| 1. |
- Guo, X. W., et al.
(author)
-
Methylation of 4-methylbiphenyl with methanol over metal oxide-modified HZSM-5 zeolite catalysts
- 2003
-
In: Cuihuà xuébào. - 0253-9837 .- 1872-2067. ; 24:5, s. 333-337
-
Journal article (peer-reviewed)abstract
- A series of HZSM-5 zeolite catalysts modifed with metal oxides (MgO, CaO, SrO, BaO, ZnO, La2O3 and CeO2) were prepared by impregnation method and characterized by XRD, TPD and N-2-adsorption. Methylation of 4-methylbiphenyl (4-MBP) with methanol to 4,4'-dimethylbiphenyl (4,4'-DMBP) was carried out over the prepared catalysts under fixed-bed down-flow conditions. The results showed that the MgO-modified HZSM-5 can significantly improve the selectivity for target product 4,4'-DMBP (up to 80 % vs only 13 % over the parent HZSM-5). The effects of metal oxides on 4,4'-DMBP selectivity are arranged in the following order: MgO>SrOapproximate toZnOapproximate toCaOapproximate toLa(2)O(3)>BaO>CeO2. The effects of MgO contents, precursor-salt types, and loading methods were further investigated, and the results revealed that during 4-MBP conversion, proper MgO loading (5.6 %) can be more effective, and the ion-exchange methed is much better than the impregnation method. However, it is difficult to get higher metal oxide loading by using the ion-exchange method. The high selectivity over HZSM-5 modified with MgO largely results from the depression of 4,4-DMBP second reactions such as isomerization, dealkylation and alkylation, as demonstrated by the reaction of 4,4'-DMBP as reactant over MgO/ZSM-5 catalyst and HZSM-5 zeolite.
|
|
| 2. |
- Wang, S. Y., et al.
(author)
-
High-spin level scheme of Cs-126
- 2004
-
In: Gaoneng wuli yu he wuli. - 0254-3052. ; 28:5, s. 491-494
-
Journal article (peer-reviewed)abstract
- High-spin states of Cs-126 have been populated via the Cd-116(N-14, 4n) Cs-126 reaction. The experiment was performed at Niels Bohr Institute in Denmark in 1991. After careful data analysis, most of the previously-known bands have been pushed up to much higher spins and 3 new rotational sequences have been identified. Spin, parity and configuration assignments are tentatively proposed for all of the observed bands.
|
|
