| 1. |
- Álvarez Ruiz, Jesús, et al.
(författare)
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Neutral dissociation of superexcited states in carbon monoxide
- 2002
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Ingår i: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 35:13, s. 2975-2983
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Tidskriftsartikel (refereegranskat)abstract
- Neutral photodissociation of CO has been investigated using synchrotron light in the range 19-26 eV by observing dispersed fluorescence from excited neutral C atoms. Follow-up ab initio calculations support the observed neutral carbon excitation functions, which to a large extent are associated with the CO Rydberg - series converging to the CO+ C and D states.
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| 2. |
- Álvarez Ruiz, Jesús, 1975-
(författare)
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Synchrotron radiation induced fluorescence spectroscopy of gas phase molecules
- 2004
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- A new experimental set-up for gas phase fluorescence studies using synchrotron radiation has been designed and constructed to perform simultaneously total and dispersed fluorescence measurements. Neutral photodissociation of CO has been investigated after excitation with 19-26 eV photons. Fluorescence from 3p 3P, 3p 3S and 3p 1D excited states in carbon was recorded and interpreted by ab initio calculations. The population and dissociation of states belonging to the C and D Rydberg series in CO seem to explain the production of the observed triplet states but not the 3p 1D state. Neutral photodissociation of NO is reported in the 17-26 eV energy range. No known molecular states can account for the collected data. New information regarding the precursor states of the observed neutral dissociation is provided by ab initio calculations. Autoionization of superexcited states in molecular nitrogen is evidenced by strong deviations of the Franck-Condon ratio in the fluorescence of the N2+ B state. Ab initio calculations predict the existence of autoionizing-excited states that may account for some of the observed structures in the 20-46 eV energy range. Selective molecular fluorescence from the npó1Óu+ and npð 1Ðu (n=3-7) Rydberg levels to the E,F 1Óg+ state in H2 was recorded and rotationally analyzed. Vibrational levels of the E,F 1Óg+ state (vEF =0,1,3,6-10) are determined. The predissociation of npð 1Ð+ levels is observed in agreement with the literature. Fragmentation of SF6 was investigated after excitation with 25–80 eV photons. Dispersed fluorescence measurements reveal the emission of S, S+, F and F+ excited atoms. These fragments are produced after single, double and triple excitations as well as direct ionizations and shake-ups in SF6. Photoabsorption and fluorescence yield have been measured in SF5CF3 using 10-30eV photons. The photoabsorption spectrum can be explained in terms of its similarities to those of the SF6 and CF4 molecules. The dispersed and un-dispersed fluorescence resemble those of the CF3X family. Several features suggest the migration of an F atom across the S-C bond that fragments the molecule producing excited CF4. Doubly excited states of H2 have been investigated in the range of 26-60 eV by monitoring Balmer á emission. The experimental data show the already known emission correlated with the fragmentation of the Q1 and Q2 states, and new features which could be attributed to dissociative photoionization and higher lying doubly excited states Qn (n>2) of the hydrogen molecule
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| 3. |
- Erman, P., et al.
(författare)
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Non Franck-Condon effects in photoionization of molecular oxygen
- 2000
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Ingår i: Physica scripta. T. - 0281-1847. ; 62:4, s. 294-300
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Tidskriftsartikel (refereegranskat)abstract
- We present a theoretical and experimental analysis of non Franck-Condon effects in photoionization to the b (4)Sigma(g)(-), state of O-2(+). Experimentally, by dispersing the synchrotron radiation induced O-2(+) b (4)Sigma(g)(-) a (IIu)-I-4 fluorescence we derive the b (4)Sigma(g)(-), State vibrational branching ratios in the excitation energy range 21-34 eV. The vibrational branching ratios reveal features in the region 21-28 eV indicating strong non Franck-Condon effects. The experimental results have been analysed by computing ab initio the vibrational population branching ratios using a many-body perturbation method. Additionally the autoionizing neutral states existing in this energy region have been studied. We have computed the energies of the valence states up to an energy of 30 eV their transition moments for excitations from the ground state, and autoionization rates. Our calculations show, that strong non Franck-Condon effects recorded in the branching ratio spectrum (below 25 eV) are actually caused by the narrow 3 sigma(g) --> sigma(u) shape resonance, and its coupling to the 1 pi(u) --> pi(g) channel.
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| 4. |
- García, Emilio Melero, et al.
(författare)
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Neutral dissociation of superexcited states in nitric oxide
- 2003
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Ingår i: Chemical Physics. - 0301-0104 .- 1873-4421. ; 293:1, s. 65-73
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Tidskriftsartikel (refereegranskat)abstract
- Near-infrared dispersed fluorescence measurements of 13 different atomic multiplets of neutral atomic fragments from photon induced neutral dissociation processes in NO are reported. For excitation of the molecules narrow band synchrotron photons of energy 17.2-25.8 eV were used. Neither Rydberg series nor other molecular states in NO known so far can account for the collected data. From ab initio calculations we try to obtain more information regarding the NO precursor states, and the mechanism behind the observed neutral dissociation.
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| 5. |
- Gravestijn, Robert, et al.
