| 1. |
- Ryde, Nils, et al.
(författare)
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Lumen Accipe et Imperti - Föreläsning och motivation
- 2011
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Ingår i: Lednings- och kompetensutbildning/CED. - 9789197797467 ; , s. 24-30
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Konferensbidrag (refereegranskat)abstract
- Abstract in Undetermined Vi problematiserar den kritik mot föreläsningsbaserat lärande vid universitet och högskolor, som är vanlig i dagens pedagogiska diskussioner. Vi baserar vårt arbete på enkätundersökningar och på djupintervjuer av studenter på grundutbildningskurser i fysik vid Lunds universitet och Kungliga Tekniska högskolan. Vi anser att den rådande bilden av föreläsningens värde bör nyanseras så att man inte bortser från det unikt positiva hos en bra föreläsning. Man bör därför inte förkasta denna pedgogiska metod, utan, väl förberedd, har föreläsningen en viktig och uppskattad roll i inlärningen.
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| 2. |
- Bengtsson, Ragnar, et al.
(författare)
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Magic gaps and intruder levels in triaxially superdeformed nuclei
- 2004
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Ingår i: European Physical Journal A. Hadrons and Nuclei. - : Springer Science and Business Media LLC. - 1434-6001. ; 22:3, s. 355-362
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Tidskriftsartikel (refereegranskat)abstract
- Nuclear shell model calculations based on a modified harmonic-oscillator potential result in amazingly stable triaxial nuclear shapes. Major gaps in the single-particle energy spectra at proton number 71 and neutron number 94 combine constructively at low and intermediate rotational frequencies. At high frequencies, gaps at proton number 72 and neutron number 97 combine in an equally favourable way. The sizes of the gaps may be as large as 35% of the values for the gaps at the classical magic numbers 50 and 82 at spherical shape. The dependence on the positions of the intruder levels in forming the gaps is discussed. Experimentally observed rotational bands in lutetium (Z = 71) and hafnium (Z = 72) appear in isotopes and frequency ranges, which are consistent with the gaps in the theoretical single-particle energy spectra.
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| 3. |
- Chauvin, Maxime, et al.
(författare)
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Observation of polarized hard X-ray emission from the Crab by the PoGOLite Pathfinder
- 2016
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Ingår i: Monthly notices of the Royal Astronomical Society. - : Oxford University Press. - 0035-8711 .- 1365-2966 .- 1745-3925 .- 1745-3933. ; 456:1, s. L84-L88
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Tidskriftsartikel (refereegranskat)abstract
- We have measured the linear polarization of hard X-ray emission from the Crab in a previously unexplored energy interval, 20-120 keV. The introduction of two new observational parameters, the polarization fraction and angle stands to disentangle geometrical and physical effects, thereby providing information on the pulsar wind geometry and magnetic field environment. Measurements are conducted using the PoGOLite Pathfinder - a balloon-borne polarimeter. Polarization is determined by measuring the azimuthal Compton scattering angle of incident X-rays in an array of plastic scintillators housed in an anticoincidence well. The polarimetric response has been characterized prior to flight using both polarized and unpolarized calibration sources. We address possible systematic effects through observations of a background field. The measured polarization fraction for the integrated Crab light curve is 18.4(-10.6)(+9.8) per cent, corresponding to an upper limit (99 per cent credibility) of 42.4 per cent, for a polarization angle of (149.2 +/- 16.0)degrees.
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| 4. |
- Dong, Geng, et al.
(författare)
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Exploration of H2 binding to the [NiFe]-hydrogenase active site with multiconfigurational density functional theory
- 2018
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Ingår i: Physical Chemistry Chemical Physics. - : Royal Society of Chemistry (RSC). - 1463-9076 .- 1463-9084. ; 20:2, s. 794-801
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Tidskriftsartikel (refereegranskat)abstract
- The combination of density functional theory (DFT) with a multiconfigurational wave function is an efficient way to include dynamical correlation in calculations with multiconfiguration self-consistent field wave functions. These methods can potentially be employed to elucidate reaction mechanisms in bio-inorganic chemistry, where many other methods become either too computationally expensive or too inaccurate. In this paper, a complete active space (CAS) short-range DFT (CAS-srDFT) hybrid was employed to investigate a bio-inorganic system, namely H2 binding to the active site of [NiFe] hydrogenase. This system was previously investigated with coupled-cluster (CC) and multiconfigurational methods in the form of cumulant-approximated second-order perturbation theory, based on the density matrix renormalization group (DMRG). We find that it is more favorable for H2 to bind to Ni than to Fe, in agreement with previous CC and DMRG calculations. The accuracy of CAS-srDFT is comparable to both CC and DMRG, despite much smaller active spaces were employed than in the corresponding DMRG calculations. This enhanced efficiency at the smaller active spaces shows that CAS-srDFT can become a useful method for bio-inorganic chemistry.
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| 5. |
- Hersleth, Hans-Petter, et al.
