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Träfflista för sökning "WFRF:(Roldin Pontus) ;pers:(Brune William H.)"

Sökning: WFRF:(Roldin Pontus) > Brune William H.

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1.
  • Ahlberg, Erik, et al. (författare)
  • Effect of salt seed particle surface area, composition and phase on secondary organic aerosol mass yields in oxidation flow reactors
  • 2019
  • Ingår i: Atmospheric Chemistry and Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 19:4, s. 2701-2712
  • Tidskriftsartikel (refereegranskat)abstract
    • Atmospheric particulate water is ubiquitous, affecting particle transport and uptake of gases. Yet, research on the effect of water on secondary organic aerosol (SOA) mass yields is not consistent. In this study, the SOA mass yields of an α-pinene and m-xylene mixture, at a concentration of 60 μgm-3, were examined using an oxidation flow reactor operated at a relative humidity (RH) of 60% and a residence time of 160 s. Wet or dried ammonium sulfate and ammonium nitrate seed particles were used. By varying the amount of seed particle surface area, the underestimation of SOA formation induced by the short residence time in flow reactors was confirmed. Starting at a SOA mass concentration of 5 μgm-3, the maximum yield increased by a factor of 2 with dry seed particles and on average a factor of 3.2 with wet seed particles. Hence, wet particles increased the SOA mass yield by 60% compared to the dry experiment. Maximum yield in the reactor was achieved using a surface area concentration of 1600 μm2 cm-3. This corresponded to a condensational lifetime of 20 s for low-volatility organics. The O V C ratio of SOA on wet ammonium sulfate was significantly higher than when using ammonium nitrate or dry ammonium sulfate seed particles, probably due to differences in heterogeneous chemistry.
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2.
  • Ahlberg, Erik, et al. (författare)
  • No particle mass enhancement from induced atmospheric ageing at a rural site in northern Europe
  • 2019
  • Ingår i: Atmosphere. - : MDPI AG. - 2073-4433. ; 10:7
  • Tidskriftsartikel (refereegranskat)abstract
    • A large portion of atmospheric aerosol particles consists of secondary material produced by oxidation reactions. The relative importance of secondary organic aerosol (SOA) can increase with improved emission regulations. A relatively simple way to study potential particle formation in the atmosphere is by using oxidation flow reactors (OFRs) which simulate atmospheric ageing. Here we report on the first ambient OFR ageing experiment in Europe, coupled with scanning mobility particle sizer (SMPS), aerosol mass spectrometer (AMS) and proton transfer reaction (PTR)-MS measurements. We found that the simulated ageing did not produce any measurable increases in particle mass or number concentrations during the two months of the campaign due to low concentrations of precursors. Losses in the reactor increased with hydroxyl radical (OH) exposure and with increasing difference between ambient and reactor temperatures, indicating fragmentation and evaporation of semivolatile material.
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  • Resultat 1-2 av 2
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refereegranskat (2)
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Eriksson, Axel (2)
Ahlberg, Erik (2)
Roldin, Pontus (2)
Svenningsson, Birgit ... (2)
Ausmeel, Stina (1)
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Kristensson, Adam (1)
Holst, Thomas (1)
Karlsson, Tomas (1)
Frank, Göran (1)
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