| 1. |
- Larsson, Ann-Charlotte, et al.
(författare)
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Targeting by Comparison with Laboratory Experiments the SCR Catalyst Deactivation Process by Potassium and Zinc Salts in a Large-Scale Biomass Combustion Boiler
- 2006
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Ingår i: Energy & Fuels. - : American Chemical Society (ACS). - 0887-0624 .- 1520-5029. ; 20:4, s. 1398-1405
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Tidskriftsartikel (refereegranskat)abstract
- The deactivation of a commercial selective catalytic reduction (SCR) catalyst of type V2O5−WO3/TiO2 has been studied in this work through comparisons of results from a full-scale biomass combustion plant with those from laboratory experiments. In the latter, the catalyst was exposed to KCl, K2SO4, and ZnCl2 by both wet impregnation with diluted salt solutions and deposition of generated submicrometer aerosol particles by means of an electrostatic field. The reactivity of freshly prepared and deactivated catalyst samples was examined in the SCR reaction, for which the influence of the different salts and the method of exposure were explored. Chemical and physical characterizations of the catalyst samples were carried out focusing on surface area, pore volume, pore size, chemical composition, and the penetration profiles of potassium and zinc. Particle-deposition deactivation as well as commercially exposed catalyst samples were shown to impact surface area and catalyst activity similarly and to have penetration profiles with pronounced peaks. Salt impregnation influenced pore sizes and catalyst activity more strongly and showed flat penetration profiles. Deposition of submicrometer-sized particles on the monolithic SCR catalyst has been shown to induce deactivation of the catalyst with characteristics resembling those obtained in a commercial biomass combustion plant; the laboratory process can be used to further assess the deactivation mechanism by biomass combustion.
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| 2. |
- Fhager, Andreas, 1976, et al.
(författare)
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Image Reconstruction in Microwave Tomography Using a Dielectric Debye Model
- 2012
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Ingår i: IEEE Transactions on Biomedical Engineering. - 0018-9294 .- 1558-2531. ; 59:1, s. 156 - 166
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Tidskriftsartikel (refereegranskat)abstract
- In this paper, quantitative dielectric image reconstruction based on broadband microwave measurements is investigated. A time-domain-based algorithm is derived where Debye model parameters are reconstructed in order to take into account the strong dispersive behavior found in biological tissue. The algorithm is tested with experimental and numerical data in order to verify the algorithm and to investigate improvements in the reconstructed image resulting from the improved description of the dielectric properties of the tissue when using broadband data. The comparison is made in relation to the more commonly used conductivity model. For the evaluation, two examples were considered, the first was a lossy saline solution and the second was less lossy tap water. Both liquids are strongly dispersive and used as a background medium in the imaging examples. The results show that the Debye model algorithm is of most importance in the tap water for a bandwidth of more than 1.5 GHz. Also the saline solution exhibits a dispersive behavior but since the losses restrict the useful bandwidth, the Debye model is of less significance even if somewhat larger and stronger artifacts can be seen in the conductivity model reconstructions.
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| 3. |
- Ali, Sharafat, Associate Professor, 1976-, et al.
(författare)
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Composition–structure–property relationships of transparent Ca–Al–Si–O–N oxynitride glasses : The roles of nitrogen and aluminum
- 2023
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Ingår i: Journal of The American Ceramic Society. - : John Wiley & Sons. - 0002-7820 .- 1551-2916. ; 106:3, s. 1748-1765
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Tidskriftsartikel (refereegranskat)abstract
- We explore the formation and composition–structure–property correlations of transparent Ca–Al–Si–O–N glasses, which were prepared by a standard melt-quenching technique using AlN as the nitrogen source and incorporating up to 8 at.% of N. Their measured physical properties of density, molar volume, compactness, refractive index, and hardness—along with the Young, shear, and bulk elastic moduli—depended roughly linearly on the N content. These effects are attributed primarily to the improved glass-network cross-linking from N compared to O, rather than the formation of higher-coordination AlO5 and AlO6 groups, where 27Al magic-angle-spinning nuclear magnetic resonance experimentation revealed that aluminum is predominately present in tetrahedral coordination as AlO4 units. Yet, several physical properties, such as the refractive index along with the bulk, shear, and Young's elastic moduli, increase concomitantly with the Al content of the glass. We discuss the incompletely understood mechanical–property boosting role of Al as observed both herein and in previous reports on oxynitride glasses, moreover suggesting glass-composition domains that are likely to offer optimal mechanical properties.
