| 1. |
- Hu, Huiqing, et al.
(författare)
-
Effects of composition on the electrochemical property and cell performance of single layer fuel cell
- 2015
-
Ingår i: Journal of Power Sources. - : Elsevier BV. - 0378-7753 .- 1873-2755. ; 275, s. 476-482
-
Tidskriftsartikel (refereegranskat)abstract
- In this study, the enhanced electrochemical performance of single layer fuel cells (SLFCs) based upon mixed ion and electron conductors is analyzed as a function of composition. We synthesize a series of Ce0.8Sm0.2O2-delta-Li0.3Ni0.6Cu0.07Sr0.03O2-delta (SDC-LNCS) with different weight ratios. The microstructure and morphology of the composite materials are characterized through X-ray diffraction (XRD), transmission electron microscope (TEM), and energy-dispersive X-ray spectrometer (EDS). Stability of the synthesized samples is evaluated by thermal gravity analysis (TGA). The SLFC with 6SDC-4LNCS exhibits a uniform distribution of the two compositions as well as demonstrates the highest power density of 312 mW cm-2 at 550 mu C. The performance is correlated to the balance of the conduction properties (ionic and electronic) of the functional SLFC layer. The results are a critical contribution to further development of this new energy transfer device.
|
|
| 2. |
- Hu, Huiqing, et al.
(författare)
-
Fabrication of electrolyte-free fuel cell with Mg0.4Zn0.6O/Ce0.8Sm0.2O2-delta-Li0.3Ni0.6Cu0.07Sr0.03O2-delta layer
- 2014
-
Ingår i: Journal of Power Sources. - : Elsevier BV. - 0378-7753 .- 1873-2755. ; 248, s. 577-581
-
Tidskriftsartikel (refereegranskat)abstract
- Electrolyte-free fuel cell (EFFC) which holds the similar function with the traditional solid oxide fuel cell (SOFC) but possesses a completely different structure, has draw much attention during these years. Herein, we report a complex of MZSDC LNCS (Mg0.4Zn0.6O/Ce0.8Sm0.2O2-delta-Li0.3Ni0.6Cu0.07Sr0.03O2-delta) for EFFC that demonstrates a high electrochemical power output of about 600 mW cm(-2) at 630 degrees C. The co-doped MZSDC is synthesized by a co-precipitation method. Semiconductor material of LNCS is synthesized by direct solid state reaction. The microstructure and morphology of the composite materials are characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and energy-dispersive Xray spectrometer (EDS). The performance of the cell with a large size (6 x 6 cm(2)) is comparable or even better than that of the conventional solid oxide fuel cells with large sizes. The maximum power output of 9.28 W is obtained from the large-size cell at 600 degrees C. This paper develops a new functional nanocomposite for EFFC which is conducive to its commercial use.
|
|
| 3. |
- Hu, Huiging, et al.
(författare)
-
Time-dependent performance change of single layer fuel cell with Li0.4Mg0.3Zn0.3O/Ce0.8Sm0.2O2-delta composite
- 2014
-
Ingår i: International journal of hydrogen energy. - : Elsevier BV. - 0360-3199 .- 1879-3487. ; 39:20, s. 10718-10723
-
Tidskriftsartikel (refereegranskat)abstract
- A Large-size engineering single layer fuel cell (SLFC) consisting of a nano-structured Li0.4Mg0.3Zn0.3O2-delta/Ce0.8Sm0.2O2-delta (LMZSDC) composite with an active area of 25 cm(2) (6 cm x 6 cm x 0.1 cm) is successfully fabricated. The SLFC is evaluated by testing the cell durability with a time-dependent degradation using an H-2 fuel and an air oxidant at 600 degrees C for over 120 h. A maximum power of 12.8 W (512 mW cm(-2)) is achieved at 600 degrees C. In the initial operation stage around 50 h, the cell's performance decreases from 12.8 to 11.2 W; however, after this point, the performance was consistently stable, and no significant degradation is observed in the current density or the cell performance. The device performed excellently at low temperatures with a delivered power output of more than 250 mW cm(-2) at a temperature as low as 400 degrees C. By curve fitting the X-ray photoelectron spectroscopy (XPS) results, the ratio of Ce3+/(Ce3++Ce4+) before and after the long-time operation is analyzed. The ratio increased from 28.2% to 31.4% in the electrolyte which indicates a reduction occurs in the beginning operation that causes an initial performance loss for the device power output and OCV. Electrochemical impedance analyses indicate that the LMZSDC had a high ionic transport, and the device had quick dynamic processes and, thus, a high fuel cell performance. The LMZSDC is a new type of ionic material that has been successfully applied to SLFCs.
|
|
| 4. |
- Mat, Mahmut D., et al.