(författare)
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Comparison of confinement in resistive-shell reversed-field pinch devices with two different magnetic shell penetration times
- 2004
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Ingår i: Plasma Physics and Controlled Fusion. - : IOP Publishing. - 0741-3335 .- 1361-6587. ; 46:1, s. 11-22
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Tidskriftsartikel (refereegranskat)abstract
- A loop voltage is required to sustain the reversed-field pinch (RFP) equilibrium. The configuration is characterized by redistribution of magnetic helicity but with the condition that the total helicity is maintained constant. The magnetic field shell penetration time, tau(s), has a critical role in the stability and performance of the RFP Confinement in the EXTRAP device has been studied with two values of tau(s), first (EXTRAP-T2) with tau(s), of the order of the typical relaxation cycle timescale and then (EXTRAP-T2R) with tau(s), much longer than the relaxation cycle timescale, but still much shorter than the pulse length. Plasma parameters show significant improvements in confinement in EXTRAP-T2R. The typical loop voltage required to sustain comparable electron poloidal beta values is a factor of 3 lower in the EXTRAP-T2R device. The improvement is attributed to reduced magnetic turbulence.
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| 6. |
- Hawkes, N. C., et al.
(författare)
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Observation of zero current density in the core of JET discharges with lower hybrid heating and current drive
- 2001
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Ingår i: Physical Review Letters. - 0031-9007 .- 1079-7114. ; 8711:11, s. art. no.-115001
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Tidskriftsartikel (refereegranskat)abstract
- Simultaneous current ramping and application of lower hybrid heating and current drive (LHCD) have produced a region with zero current density within measurement errors in the core (r/a less than or equal to 0.2) of JET tokamak optimized shear discharges. The reduction of core current density is consistent with a simple physical explanation and numerical simulations of radial current diffusion including the effects of LHCD. However, the core current density is clamped at zero, indicating the existence of a physical mechanism which prevents it from becoming negative.
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| 7. |
- Hawkes, N. C., et al.
(författare)
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The formation and evolution of extreme shear reversal in JET and its influence on local thermal transport
- 2002
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Ingår i: Plasma Physics and Controlled Fusion. - : IOP Publishing. - 0741-3335 .- 1361-6587. ; 44:7, s. 1105-1125
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Tidskriftsartikel (refereegranskat)abstract
- In JET discharges where lower hybrid heating and current drive (LHCD) is applied early during the current ramp, a region of the plasma with zero current density is formed near the axis. At the boundary of this region the current density is large and B-theta increases rapidly over a small distance. In the central region the safety factor, q, is effectively infinite, but this falls steeply in the boundary region. Outside the boundary region q reaches a minimum, where the magnetic shears equivalent to r/q (dq/dr) becomes zero. The formation of this region of zero current is dependent on both the heating and the current drive effects of the LHCD. When LHCD is switched off the current profile begins to relax towards the resistive peaked current distribution of fully inductive tokamak operation. If LHCD is not used in the current rise then these current profiles are not established. Although the physical mechanism exists to drive the central plasma current below zero, in most cases it appears to be prevented from going negative. At least one MHD mechanism has been identified which could be responsible for this. The presence of the zero central current is closely linked to the periodic relaxation events seen in these discharges. In these discharges, internal transport barriers have been observed with additional heating powers substantially below the values required to obtain barriers in monotonic q profile cases.
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| 8. |
- Hedqvist, Anders, et al.
(författare)
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Contributions of thermal charge exchange excitation to the Rydberg series of Cl16
- 2000
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Ingår i: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 33:3, s. 375-382
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Tidskriftsartikel (refereegranskat)abstract
- Spectra from the Rydberg series 1s-np for the principal quantum numbers n greater than or equal to 8 of Cl16+ are observed on the JET tokamak. Individual lines up to n = 15 are resolved. The line intensity of n = 10 is enhanced, relative to the underlying 1/n(3) scaling, due to charge exchange collisions with neutral deuterium in the ground state. The observations are compared with predictions based on available partial charge exchange cross section data. There is generally good agreement, however, some details of the predicted n-shell distribution are different from those observed in the experiment.
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| 9. |
- Karawajczyk, A., et al.
(författare)
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Neutral fragmentation of superexcited oxygen molecules
- 2000
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - 1050-2947 .- 1094-1622. ; 61:3, s. art. no.-32718
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Tidskriftsartikel (refereegranskat)abstract
- The mechanisms of neutral dissociation of oxygen molecules in the excitation energy range 15-25 eV have been studied in a dispersed fluorescence experiment. By detecting the fluorescence from excited oxygen atoms, we find that neutral superexcited O-2 states below 20 eV dissociate into O(g.s.) + O(3s,3p). At higher excitation energies (h nu = 20-25 eV) the curve-crossing interactions following excitations to members of the Rydberg c (4)Sigma(u)(-) series also yield atoms in Rydberg states (nl,n greater than or equal to 4). The experimental data are analyzed on the ground of many-body perturbation theory, calculations which indicate the structure of the predissociating states converging to the experimentally observed ones.
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| 10. |
- Kivimäki, Antti, et al.
(författare)
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An energy resolved electron-ion coincidence study near the S 2p thresholds of the SF6 molecule
- 2003
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Ingår i: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 36:4, s. 781-791
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Tidskriftsartikel (refereegranskat)abstract
- The fragmentation dynamics of the SF6 molecule following the excitations of S 2p electrons into unoccupied molecular orbitals has been studied using the energy-resolved electron-ion coincidence technique. Fragmentation patterns were found to depend on the particular excitation and on the electronic state of the molecular ion. The spectator resonant Auger decay at the 2p --> 6a(1g) resonance induces changes in the ion distributions as compared to direct photoionization. Furthermore, coincidence spectra related to the same Auger structure display different ion abundances at the 2t(2g) and 4e(g) shape resonances. Differences were also found in the Auger decay spectra. These findings give further support for the previously suggested many-electron character of the 4e(g) shape resonance.
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