| 1. |
- Anttu, Nicklas, et al.
(författare)
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Absorption of light in InP nanowire arrays
- 2014
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Ingår i: Nano Reseach. - : Springer Science and Business Media LLC. - 1998-0124 .- 1998-0000. ; 7:6, s. 816-823
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Tidskriftsartikel (refereegranskat)abstract
- An understanding of the absorption of light is essential for efficient photovoltaic and photodetection applications with III-V nanowire arrays. Here, we correlate experiments with modeling and verify experimentally the predicted absorption of light in InP nanowire arrays for varying nanowire diameter and length. We find that 2,000 nm long nanowires in a pitch of 400 nm can absorb 94% of the incident light with energy above the band gap and, as a consequence, light which in a simple ray-optics description would be travelling between the nanowires can be efficiently absorbed by the nanowires. Our measurements demonstrate that the absorption for long nanowires is limited by insertion reflection losses when light is coupled from the air top-region into the array. These reflection losses can be reduced by introducing a smaller diameter to the nanowire-part closest to the air top-region. For nanowire arrays with such a nanowire morphology modulation, we find that the absorptance increases monotonously with increasing diameter of the rest of the nanowire.
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| 2. |
- Anttu, Nicklas, et al.
(författare)
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Optical Far-Field Method with Subwavelength Accuracy for the Determination of Nanostructure Dimensions in Large-Area Samples.
- 2013
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Ingår i: Nano Letters. - : American Chemical Society (ACS). - 1530-6992 .- 1530-6984. ; 13:6, s. 2662-2667
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Tidskriftsartikel (refereegranskat)abstract
- The physical, chemical, and biological properties of nanostructures depend strongly on their geometrical dimensions. Here we present a fast, noninvasive, simple-to-perform, purely optical method that is capable of characterizing nanostructure dimensions over large areas with an accuracy comparable to that of scanning electron microscopy. This far-field method is based on the analysis of unique fingerprints in experimentally measured reflectance spectra using full three-dimensional optical modeling. We demonstrate the strength of our method on large-area (millimeter-sized) arrays of vertical InP nanowires, for which we simultaneously determine the diameter and length as well as cross-sample morphological variations thereof. Explicitly, the diameter is determined with an accuracy better than 10 nm and the length with an accuracy better than 30 nm. The method is versatile and robust, and we believe that it will provide a powerful and standardized measurement technique for large-area nanostructure arrays suitable for both research and industrial applications.
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| 3. |
- Anttu, Nicklas, et al.
(författare)
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Reflection measurements to reveal the absorption in nanowire arrays
- 2013
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Ingår i: Optics Letters. - 0146-9592. ; 38:9, s. 1449-1451
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Tidskriftsartikel (refereegranskat)abstract
- The absorption of light is at the core of photovoltaic applications. For many nanostructure-based devices, an assessment of the absorption in the nanostructures is complicated by a thick, opaque substrate that prohibits transmission measurements. Here, we show how a single reflection measurement can be used for approximating the amount of light absorbed in vertical semiconductor nanowire arrays. (C) 2013 Optical Society of America
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| 4. |
- Borgström, Magnus, et al.
(författare)
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Nanowires With Promise for Photovoltaics
- 2011
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Ingår i: IEEE Journal of Selected Topics in Quantum Electronics. - 1077-260X. ; 17:4, s. 1050-1061
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Tidskriftsartikel (refereegranskat)abstract
- Solar energy harvesting for electricity production is regarded as a fully credible future energy source: plentiful and without serious environmental concerns. The breakthrough for solar energy technology implementation has, however, been hampered by two issues: the conversion efficiency of light into electricity and the solar panel production cost. The use of III-V nanowires (NWs) in photovoltaics allows to respond to both these demands. They offer efficient light absorption and significant cost reduction. These low-dimensional structures can be grown epitaxially in dense NW arrays directly on silicon wafers, which are abundant and cheaper than the germanium substrates used for triple-junction solar cells today. For planar structures, lattice matching poses a strong restriction on growth. III-V NWs offer to create highly efficient multijunction devices, since multiple materials can be combined to match the solar spectrum without the need of tightly controlled lattice matching. At the same time, less material is required for NW-based solar cells than for planar-based architecture. This approach has potential to reach more than 50% in efficiency. Here, we describe our work on NW tandem solar cells, aiming toward two junctions absorbing different parts of the solar spectrum, connected in series via a tunnel diode.
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| 5. |
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| 6. |
- Heurlin, Magnus, et al.