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| 4. |
- Finnerman, Oskar, et al.
(författare)
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Reactor modeling assessment for urea-SNCR applications
- 2017
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Ingår i: International Journal of Numerical Methods for Heat and Fluid Flow. - : Emerald Group Publishing Limited. - 0961-5539 .- 1758-6585. ; 27:7, s. 1395-1411
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Tidskriftsartikel (refereegranskat)abstract
- Purpose – The work investigates the effects of neglecting, modeling or partly resolving turbulent fluctuations of velocity, temperature and concentrations on the predicted turbulence-chemistry interaction in urea-SNCR systems.Design/methodology/approach – Numerical predictions of the NO conversion efficiency in an industrial urea-SNCR system are compared to experimental data. Reactor models of varying complexity are assessed, ranging from one-dimensional ideal reactor models to state-of-the-art CFD simulations based on the DES approach. The models employ the same reaction mechanism, but differ in the degree to which they resolve the turbulent fluctuations of the gas phase. A methodology for handling of unknown experimental data with regard to providing adequate boundary conditions is also proposed.Findings – One-dimensional reactor models may be useful for a first quick assessment of urea-SNCR system performance. It is critical to account for heat losses, if present, due to the significant sensitivity of the overall process to temperature. The most comprehensive DES setup evaluated is associated with approximately two orders of magnitude higher computational cost than the conventional RANS-based simulations. For studies that require a large number of simulations (e.g. optimizations or handling of incomplete experimental data), the less costly approaches may be favored with a tolerable loss of accuracy.Originality/value – Novel numerical and experimental results are presented to elucidate the role of turbulent fluctuations on the performance of a complex, turbulent, reacting multiphase flow.
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| 5. |
- Rupar, Katarina, et al.
(författare)
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Solid Phase Micro Extraction Fibers, Calibration for Use in Biofilter Applications
- 2006
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Ingår i: Biochemical Engineering Journal. - : Elsevier BV. - 1369-703X. ; 31:2, s. 107-112
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Tidskriftsartikel (refereegranskat)abstract
- The main purpose of this study is to develop a SPME calibration method suitable for use in evaluation of concentrations of hydrophobic substances in environmental samples. The analyte used in the experiments was alpha-pinene, a hydrophobic organic compound commonly found in wood, and therefore found in wood storage facilities, wood processing industries and wood based biofilters. The SPME fibres were calibrated for different concentrations of alpha-pinene at different temperatures and relative humidities. The method was used to evaluate the removal efficiency of a lab-scale biofilter.
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| 6. |
- Jalilzadehazhari, Elaheh, 1985-, et al.
(författare)
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Achieving a trade‐off construction solution using BIM, an optimization algorithm, and a multi‐criteria decision‐making method
- 2019
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Ingår i: Buildings. - Basel, Switzerland : MDPI. - 2075-5309. ; 9:4, s. 1-14
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Tidskriftsartikel (refereegranskat)abstract
- The Energy Performance of Building Directive obligated all European countries to reduce the energy requirements of buildings while simultaneously improving indoor environment quality. Any such improvements not only enhance the health of the occupants and their productivity, but also provide further economic benefits at the national level. Accomplishing this task requires a method that allows building professionals to resolve conflicts between visual and thermal comfort, energy demands, and life‐cycle costs. To overcome these conflicts, this study exploits the incorporation of building information modelling (BIM), the design of experiments as an optimization algorithm, and the analytical hierarchy process (AHP) into a multi‐criteria decision‐ making method. Any such incorporation can (i) create constructive communication between building professionals, such as architects, engineers, and energy experts; (ii) allow the analysis of the performance of multiple construction solutions with respect to visual and thermal comfort, energy demand, and life‐cycle costs; and (iii) help to select a trade‐off solution, thereby making a suitable decision. Three types of energy‐efficient windows, and five types of ground floors, roofs, and external wall constructions were considered as optimization variables. The incorporation of several methods allowed the analysis of the performance of 375 construction solutions based on a combination of optimization variables, and helped to select a trade‐off solution. The results showed the strength of incorporation for analyzing big‐data through the intelligent use of BIM and a simulation in the field of the built environment, energy, and costs. However, when applying AHP, the results are strongly contingent on pairwise comparisons
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| 7. |
- Brandin, Jan, 1958-, et al.
