1. |
|
|
2. |
- Blidberg, Andreas, 1987-, et al.
(författare)
-
Identifying the Electrochemical Processes in LiFeSO4F Cathodes for Lithium Ion Batteries
- 2017
-
Ingår i: ChemElectroChem. - : Wiley. - 2196-0216. ; 4:8, s. 1896-1907
-
Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- The electrochemical performance of tavorite LiFeSO4F can be considerably improved by coating the material with a conducting polymer (poly(3,4-ethylenedioxythiophene); PEDOT). Herein, the mechanisms behind the improved performance are studied systematically by careful electrochemical analysis. It is shown that the PEDOT coating improves the surface reaction kinetics for the Li-ion insertion into LiFeSO4F. For such coated materials no kinetic limitations remain, and a transition from solid state to solution-based diffusion control was observed at 0.6 mA cm−2 (circa C/2). Additionally, the quantity of PEDOT is optimized to balance the weight added by the polymer and the improved electrochemical function. Post mortem analysis shows excellent stability for the LiFeSO4F-PEDOT composite, and maintaining the electronic wiring is the most important factor for stable electrochemical cycling of LiFeSO4F. The insights and the methodology used to determine the rate-controlling steps are readily transferable to other ion-insertion-based electrodes, and the findings are important for the development of improved battery electrodes.
|
|
3. |
|
|
4. |
|
|
5. |
|
|