(författare)
-
Development of cathodes for methanol and ethanol fuelled low temperature (300-600 degrees C) solid oxide fuel cells
- 2007
-
Ingår i: International journal of hydrogen energy. - : Elsevier BV. - 0360-3199 .- 1879-3487. ; 32:7, s. 796-801
-
Tidskriftsartikel (refereegranskat)abstract
- We have made extensive efforts to develop various compatible cathode materials for the ceria-carbonate composite (CCC) electrolytes to be used in direct alcohol fuelled solid oxide fuel cells (DLFC). The following cathode materials were mainly investigated: (i) BSCF (BaSrCoFeO) perovskite oxide; (ii) LFN (LaFeO-based oxides, e.g. LaFe0.8Ni0.2O3) perovskite oxides; (iii) bi- or tri-phase metal oxides with or without lithiation. A number of copper- and nickel-based anode composites were also developed for methanol and ethanol with maximum catalytic activity. The tri-metal oxide (CuNiOx-ZnO) cathode produced the maximum power density output of 500 mW/cm(-2) at 580 degrees C for DLFC with methanol operation.
|
|
| 5. |
- Qin, Haiying, et al.
(författare)
-
Direct biofuel low-temperature solid oxide fuel cells
- 2011
-
Ingår i: ENERGY & ENVIRONMENTAL SCIENCE. - : Royal Society of Chemistry (RSC). - 1754-5692 .- 1754-5706. ; 4:4, s. 1273-1276
-
Tidskriftsartikel (refereegranskat)abstract
- A low-temperature solid oxide fuel cell system was developed to use bioethanol and glycerol as fuels directly. This system achieved a maximum power density of 215 mW cm(-2) by using glycerol at 580 degrees C and produced a great impact on sustainable energy and the environment.
|
|
| 6. |
- Zhu, Bin, 1956-, et al.
(författare)
-
A new energy conversion technology joining electrochemical and physical principles
- 2012
-
Ingår i: RSC Advances. - 2046-2069. ; 2:12, s. 5066-5070
-
Tidskriftsartikel (refereegranskat)abstract
- We report a new energy conversion technology joining electrochemical and physical principles. This technology can realize the fuel cell function but built on a different scientific principle. The device consists of a single component which is a homogenous mixture of ceria composite with semiconducting materials, e.g. LiNiCuZn-based oxides. The test devices with hydrogen and air operation delivered a power density of 760mWcm(-2) at 550 degrees C. The device has demonstrated a multi-fuel flexibility and direct alcohol and biogas operations have delivered 300-500 mW cm(-2) at the same temperature. Device physics reveal a key principle similar to solar cells realizing the function based on an effective separation of electronic and ionic conductions and phases within the single-component. The component material multi-functionalities: ion and semi-conductions and bi-catalysis to H-2 or alcohol (methanol and ethanol) and air (O-2) enable this device realized as a fuel cell.
|
|
| 7. |
- Zhu, Bin, et al.
(författare)
-
Solid oxide fuel cell (SOFC) using industrial grade mixed rare-earth oxide electrolytes
- 2008
-
Ingår i: International journal of hydrogen energy. - : Elsevier BV. - 0360-3199 .- 1879-3487. ; 33:13, s. 3385-3392
-
Tidskriftsartikel (refereegranskat)abstract
- This work reports on solid oxide fuel cells (SOFCs) based on abundant natural resources of industrial grade mixed rare-earth carbonates and composites. The materials possessed natural compositions and nano-scale particles. The electrolytes made from these materials were able to achieve excellent fuel cell performances, 300-800 mW/cm(2), at low temperatures (LT: 300-600 degrees C). Ionic transport mechanism, two-phase interface functions and composite role in electrolytes as well as resulted advanced fuel cell performances are discussed.
|
|
| 8. |
- Xiao, Kai, et al.
(författare)
-
Photoelectrical characteristics of a C/CNx multiwalled nanotube
- 2007
-
Ingår i: Advanced Functional Materials. - : Wiley. - 1616-301X .- 1616-3028. ; 17:15, s. 2842-2846
-
Tidskriftsartikel (refereegranskat)abstract
- A nanotube diode fabricated from a single C/CNx multiwalled nanotube exhibits a large photocurrent and a large photovoltage under illumination. The current-voltage (I-V) characteristics of the diode indicate a clear rectification effect. By comparing the I-V characteristics of C, CNx, and C/CNx nanotube diodes, we show that the rectifying characteristics of the C/CNx diode arises from the molecular junction formed at the C/CNx interface where the C and CNx segments are chemically bonded. External radiation photochernically generates electrons and holes in the C/CNx nanotube, producing a large photocurrent because of the influence of the strong electric field in the vicinity of the C/CNx junction. These unique photoresponsive characteristics of C/CNx, nanotube junction diodes points to potential applications such as photovoltaic devices and photodiodes.
|
|