(författare)
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A review of thermo-chemical conversion of biomass into biofuels-focusing on gas cleaning and up-grading process steps
- 2017
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Rapport (övrigt vetenskapligt/konstnärligt)abstract
- It is not easy to replace fossil-based fuels in the transport sector, however, an appealing solution is to use biomass and waste for the production of renewable alternatives. Thermochemical conversion of biomass for production of synthetic transport fuels by the use of gasification is a promising way to meet these goals.One of the key challenges in using gasification systems with biomass and waste as feedstock is the upgrading of the raw gas produced in the gasifier. These materials replacing oil and coal contain large amounts of demanding impurities, such as alkali, inorganic compounds, sulphur and chlorine compounds. Therefore, as for all multi-step processes, the heat management and hence the total efficiency depend on the different clean-up units. Unfortunately, the available conventional gas filtering units for removing particulates and impurities, and also subsequent catalytic conversion steps have lower optimum working temperatures than the operating temperature in the gasification units.This report focuses on on-going research and development to find new technology solutions and on the key critical technology challenges concerning the purification and upgrading of the raw gas to synthesis gas and the subsequent different fuel synthesis processes, such as hot gas filtration, clever heating solutions and a higher degree of process integration as well as catalysts more resistant towards deactivation. This means that the temperature should be as high as possible for any particular upgrading unit in the refining system. Nevertheless, the temperature and pressure of the cleaned synthesis gas must meet the requirements of the downstream application, i.e. Fischer-Tropsch diesel or methanol.Before using the gas produced in the gasifier a number of impurities needs to be removed. These include particles, tars, sulphur and ammonia. Particles are formed in gasification, irrespective of the type of gasifier design used. A first, coarse separation is performed in one or several cyclone filters at high temperature. Thereafter bag-house filters (e.g. ceramic or textile) maybe used to separate the finer particles. A problem is, however, tar condensation in the filters and there is much work performed on trying to achieve filtration at as high a temperature as possible.The far most stressed technical barriers regarding cleaning of the gases are tars. To remove the tar from the product gas there is a number of alternatives, but most important is that the gasifier is operated at optimal conditions for minimising initial tar formation. In fluid bed and entrained flow gasification a first step may be catalytic tar cracking after particle removal. In fluid bed gasification a catalyst, active in tar cracking, may be added to the fluidising bed to further remove any tar formed in the bed. In this kind of tar removal, natural minerals such as dolomite and olivine, are normally used, or catalysts normally used in hydrocarbon reforming or cracking. The tar can be reformed to CO and hydrogen by thermal reforming as well, when the temperature is increased to 1300ºC and the tar decomposes. Another method for removing tar from the gas is to scrub it by using hot oil (200-300ºC). The tar dissolves in the hot oil, which can be partly regenerated and the remaining tar-containing part is either burned or sent back to the gasifier for regasification.Other important aspects are that the sulphur content of the gas depends on the type of biomass used, the gasification agent used etc., but a level at or above 100 ppm is not unusual. Sulphur levels this high are not acceptable if there are catalytic processes down-stream, or if the emissions of e.g. SO2 are to be kept down. The sulphur may be separated by adsorbing it in ZnO, an irreversible process, or a commercially available reversible adsorbent can be used. There is also the possibility of scrubbing the gas with an amine solution. If a reversible alternative is chosen, elementary sulphur may be produced using the Claus process.Furthermore, the levels of ammonia formed in gasification (3,000 ppm is not uncommon) are normally not considered a problem. When combusting the gas, nitrogen or in the worst case NOx (so-called fuel NOx) is formed; there are, however, indications that there could be problems. Especially when the gasification is followed by down-stream catalytic processes, steam reforming in particular, where the catalyst might suffer from deactivation by long-term exposure to ammonia.The composition of the product gas depends very much on the gasification technology, the gasifying agent and the biomass feedstock. Of particular significance is the choice of gasifying agent, i.e. air, oxygen, water, since it has a huge impact on the composition and quality of the gas, The gasifying agent also affects the choice of cleaning and upgrading processes to syngas and its suitability for different end-use applications as fuels or green chemicals.The ideal upgraded syngas consists of H2 and CO at a correct ratio with very low water and CO2 content allowed. This means that the tars, particulates, alkali salts and inorganic compounds mentioned earlier have to be removed for most of the applications. By using oxygen as the gasifying agent, instead of