internal electronic transport while assisting interfacial superionic transport and subsequently enhance device performance, are comprehensively reviewed. This work highlights the recent advances of SBFCs and provides new methodology and understanding with significant importance for both fundamental and applied R&D on new-generation fuel cell materials and technologies.
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| 4. |
- Raza, Rizwan, 1980, et al.
(författare)
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Functional ceria-based nanocomposites for advanced low-temperature (300–600 °C) solid oxide fuel cell: A comprehensive review
- 2020
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Ingår i: Materials Today Energy. - : Elsevier BV. - 2468-6069. ; 15
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Forskningsöversikt (refereegranskat)abstract
- There is world tendency to develop SOFC to lower temperatures and two technical routes and approaches are going in parallel. One is to use thin film technology, focussing on reducing the electrolyte thickness on conventional electrolyte, e.g. YSZ (yttria-stabilized zirconia) and SDC (samaria-doped ceria) to reduce the cell resistance i.e. to lower the operational temperatures. Another technique is to develop new materials, e.g. functional nanocomposites. This paper presents a state-of-the-art of nanocomposite electrolytes-based advanced fuel cell technology, i.e. low-temperature (300–600 °C) ceria-based fuel cells, a new scenario for fuel cell R&D with an overview of important aspects and frontier subjects. A typical nanocomposite has a core–shell type structure in nano-scale, in which ceria forms a core and a salt, e.g. carbonate or another oxide develops a shell layer covering the core. The functionality of nanocomposites is determined by the interfaces between the constituent phases, which can lead to super or fast ions transport (H+ and O2−) at interfaces. Ionic conductivities >0.1 S cm−1 already at ~300 °C have been reported. Five major characteristics of nanocomposites have been identified as important to their properties and applications in fuel cells: i) advanced materials design based on non-structure or interfacial properties/mechanisms; ii) dual or hybrid H+ and O2− conduction; iii) interfacial super-ionic conduction; iv) transition from non-functional to functional materials; v) use of interfacial and surface redox agents and reactions. In the fuel cell context, it is refer to these functional nano-composites as NANOCOFC (Nanocomposites for Advanced Fuel Cells) to distinguish them from the traditional SOFCs and to be oriented to a new fuel cell R&D strategy.
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| 5. |
- Fan, Liangdong, 1985-, et al.
(författare)
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High performance transition metal oxide composite cathode for low temperature solid oxide fuel cells
- 2012
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Ingår i: Journal of Power Sources. - : Elsevier BV. - 0378-7753 .- 1873-2755. ; 203:1, s. 65-71
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Tidskriftsartikel (refereegranskat)abstract
- Low temperature solid oxide fuel cells (SOFCs) with metal oxide composite cathode on the ceria–carbonate composite electrolyte have shown promising performance. However, the role of individual elements or compound is seldom investigated. We report here the effect of the ZnO on the physico-chemical and electrochemical properties of lithiated NiO cathode. The materials and single cells are characterized by X-ray diffraction, scanning electron microscopy, DC polarization electrical conductivity, electrochemical impedance spectroscopy and fuel cell performance. The ZnO modified lithiated NiO composite materials exhibit smaller particle size and lower electrical conductivity than lithiated NiO. However, improved electro-catalytic oxygen reduction activity and power output are achieved after the ZnO modification. A maximum power density of 808 mW cm−2 and the corresponding interfacial polarization resistance of 0.22 Ω cm2 are obtained at 550 °C using ZnO modified cathode and 300 μm thick composite electrolyte. The single cell keeps reasonable stability over 300 min at 500 °C. Thus, ZnO modified lithiated NiO is a promising cathode candidate for low temperature SOFCs.
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| 6. |
- Hussain, Jawad, et al.
(författare)
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Modeling and simulation of planar SOFC to study the electrochemical properties
- 2020
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Ingår i: Current applied physics. - : ELSEVIER. - 1567-1739 .- 1878-1675. ; 20:5, s. 660-672
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Tidskriftsartikel (refereegranskat)abstract
- In this paper, modeling and simulations are carried out using COMSOL Multiphysics. A three-dimensional model is developed for a planar intermediate temperature (IT) solid oxide fuel cell (SOFC). A parametric study has been carried out to analyze the performance of SOFC. Simulations reveal some promising features and enhanced performance of SOFC. It is shown that the maximum value of power (4-3.3) kW/m(2) still remains higher with significant rise of temperature (600 degrees C-1000 degrees C), nearly 0.15 kW/m(2) is the very small loss of power per 100 degrees C rise of temperature. Results have shown that the electrolytic current density is (6700-5500) A/m(2) for peak value of power (4-3.3) kW/m(2) with increase of temperature (600 degrees C-1000 degrees C). For model validation we have plotted a comparison of average current density.
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| 7. |
- Imran, Syed Khalid, et al.
