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- Andersson, Lars Mattias, et al.
(författare)
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Bipolar transport observed through extraction currents on organic photovoltaic blend materials
- 2006
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 89, s. 142111-
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Tidskriftsartikel (refereegranskat)abstract
- Both electron and hole mobilities have been simultaneously measured through charge extraction by linearly increasing voltage on polymer heterojunction solar cells with varying stoichiometry of polymer and acceptor. The polymer is a low band gap copolymer of fluorene, thiophene, and electron accepting groups named APFO-Green 5, and the acceptor is [6,6]-phenyl-C61-butyric acid methylester. Results are correlated to field effect transistor measurements on the same material system. A monotonous increase in mobility for both carrier types is observed with increased acceptor loading.
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2. |
- Andersson, Lars Mattias, et al.
(författare)
-
Stoichiometry, mobility, and performance in bulk heterojunction solar cells
- 2007
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 91:7, s. 071108-
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Tidskriftsartikel (refereegranskat)abstract
- Bipolar transport in blends of a copolymer of fluorene, thiophene and electron accepting groups, and the substituted fullerene [6,6]-phenyl-C61-butyric acid methylester have been studied through charge extraction by linearly increasing voltage on solar cells and with field effect transistors. Between 10% and 90% polymer has been used and the results show a clear correlation to solar cell performance. Optimal solar cells comprise 20% polymer and have a power conversion efficiency of 3.5%. The electron mobility is increasing strongly with fullerene content, but is always lower than the hole mobility, thus explaining the low amount of polymer in optimized devices.
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