| 1. |
- Hu, Lei, et al.
(författare)
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Molecular surface modification of silver chalcogenolate clusters
- 2022
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Ingår i: Dalton Trans.. - : Royal Society of Chemistry (RSC). ; 51, s. 3241-3247
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Tidskriftsartikel (refereegranskat)abstract
- This study presents a molecular surface modification approach to synthesizing a family of silver chalcogenolate clusters (SCCs) containing the same [Ag12S6] core and different surface-bonded organic ligands (DMAc or pyridines; DMAc = dimethylacetamide), with the aim of tuning the luminescence property and increasing the structural stability of the SCCs. The SCCs displayed strong and tuneable luminescence emissions at 77 K (from green to orange to red) as influenced by the peripheral pyridine ligands. In addition, SCC 5 protected by pyridine molecules was stable in ambient air, humid air and even liquid water for a long time (up to 1 week), and it was more structurally stable than SCC 1 bonded with DMAc molecules under the same conditions. The high structural stability of SCC 5 can be explained by the ability of pyridine molecules to form strong coordination bonds with silver atoms. This study offers a new way of designing structurally stable metal nanoclusters with tuneable physicochemical properties.
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| 2. |
- Wang, Ze-Kun, et al.
(författare)
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Assembly of Discrete Chalcogenolate Clusters into a One-Dimensional Coordination Polymer with Enhanced Photocatalytic Activity and Stability
- 2020
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Ingår i: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 59:4, s. 2121-2126
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Tidskriftsartikel (refereegranskat)abstract
- Interlinking discrete supertetrahedral chalcogenolate clusters with conjugated bipyridine linkers form a one-dimensional coordination polymer, [Cd6Ag4(SPh)16(DMF)(H2O)(bpe)]n (1a), displaying a broader visible-light absorption and a narrower band gap than those of the discrete cluster. More importantly, the coordination polymer demonstrates enhanced activity and stability for the photocatalytic degradation of organic dye in water.
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| 3. |
- Xu, Chao, et al.
(författare)
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A semiconducting microporous framework of Cd6Ag4(SPh)(16) clusters interlinked using rigid and conjugated bipyridines
- 2014
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Ingår i: Chemical Communications. - : Royal Society of Chemistry (RSC). - 1359-7345 .- 1364-548X. ; 50:28, s. 3710-3712
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Tidskriftsartikel (refereegranskat)abstract
- Ternary supertetrahedral chalcogenolate clusters were interlinked with bipyridines into a microporous semiconducting framework with properties qualitatively different from those of the original clusters. Both the framework and the clusters were effective photocatalysts, and rapidly degraded the dye rhodamine B.
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| 4. |
- Xu, Chao, et al.
(författare)
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Interlinking supertetrahedral chalcogenolate clusters with bipyridines to form two-dimensional coordination polymers for photocatalytic degradation of organic dye
- 2019
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Ingår i: Dalton Transactions. - 1477-9226 .- 1477-9234. ; 48:17, s. 5505-5510
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Tidskriftsartikel (refereegranskat)abstract
- Chalcogenolate clusters Cd6Ag4(EPh)16(DMF)3(CH3OH) (E = S, Se) with supertetrahedral structures are isolated. Further interlinking the clusters with organic linker 4,4′-trimethylenedipiperidine in the stepwise assembly approach forms two-dimensional coordination polymers. The clusters and the coordination polymers show tunable band gaps and efficient photocatalytic activities for the degradation of aqueous dye solution. This study demonstrates the great potential of using chalcogenolate clusters and their coordination polymers in photocatalysis applications.
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| 5. |
- Xu, Chao, et al.
(författare)
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Stepwise assembly of a semiconducting coordination polymer [Cd8S(SPh)(14)(DMF)(bpy)](n) and its photodegradation of organic dyes
- 2015
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Ingår i: Dalton Transactions. - : Royal Society of Chemistry (RSC). - 1477-9226 .- 1477-9234. ; 44:14, s. 6400-6405
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Tidskriftsartikel (refereegranskat)abstract
- Chalcogenolate clusters can be interlinked with organic linkers into semiconducting coordination polymers with photocatalytic properties. Here, discrete clusters of Cd8S(SPh)(14)(DMF)(3) were interlinked with 4,4'-bipyridine into a one dimensional coordination polymer of [Cd8S(SPh)(14)(DMF)(bpy)](n) with helical chains. A stepwise mechanism for the assembly of the coordination polymer in DMF was revealed by an ex situ dynamic light scattering study. The cluster was electrostatically neutral and showed a penta-supertetrahedral structure. During the assembly each cluster was interlinked with two 4,4'-bipyridine molecules, which replaced the two terminal DMF molecules of the clusters. In their solid-state forms, the cluster and the coordination polymer were semiconductors with wide band gaps of 3.08 and 2.80 ev. They photocatalytically degraded rhodamine B and methylene blue in aqueous solutions. The moderate conditions used for the synthesis could allow for further in situ studies of the reaction-assembly of related clusters and coordination polymers.
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