air, the content of nitrogen may be minimised without expensive nitrogen separation.In summary, there are a number of uses with respect to produced synthesis gas. The major applications will be discussed, starting with the production of hydrogen and then followed by the synthesis of synthetic natural gas, methanol, dimethyl ether, Fischer-Tropsch diesel and higher alcohol synthesis, and describing alternatives combining these methods. The SNG and methanol synthesis are equilibrium constrained, while the synthesis of DME (one-step route), FT diesel and alcohols are not. All of the reactions are exothermal (with the exception of steam reforming of methane and tars) and therefore handling the temperature increase in the reactors is essential. In addition, the synthesis of methanol has to be performed at high pressure (50-100 bar) to be industrially viable.There will be a compromise between the capital cost of the whole cleaning unit and the system efficiency, since solid waste, e.g. ash, sorbents, bed material and waste water all involve handling costs. Consequently, installing very effective catalysts, results in unnecessary costs because of expensive gas cleaning; however the synthesis units further down-stream, especially for Fischer-Tropsch diesel, and DME/methanol will profit from an effective gas cleaning which extends the catalysts life-time. The catalyst materials in the upgrading processes essentially need to be more stable and resistant to different kinds of deactivation.Finally, process intensification is an important development throughout chemical industries, which includes simultaneous integration of both synthesis steps and separation, other examples are advanced heat exchangers with heat integration in order to increase the heat transfer rates. Another example is to combine exothermic and endothermic reactions to support reforming reactions by using the intrinsic energy content. For cost-effective solutions and efficient application, new solutions for cleaning and up-grading of the gases are necessary.
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| 8. |
- Brandin, Jan, 1958-
(författare)
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Usage of Biofuels in Sweden
- 2013
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Ingår i: CSR-2 Catalyst for renewable sources. - Novosibrisk, Russia : Boreskov Institute of Catalysis. - 9785990255777 ; , s. 5-7
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Konferensbidrag (refereegranskat)abstract
- In Sweden, biofuels have come into substantial use, in an extent that are claimed to be bigger than use of fossil oil. One driving force for this have been the CO2-tax that was introduced in 1991 (1). According to SVEBIO:s calculations (2) based on the Swedish Energy Agency´s prognosis, the total energy consumption in Sweden 2012 was 404 TWh. If the figure is broken down on the different energy sources (figure 1) one can see that the consumption roughly distribute in three different, equally sized, blocks, Biofuels, fossil fuels and water & nuclear power. The major use of the fossil fuels is for transport and the water & nuclear power is used as electric power. The main use of the biofuels is for heating in the industrial sector and as district heating. In 2009 the consumption from those two segments was 85 TWh, and 10 TWh of bio power was co-produced giving an average biomass to electricity efficiency of 12%. This indicates a substantial conversion potential from hot water production to combined heat and power (CHP) production. in Sweden 2013 broken down on the different energy sources. In 2006 the pulp, paper and sawmill industry accounted for 95% of the bio energy consumption in the industrial sector, and the major biofuel consumed was black liquor (5). However, the pulp and paper industries also produced the black liquor in their own processes. The major energy source (58%) for district heating during 2006 was woody biomass (chips, pellets etc.) followed by waste (24%), peat (6%) and others (12%) (5). The use of peat has probably decreased since 2006 since peat is no longer regarded as a renewable energy source. While the use of biofuel for heating purpose is well developed and the bio-power is expected to grow, the use in the transport sector is small, 9 TWh or 7% in 2011. The main consumption there is due to the mandatory addition (5%) of ethanol to gasoline and FAME to diesel (6). The Swedish authorities have announced plans to increase the renewable content to 7.5 % in 2015 on the way to fulfill the EU’s goal of 10 % renewable transportation fuels in 2020. However the new proposed fuel directive in EU says that a maximum of 5% renewable fuel may be produced from food sources like sugars and vegetable oils. Another bothersome fact is that, in principle, all rape seed oil produced in Sweden is consumed (95-97%) in the food sector, and consequently all FAME used (in principle) in Sweden is imported as FAME, rape seed oil or seed (6). In Sweden a new source of biodiesel have emerged, tall oil diesel. Tall oil is extracted from black liquor and refined into a diesel fraction (not FAME) and can be mixed into fossil diesel, i.e. Preem Evolution diesel. The SUNPINE plant in Piteå have a capacity of 100 000 metric tons of tall oil diesel per annum, while the total potential in all of Sweden is claimed to be 200 000 tons (7). 