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- Hou, Qiong, et al.
(författare)
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A triphenylamine-based four-armed molecule for solution-processed organic solar cells with high photo-voltage
- 2013
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Ingår i: JOURNAL OF MATERIALS CHEMISTRY A. - : Royal Society of Chemistry. - 2050-7488 .- 2050-7496. ; 1:16, s. 4937-4940
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Tidskriftsartikel (refereegranskat)abstract
- A new four-armed molecule Th-4(DTPAB) with a triphenylamine-benzothiadiazole-triphenylamine unit as the core and 4-hexylthiophene as arms was synthesized. Solution-processed organic solar cells based on blends of Th-4(DTPAB) and PC71BM demonstrate a power conversion efficiency of 3.18% with a high open circuit voltage of 0.96 V.
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2. |
- Zhen, Hongyu, et al.
(författare)
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Inverted indium-tin-oxide-free cone-shaped polymer solar cells for light trapping
- 2012
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Ingår i: Applied Physics Letters. - : American Institute of Physics (AIP). - 0003-6951 .- 1077-3118. ; 100:21, s. 213901-
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Tidskriftsartikel (refereegranskat)abstract
- Based on the flexibility of polymer film, cone-shaped polymer solar cells (PSCs) are fabricated and studied. Effective light trapping is achieved due to multi-absorption in all 360 degrees directions. Monte Carlo ray tracing is used to simulate the absorption of cone-shaped PSCs with two variables: wavelength and half cone angle. With an inverted indium-tin-oxide-free device structure, a 43% enhanced light utilization without loss of material utilization is realized in the cone-shaped PSCs with a half cone angle of 45 degrees, compared with the planar PSCs.
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3. |
- Zhen, Hongyu, et al.
(författare)
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Solution-processed bulk-heterojunction organic solar cells employing Ir complexes as electron donors
- 2014
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Ingår i: Journal of Materials Chemistry A. - : Royal Society of Chemistry. - 2050-7488 .- 2050-7496. ; 2:31, s. 12390-12396
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Tidskriftsartikel (refereegranskat)abstract
- To explore enhancing photocurrent in organic solar cells (OSCs) via harvesting triplet excitons, two novel bicycloiridium complexes (R-1 and R-2) are designed and synthesized. Conventional bulk-heterojunction triplet OSCs are solution processed using R-1 or R-2 as sole electron donors and phenyl-C-71-butyric acid methyl ester (PC71BM) as the electron acceptor. A decent short circuit current (J(sc)) of 6.5 mA cm(-2) is achieved though the overlap between the absorption spectrum (with similar to 550 nm absorption onset) of R-2 and the solar flux is relatively small. With an open circuit voltage of 0.74 V and a fill factor of 0.42, an encouraging power conversion efficiency of 2.0% is achieved in the OSCs based on R-2 and PC71BM without any processing additives and post-treatments. Our preliminary result demonstrates the possibility of utilizing Ir complexes as sole electron donors in OSCs, which extends available soluble small molecules for OSCs.
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