| 1. |
- Abbas, Ghazanfar, et al.
(författare)
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Electrochemical investigation of mixed metal oxide nanocomposite electrode for low temperature solid oxide fuel cell
- 2017
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Ingår i: International Journal of Modern Physics B. - : WORLD SCIENTIFIC PUBL CO PTE LTD. - 0217-9792. ; 31:27
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Tidskriftsartikel (refereegranskat)abstract
- Zinc-based nanostructured nickel (Ni) free metal oxide electrode material Zn-0.60/CU0.20Mn0.20 oxide (CMZO) was synthesized by solid state reaction and investigated for low temperature solid oxide fuel cell (LTSOFC) applications. The crystal structure and surface morphology of the synthesized electrode material were examined by XRD and SEM techniques respectively. The particle size of ZnO phase estimated by Scherer's equation was 31.50 nm. The maximum electrical conductivity was found to be 12.567 S/cm and 5.846 S/cm in hydrogen and air atmosphere, respectively at 600 degrees C. The activation energy of the CMZO material was also calculated from the DC conductivity data using Arrhenius plots and it was found to be 0.060 and 0.075 eV in hydrogen and air atmosphere, respectively. The CMZO electrode-based fuel cell was tested using carbonated samarium doped ceria composite (NSDC) electrolyte. The three layers 13 mm in diameter and 1 mm thickness of the symmetric fuel cell were fabricated by dry pressing. The maximum power density of 728.86 mW/cm(2) was measured at 550 degrees C.
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| 2. |
- Abbas, Ghazanfar, et al.
(författare)
-
Electrochemical study of nanostructured electrode for low-temperature solid oxide fuel cell (LTSOFC)
- 2014
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Ingår i: International Journal of Energy Research. - : Hindawi Limited. - 0363-907X .- 1099-114X. ; 38:4, s. 518-523
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Tidskriftsartikel (refereegranskat)abstract
- Zn-based nanostructured Ba0.05Cu0.25Fe0.10Zn0.60O (BCFZ) oxide electrode material was synthesized by solid-state reaction for low-temperature solid oxide fuel cell. The cell was fabricated by sandwiching NK-CDC electrolyte between BCFZ electrodes by dry press technique, and its performance was assessed. The maximum power density of 741.87 mW-cm(-2) was achieved at 550 degrees C. The crystal structure and morphology were characterized by X-ray diffractometer (XRD) and SEM. The particle size was calculated to be 25 nm applying Scherer's formula from XRD data. Electronic conductivities were measured with the four-probe DC method under hydrogen and air atmosphere. AC Electrochemical Impedance Spectroscopy of the BCFZ oxide electrode was also measured in hydrogen atmosphere at 450 degrees C.
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| 3. |
- Abbas, Ghazanfar, et al.
(författare)
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Synthesize and characterization of nanocomposite anodes for low temperature solid oxide fuel cell
- 2015
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Ingår i: International journal of hydrogen energy. - : Elsevier BV. - 0360-3199 .- 1879-3487. ; 40:1, s. 891-897
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Tidskriftsartikel (refereegranskat)abstract
- Solid oxide fuel cells have much capability to become an economical alternative energy conversion technology having appropriate materials that can be operated at comparatively low temperature in the range of 400-600 degrees C. The nano-scale engineering has been incorporated to improve the catalytic activity of anode materials for solid oxide fuel cells. Nanostructured Al0.10NixZn0.90-xO oxides were prepared by solid state reaction, which were then mixed with the prepared Gadolinium doped Ceria GDC electrolyte. The crystal structure and surface morphology were characterized by XRD and SEM. The particle size was evaluated by XRD data and found in the range of 20-50 nm, which was then ensured by SEM pictures. The pellets of 13 mm diameter were pressed by dry press technique and electrical conductivities (DC and AC) were determined by four probe techniques and the values have been found to be 10.84 and 4.88 S/cm, respectively at hydrogen atmosphere in the temperature range of 300-600 degrees C. The Electrochemical Impedance Spectroscopy (EIS) analysis exhibits the pure electronic behavior at hydrogen atmosphere. The maximum power density of ANZ-GDC composite anode based solid oxide fuel cell has been achieved 705 mW/cm(2) at 550 degrees C.
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