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- Wang, Xiaohong, et al.
(författare)
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Effects of tungsten and aluminum additions on the formation of molybdenum disilicide by mechanically-induced self-propagating reaction
- 2010
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Ingår i: Journal of Alloys and Compounds. - : Elsevier BV. - 0925-8388 .- 1873-4669. ; 490:1, s. 388-392
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Tidskriftsartikel (refereegranskat)abstract
- The effects of tungsten and aluminum additions to Mo–Si system on the formation of MoSi2 by mechanically-induced self-propagating reaction in a high-energy ball mill were investigated by X-ray diffraction. The incubation time for mechanically-induced self-propagating reaction to form MoSi2 was 90 min in Mo–Si system. With the addition of tungsten to Mo–Si system, the incubation time of mechanically-induced self-propagating reaction of (Wx,Mo1−x)Si2 system was prolonged. It was due to the decrease of adiabatic temperature with increase in x, and the mechanically-induced self-propagating reaction was not observed until 150 min of high-energy milling in (Wx,Mo1−x)Si2 powder sample with x equals to 0.4. Conversely, the minor aluminum (y < 0.2 in Mo(Si1−y,Aly)2 system) substituting for silicon had shorten the incubation period and accelerated the reaction. When tungsten and aluminium were added simultaneously to Mo–Si system, the mechanically-induced self-propagating reaction was observed in (W0.1,Mo0.9)(Si0.9,Al0.1)2 sample, but it was not observed in (W0.2,Mo0.8)(Si0.8,Al0.2)2 and (W0.3,Mo0.7)(Si0.7,Al0.3)2 samples.
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| 2. |
- Feng, Peizhong, et al.
(författare)
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Combustion synthesis of (Mo1-xCrx)Si-2 (x=0.00-0.30) alloys in SHS mode
- 2012
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Ingår i: Advanced Powder Technology. - : Elsevier BV. - 0921-8831 .- 1568-5527. ; 23:2, s. 133-138
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Tidskriftsartikel (refereegranskat)abstract
- Combustion synthesis was adopted to successfully synthesize molybdenum-silicon-chromium (Mo-Si-Cr) alloys by the mode of self-propagating high-temperature synthesis (SHS). The experimental study of combustion synthesis of Mo-Si-Cr alloys was conducted on elemental powder compacts. Powder compacts with nominal compositions including MoSi2, (Mo0.95Cr0.05)Si-2, (Mo0.90Cr0.10)Si-2, (Mo0.85Cr0.15)Si-2, (Mo0.80Cr0.20)Si-2, (Mo0.75Cr0.25)Si-2 and (Mo0.20Cr0.30)Si-2 were employed in combustion synthesis experiments. The combustion mode, combustion temperature, flame-front propagation velocity and product structure were investigated. The results showed that Mo-Si-Cr alloys were synthesized by an unsteady state combustion mode with a spiral-trajectory reaction front. The peak combustion temperature reduced with the addition of Cr to Mo-Si system. The flame-front propagation velocity decreased with an increase in Cr content of the powder compact. The X-ray diffraction (XRD) results showed that the crystal structure of the combustion product changed from CIIb-type structure (Mo0.90Cr0.10)Si-2 to C40-type structure (Mo0.80Cr0.15)Si-2 with increase in Cr content of Mo-Cr-Si alloys. The intensities of diffraction peaks of the C40-type phase gradually increased with increase in Cr content.
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