(författare)
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The crystal structure of peroxymyoglobin generated through cryoradiolytic reduction of myoglobin compound III during data collection
- 2008
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Ingår i: Biochemical Journal. - 0264-6021. ; 412, s. 257-264
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Tidskriftsartikel (refereegranskat)abstract
- Myoglobin has the ability to react with hydrogen peroxide, generating high-valent complexes similar to peroxidases (compounds I and II), and in the presence of excess hydrogen peroxide a third intermediate, compound III, with an oxymyoglobin-type structure is generated from compound II. The compound III is, however, easily one-electron reduced to peroxymyoglobin by synchrotron radiation during crystallograpic data collection. We have generated and solved the 1.30 angstrom (1 angstrom= 0.1 nin) resolution crystal structure of the peroxymyoglobin intermediate, which is isoelectric to compound 0 and has a Fe-O distance of 1.8 angstrom and O-O bond of 1.3 angstrom in accordance with a Fe-II-O-O- (or Fe-III-O-O2-) structure. The generation of the peroxy intermediate through reduction of compound III by X-rays shows the importance of using single-crystal microspectrophotometry when doing crystallography on metal loproteins. After having collected crystallographic data on a peroxy-generated myoglobin crystal, we were able (by a short annealing) to break the O-O bond leading to formation of compound II. These results indicate that the cryoradiolytic-generated peroxymyoglobin is biologically relevant through its conversion into compound II upon heating. Additionally, we have observed that the Xe1 site is occupied by a water molecule, which might be the leaving group in the compound II to compound III reaction.
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| 6. |
- Hersleth, Hans-Petter, et al.
(författare)
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The Influence of X-Rays on the Structural Studies of Peroxide-Derived Myoglobin Intermediates
- 2008
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Ingår i: Chemistry and Biodiversity. - 1612-1872. ; 5:10, s. 2067-2089
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Forskningsöversikt (refereegranskat)abstract
- In recent years, the awareness of potential radiation damage of metal centers in protein crystals during crystallographic data collection has received increasing attention. The radiation damage can lead to radiation-induced changes and reduction of the metal sites. One of the research fields where these concerns have been comprehensively addressed is the study of the reaction intermediates of the heme peroxidase and oxygenase reaction cycles. For both the resting states and the high-valent intermediates, the X-rays used in the structure determination have given undesired side effects through radiation-induced changes to the trapped intermediates. However, X-rays have been used to generate and trap the peroxy/hydroperoxy state in crystals. In this review, the structural work and the influence of X-rays on these intermediates in myoglobin are summarized and viewed in light of analogous studies on similar intermediates in peroxidases and oxygenases.
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| 7. |
- Kiss, Mózsi, et al.
(författare)
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The PoGOLite balloon-borne soft gamma-ray polarimeter
- 2008
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Ingår i: COOL DISCS, HOT FLOWS. - : AIP. ; , s. 225-232
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Konferensbidrag (refereegranskat)abstract
- Linearly polarized radiation in the hard X-ray/soft gamma-ray band is expected from a large variety of astronomical sources. We discuss the importance of polarimetric studies for several classes of sources - pulsars, accreting black holes. magnetic neutron stars and jets from active galaxies - and then describe PoGOLite, a balloon-borne instrument which is currently under construction and will be able to measure the polarization of electromagnetic radiation from such extra-solar objects in the energy range 25-80 keV.
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| 8. |
- Ma, Hai-Liang, et al.
(författare)
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Interpretation of the high spin states in Lu-161: A paired and unpaired study
- 2014
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Ingår i: Physical Review C (Nuclear Physics). - 0556-2813. ; 90:1
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Tidskriftsartikel (refereegranskat)abstract
- A paired cranked Nilsson-Strutinsky-Bogoliubov (CNSB) model is presented, which employs the same method to calculate the liquid-drop energy and moment of inertia as the unpaired cranked Nilsson-Strutinsky (CNS) model. In the CNSB model, the energy minimization is carried out in the mesh of pairing gaps Delta and Fermi levels lambda as well as deformation parameters. The high spin states in Lu-161 are then investigated with the CNSB and CNS models. The terminating structure shows a striking similarity with these two models. Combining the CNSB and CNS models, a complete understanding of high spin structures, including the normal deformed (ND) and triaxial strongly deformed (TSD) bands and observed side bands in Lu-161, is achieved. It appears that the only important paired crossings are the first i(13/2) neutron crossing and the first h(11/2) proton crossing. For the description of the unpaired high spin crossings, it is important to be able to distinguish between the pseudospin partners in the proton N = 4 shell, (d(5/2), g(7/2)) and (d(3/2), s(1/2)). The yrast bands are predicted to terminate, which explains the structure of a TSD-like band X2. A band crossing at I approximate to 36.5 for the TSD band in Lu-161, unique within the chain of even-N Lu isotopes, is well described by the CNSB model.
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| 9. |
- Marsh, J. C., et al.
(författare)
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Identification of triaxial strongly deformed bands in Hf-164
- 2013
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Ingår i: Physical Review C (Nuclear Physics). - 0556-2813. ; 88:4
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Tidskriftsartikel (refereegranskat)abstract
- Two new rotational bands of distinct character have been identified in Hf-164. They are suggested to correspond to the long-anticipated triaxial strongly deformed (TSD) bands predicted by theoretical studies. The bands have been linked to known states, and the level spins and energies could be determined. The bands are also substantially stronger in intensity and are located at lower spins than the previously observed TSD bands in Hf-168, hereby making Hf-164 the best even-even system so far for the study of TSD structures in the A similar to 160 mass region. Cranking calculations based on the modified-oscillator model suggest that the bands are associated with four-quasiparticle configurations that involve high-j intruder (i(13/2))(2) proton orbitals.
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| 10. |
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