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Sökning: WFRF:(Schumann G) > RISE

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1.
  • Böckler, H B, et al. (författare)
  • Metrology infrastructure for high-pressure gas and liquified hydrogen flows. A brief outline of the MetHyInfra project, measurement challenges, and first results
  • 2024
  • Ingår i: Measurement. - : Elsevier B.V.. - 0263-2241 .- 1873-412X. ; 232
  • Tidskriftsartikel (refereegranskat)abstract
    • This paper gives an overview of the ongoing Joint Research Project (JRP) 20IND11 “Metrology infrastructure for high pressure gas and liquefied hydrogen flows” (MetHyInfra), which will ensure traceability in the hydrogen distribution chain. For this purpose, very precise nozzles with well-defined geometries have been produced. In this project, Critical Flow Venturi Nozzles (CFVNs) will be traceably calibrated for the first time with hydrogen and pressures up to 100 MPa using a Coriolis Flow Meter (CFM) as a secondary standard. A CFM has been successfully calibrated with hydrogen against a gravimetric primary standard. Equations of State (EoS) are important for the high-pressure calibration of the nozzles, but also for Computational Fluid Dynamics (CFD) simulations. With regard to CFD, a numerical model has been developed to simulate high pressure hydrogen flow in the CFVN. In a parameter study, non-ideal nozzle shapes are investigated using a shape variation parameter. New Speed of Sound (SoS) measurements were conducted at temperatures from 273 to 323 K and pressures from 1 to 100 MPa. These new data were then used to develop a new EoS for normal hydrogen, optimized for gas phase calculations. In addition to gaseous hydrogen, the project has a strong focus on liquefied hydrogen. Here a three-pronged approach allows traceable measurements. Each of the approaches presented is based on a unique flow calibration principle and relies on independent traceability schemes. The results of the project will ensure traceable measurements and thus a higher level of confidence among end users. © 2024 The Authors
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2.
  • Thiel, V, et al. (författare)
  • Analysis of archaeal core ether lipids using Time of Flight-Secondary Ion Mass Spectrometry (ToF-SIMS): Exploring a new prospect for the study of biomarkers in geobiology
  • 2007
  • Ingår i: Geobiology. - 1472-4677 .- 1472-4669. ; 5:1, s. 75-83
  • Tidskriftsartikel (refereegranskat)abstract
    • The capability of Time of Flight-Secondary Ion Mass Spectrometry (ToF-SIMS) of analysing molecular archaeal biomarkers in geobiological samples was tested and demonstrated. Using a bismuth cluster primary ion source, isopranyl glycerol di- and tetraether core lipids were detected in small amounts of total organic extracts from methanotrophic microbial mats, simultaneously and without further chemical treatment and chromatographic separation. ToF-SIMS was also employed to track the distribution of fossilized ether lipids in a massive carbonate (aragonite) microbialite that precipitated as a result of the microbial anaerobic oxidation of methane. An unambiguous signal was obtained when analysing a freshly broken rock surface (base of a microdrill core). Though some limitation occurred due to μm-topographical effects (sample roughness), it was possible to display the abundance of high molecular weight (C86) of tetraethers exposed in particular regions of the rock surface. 'Molecular mapping' revealed that a part of these molecules was encased within the rock fabric in a cluster-like distribution that might trace the arrangement of the calcifying microbial colonies in the once active mat system. The results reveal promising perspectives of ToF-SIMS for (i) the quasi-nondestructive analysis of lipids in extremely small geobiological samples at low concentrations; (ii) resolving the spatial distribution of these compounds on a μm2- to cm2-scale; and (iii) the more exact assignment of lipid biomarkers to their biological source. © 2006 The Authors.
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Schumann, G (1)
Sjövall, Peter (1)
Schumann, D. (1)
Lausmaa, J (1)
Büker, Oliver (1)
Weiss, S (1)
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Toporski, J (1)
Böckler, H B (1)
de Huu, M. (1)
Maury, R. (1)
Schmelter, S. (1)
Schakel, M. D. (1)
Kutin, J. (1)
Bobovnik, G. (1)
Wedler, C. (1)
Trusler, J. P. M. (1)
Thol, M. (1)
Günz, C. (1)
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