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- Borseth, T.M., et al.
(författare)
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Identification of oxygen and zinc vacancy optical signals in ZnO
- 2006
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 89:26, s. 262112-262115
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Tidskriftsartikel (refereegranskat)abstract
- Photoluminescence spectroscopy has been used to study single crystalline ZnO samples systematically annealed in inert, Zn-rich and O-rich atmospheres. A striking correlation is observed between the choice of annealing ambient and the position of the deep band emission (DBE) often detected in ZnO. In particular, annealing in O2 results in a DBE at 2.35±0.05 eV, whereas annealing in the presence of metallic Zn results in DBE at 2.53±0.05 eV. The authors attribute the former band to zinc vacancy (VZn) related defects and the latter to oxygen vacancy (VO) related defects. Additional confirmation for the VO and VZn peak identification comes from the observation that the effect is reversible when O- and Zn-rich annealing conditions are switched. After annealing in the presence of ZnO powder, there is no indication for the VZn- or VO-related bands, but the authors observe a low intensity yellow luminescence band peaking at 2.17 eV, probably related to Li, a common impurity in hydrothermally grown ZnO.
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| 2. |
- da Silva, A. Ferreira, et al.
(författare)
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Growth, Electrical and Optical Properties of SnO2:F on ZnO, Si and Porous Si Structures
- 2009
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Ingår i: NANOTECH CONFERENCE & EXPO 2009, VOL 1, TECHNICAL PROCEEDINGS. - : CRC PRESS-TAYLOR & FRANCIS GROUP. - 9781439817827 ; , s. 352-
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Konferensbidrag (refereegranskat)abstract
- In this work we have analyzed the optical absorption of the ZnO and SnO2:F (FTO) films and applied them in porous silicon light-emitting diodes. The absorption and energy gap were calculated by employing the projector augmented wave method [1] within the local density approximation and with a modeled on-site self-interaction-like correction potential within the LDA+U-S/C [2]. Experiment and theory show a good agreement when the optical absorption and optical energy gap are considered. A layer of FTO is deposited by spray pyrolysis on top of porous Si (PSi) or ZnO/(PSi) in order to make the LEDs. The morphology and roughness of the films are analyzed by Atomic Force Microscopy before and after the FTO deposition. The electrical and optical properties are studied by characteristics curves J x V, and electroluminescence intensity versus bias.
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| 4. |
- Klason, T., et al.
(författare)
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A CFD simulation of a 31 MW district heating boiler
- 2005
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Ingår i: Swedish-Finnish Flame Days 2005, International Flame Research Foundation / edited by Åse Myrhinger. - 9171781854 ; , s. 237-251
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)
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| 5. |
- Klason, Torbern, et al.
(författare)
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Investigation of radiative heat transfer in fixed bed biomass furnaces
- 2008
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Ingår i: Fuel. - : Elsevier BV. - 1873-7153 .- 0016-2361. ; 87:10-11, s. 2141-2153
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Tidskriftsartikel (refereegranskat)abstract
- This paper presents an investigation of the radiative heat transfer process in two fixed bed furnaces firing biomass fuels and the performance of several widely used models for calculation of radiative heat transfer in the free-room of fixed bed furnaces. The simple optically thin (OT) model, the spherical harmonic P-1-approximation model, the grey gas model based on finite volume discretization (FGG), and the more accurate but time consuming spectral line weighted-sum-of-grey-gases (SLW) model are investigated. The effective mean grey gas absorption coefficients are calculated using an optimised version of the exponential wide band model (EWBM) based on an optical mean beam length. Fly-ash and char particles are taken into account using Mie scattering. In the investigated updraft small-scale fixed bed furnace radiative transfer carries heat from the bed to the free-room, whereas in the cross-current bed large-scale industry furnace, radiative transfer brings heat from the hot zones in the free-room to the drying zone of the bed. Not all the investigated models can predict these heat transfer trends, and the sensitivity of results to model parameters is fairly different in the two furnaces. In the small-scale furnace, the gas absorption coefficient predicted by using different optical lengths has great impact on the predicted temperature field. In the large-scale furnaces, the predicted temperature field is less sensitive to the optical length. In both furnaces, with the same radiative properties, the low-computational-cost P-1 model predicts a temperature field in the free-room similar to that by the more time consuming SLW model. In general, the radiative heat transfer rates to the fuel bed are not very sensitive to the radiative properties, but they are sensitive to the different radiative heat transfer models. For a realistic prediction of the radiative heat transfer rate to the fuel bed or to the walls, more computationally demanding models such as the FGG or SLW models should be used.
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