(författare)
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Axial InP Nanowire Tandem Junction Grown on a Silicon Substrate
- 2011
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Ingår i: Nano Letters. - : American Chemical Society (ACS). - 1530-6992 .- 1530-6984. ; 11:5, s. 2028-2031
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Tidskriftsartikel (refereegranskat)abstract
- Tandem InP nanowire pn-junctions have been grown on a Si substrate using metal-organic vapor phase epitaxy. In situ HCl etching allowed the different subcomponents to be stacked on top of each other in the axial extension of the nanowires without detrimental radial growth. Electro-optical measurements on a single nanowire tandem pn-junction device show an open-circuit voltage of 1.15 V under illumination close to 1 sun, which is an increase of 67% compared to a single pn-junction device.
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| 7. |
- Heurlin, Magnus, et al.
(författare)
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Synthesis of Doped InP Core-Shell Nanowires Evaluated Using Hall Effect Measurements.
- 2014
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Ingår i: Nano Letters. - : American Chemical Society (ACS). - 1530-6992 .- 1530-6984. ; 14:2, s. 749-753
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Tidskriftsartikel (refereegranskat)abstract
- InP core-shell nanowire pn-junctions doped with Zn and Sn have been investigated in terms of growth morphology and shell carrier concentration. The carrier concentrations were evaluated using spatially resolved Hall effect measurements and show improved homogeneity compared to previous investigations, attributed to the use of Sn as the n-type dopant. Anisotropies in the growth rate of different facets are found for different doping levels that in turn affects the migration of Sn and In on the nanowire surface. A route for increasing the In migration length to obtain a more homogeneous shell thickness is presented.
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| 8. |
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| 9. |
- Jain, Vishal, 1989-, et al.
(författare)
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Large Area Photodetectors at 1.3/1.55 μm Based on InP/InAsP NWs
- 2014
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Konferensbidrag (refereegranskat)abstract
- Optical communication systems benefit a lot from APDs due to their increased photocurrent gain as compared to conventional photodetectors. An avalanche region in a high bandgap material is especially useful to avoid the tunneling leakage currents in smaller bandgap materials needed for absorption at 1.3/1.55 µm wavelengths. Self-assembled III-V semiconductor nanowires have a key advantage owing to the enhanced absorption due to optical resonance effects and the strain relaxation in NWs, thus facilitating monolithic integration of different heterostructures on cheaper substrates. Here, we present electrical and optical results from large ensembles of InP/InAsP NWs, axially grown on p+ InP substrates. The NW base consists of an InP p-n junction acting as the avalanche region followed by an InP/InAsP absorption region, and ending with a top InP n+-segment. The 130nm diameter NW arrays are contacted in a vertical geometry using SiO2 as the insulating layer and ITO as the top contact. The n-doping in the avalanche region is varied to study it’s influence on the avalanche mechanism. Also the bandgap in the absorption region is varied from pure InP to smaller bandgap InAsP by varying the As content. Clear interband signals from different crystal phases of InP/InAsP are observed in photocurrent spectroscopy. Moreover, the photocurrent spectra are consistent with spatially resolved photoluminescence signals. We also report on polarization and angle dependent photocurrent response of the NW array.
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| 10. |
- Jain, Vishal, 1989-, et al.
(författare)
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Large area photodetectors based on InP NWs with InAs/InAsP QWs
- 2014
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Konferensbidrag (refereegranskat)abstract
- Focal plane arrays have a widespread use in infrared imaging, which often rely on cryogenic cooling to curtail the dark current level necessary for a reasonable signal-to-noise ratio. Quantum well (QW) infrared photodetectors are uniform over large areas, but suffer from a severe drawback related to the selection rules for intersubband absorption. An interesting alternative is self-assembled III-V nanowires offering a key advantage owing to the enhanced absorption by optical resonance effects and strain relaxation.We present electrical and optical results from large ensembles of n+-i-n+ InP NWs, axially grown on InP substrates with InAs/InAsP QWs embedded within the i-segment, designed for both interband and intersubband detection. The NWs are contacted in a vertical geometry using 50 nm SiO2 as the insulating layer and ITO as the top contact. We first investigate the crystal quality of the InAsP QWs grown in 180 nm diameter NWs, using PL, CL and TEM. To achieve more abrupt InAs/InAsP QWs, we grow 130 nm diameter NWs and deplete the In present in the Au catalysts. The effect of n-doping on the device performance is studied by fabricating two different NW geometries, with and without an n+-segment grown before the nominal i-segment in the NW. In addition, the position of the QWs within the i-segment is varied to further scrutinize effects related to doping and crystal structure. Finally, we report spectrally resolved photocurrent results from the QWs in the near-infrared region and discuss about the further developments needed for intersubband detection.
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