(författare)
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Characterization and Development of Bio-Ethanol Solid Oxide Fuel Cell
- 2011
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Ingår i: Journal of Fuel Cell Science and Technology. - : ASME International. - 1550-624X .- 1551-6989. ; 8:6, s. 061014-
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Tidskriftsartikel (refereegranskat)abstract
- Bio-ethanol based fuel cell is an energy source with a promising future. The low temperature solid oxide fuel cell fed by direct bio-ethanol is receiving considerable attention as a clean and highly efficient for the production of both electricity and high grade waste heat. The comparison of fuel cell performance with different metal-oxide based electrodes was investigated. The power densities of 584 mW cm(-2) and 514 mW cm(-2) at 520 degrees C and 570 degrees C respectively were found. The effect of electrode catalyst function, ethanol concentration on the electrical performance was investigated at different temperature ranged in between 300 degrees C-600 degrees C. The effect of deposited carbon on the electrode was investigated by energy-dispersive X-ray spectroscopy and scanning electron microscope after testing the cell with bio-ethanol.
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| 8. |
- Irshad, Muneeb, et al.
(författare)
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A Brief Description of High Temperature Solid Oxide Fuel Cell's Operation, Materials, Design, Fabrication Technologies and Performance
- 2016
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Ingår i: Applied Sciences. - : MDPI AG. - 2076-3417. ; 6:3
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Forskningsöversikt (refereegranskat)abstract
- Today's world needs highly efficient systems that can fulfill the growing demand for energy. One of the promising solutions is the fuel cell. Solid oxide fuel cell (SOFC) is considered by many developed countries as an alternative solution of energy in near future. A lot of efforts have been made during last decade to make it commercial by reducing its cost and increasing its durability. Different materials, designs and fabrication technologies have been developed and tested to make it more cost effective and stable. This article is focused on the advancements made in the field of high temperature SOFC. High temperature SOFC does not need any precious catalyst for its operation, unlike in other types of fuel cell. Different conventional and innovative materials have been discussed along with properties and effects on the performance of SOFC's components (electrolyte anode, cathode, interconnect and sealing materials). Advancements made in the field of cell and stack design are also explored along with hurdles coming in their fabrication and performance. This article also gives an overview of methods required for the fabrication of different components of SOFC. The flexibility of SOFC in terms fuel has also been discussed. Performance of the SOFC with varying combination of electrolyte, anode, cathode and fuel is also described in this article.
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| 9. |
- Raza, Rizwan, 1980-, et al.
(författare)
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Enhancement of conductivity in ceria-carbonate nanocomposites for LTSOFCs
- 2009
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Ingår i: Journal of nano research. - STAFA-ZUERICH : Trans Tech Publications Inc.. - 1662-5250. ; 6, s. 197-204
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Tidskriftsartikel (refereegranskat)abstract
- This work first explores high resolution transmission electron microscopy (TEM) to determine the interfacial regions and provide experimental evidences for interfaces between the SDC and carbonate constituent phases of the SD-carbonate two-phase composites to further investigate the superionic conduction mechanism in the ceria-carbonate composite systems and enhancement of conductivity. Schober first reported interfacial superionic conduction in ceria-based composites but without direct experimental proofs. Such superionic conduction mechanism remains unknown. Especially, in the nano-scale, this region is trifle to be detected.
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| 10. |
- Raza, Rizwan, et al.
(författare)
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Nanocomposite BaZr0.7Sm0.1Y0.2O3-delta-La0.8Sr0.2Co0.2Fe0.8O3-delta materials for single layer fuel cell
- 2017
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Ingår i: International journal of hydrogen energy. - : PERGAMON-ELSEVIER SCIENCE LTD. - 0360-3199 .- 1879-3487. ; 42:34, s. 22280-22287
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Tidskriftsartikel (refereegranskat)abstract
- Single layer fuel cell (SLFC) is a novel breakthrough in energy conversion technology. This study is to realize the physical-electrochemical co-driving mechanism of a single component device composed of mixed ionic and semiconductor material. This paper is focused on investigating the mechanism and characterization of synthesized nanocomposite BaZr0.7Sm0.1Y0.2O3-delta (BZSY) La0.8Sr0.2Co0.2Fe0.8O3-delta (LSCF) in proportion 1:1 and 3:7 for SLFC. The crystallographic structure and morphology is studied with X-ray diffraction (XRD) and scanning electron microscopy (SEM). The nano-particles lie in the range of 100 210 nm. Ultraviolet (UV) and electrochemical impedance spectroscopy (EIS) is used to analyze the semiconducting nature of nanocomposite (BZSY LSCF). The performance of SLFC was carried out at different temperatures ranging between 400 and 650 degrees C. The mixed conductivity of the synthesized material was about 2.3 S cm(-1). The synergic effect of junction and energy band gap towards charge separation as well as the promotion of ion transport by junction built in field contributes to the working principle and high power output in the SLFC. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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