100 000 tons of tall oil corresponds to 1% of the total diesel consumption in Sweden. in Sweden for 2010 and a prognosis for 2014. (6). Accordingly, the profoundest task is to decrease the fossil fuel dependency in the transport sector, and clearly, the first generation biofuels can´t do this on its own. Biogas is a fuel gas with high methane content that can be used in a similar way to natural gas; for instance for cooking, heating and as transportation fuel. Today biogas is produced by fermentation of waste (municipal waste, sludge, manure), but can be produced by gasification of biomass, for instance from forest residues such as branches and rots (GROT in Swedish). To get high efficiency in the production, the lower hydrocarbons, mainly methane, in the producer gas, should not be converted into synthesis gas. Instead a synthesis gas with high methane content is sought. This limits the drainage of chemically bonded energy, due to the exothermic reaction in the synthesis step (so called methanisation). In 2011 0.7 TWh of biogas was produced in Sweden by fermentation of waste (6) and there were no production by gasification, at least not of economic importance. The potential seems to be large, though. In 2008 the total potential for biogas production, in Sweden, from waste by fermentation and gasification was estimated to 70 TWh (10 TWh fermentation and 60 TWh gasification) (8). This figure includes only different types of waste and no dedicated agricultural crops or dedicated forest harvest. Activities in the biogas sector, by gasification, in Sweden are the Göteborgs energi´s Gobigas project in Gothenburg and Eon´s Bio2G-project, now pending, in south of Sweden. If the producer gas is cleaned and upgraded into synthesis gas also other fuels could be produced. In Sweden methanol and DME productions are planned for in the Värmlands metanol-project and at Chemrecs DME production plant in Piteå.
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| 9. |
- Källström, Elisabeth, et al.
(författare)
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On-board Clutch Slippage Detection and Diagnosis in Heavy Duty Machine
- 2018
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Ingår i: International Journal of Prognostics and Health Management. - : PHM Society. - 2153-2648. ; 9:1
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Tidskriftsartikel (refereegranskat)abstract
- In order to reduce unnecessary stops and expensive downtime originating from clutch failure of construction equipment machines; adequate real time sensor data measured on the machinein combination with feature extraction and classification methods may be utilized.This paper, based on a study at Volvo Construction Equipment,presents a framework with feature extraction methods and an anomaly detection module combined with Case-Based Reasoning (CBR) for on-board clutch slippage detection and diagnosis in a heavy duty equipment. The feature extraction methods used are Moving Average Square Value Filtering (MASVF) and a measure of the fourth order statistical properties of the signals implemented as continuous queries over data streams. The anomaly detection module has two components,the Gaussian Mixture Model (GMM) and the Logistics Regression classifier. CBR is a learning approach that classifies faults by creating a new solution for a new fault case from the solution of the previous fault cases. Through use of a data stream management system and continuous queries (CQs), the anomaly detection module continuously waits for a clutch slippage event detected by the feature extraction methods, the query returns a set of features which activates the anomaly detection module. The first component of the anomaly detection module trains a GMM to extracted features while the second component uses a Logistic Regression classifier for classifying normal and anomalous data. When an anomalyis detected, the Case-Based diagnosis module is activated for fault severity estimation.
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| 10. |
- Langer, Sarka, 1960, et al.
(författare)
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Impacts of fuel quality on indoor environment onboard a ship: From policy to practice
- 2020
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Ingår i: Transportation Research Part D-Transport and Environment. - : Elsevier BV. - 1361-9209 .- 1879-2340. ; 83
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Tidskriftsartikel (refereegranskat)abstract
- Environmental considerations, concerning the negative impacts of ship exhaust gases and particles on ambient air quality, are behind the requirements of cleaner marine fuels currently applied in designated emission control areas (ECAs). We investigated the impact of a ship operating on two types of fuel on the indoor air quality onboard. Gaseous and particulate air pollutants were measured in the engine room and the accommodation sections on-board an icebreaker operating first on Heavy Fuel Oil (HFO, 1%-S), and later Marine Diesel Oil (MDO, 0.1%-S). Statistically significant decrease of SO2, NOx, PM2.5 and particle number concentration were observed when the ship was operating on MDO. Due to the higher content of alkylated PAHs in MDO compared to HFO, the concentration of PAHs increased during operation on MDO. The particulate PAHs classified as carcinogens, were similar to or lower in the MDO campaign. Chemical analysis of PM2.5 revealed that the particles consisted mainly of organic carbon and sulfate, although the fraction of metals was quite large in particles from the engine room. Principal Component Analysis of all measured parameters showed a clear difference between HFO and MDO fuel on the indoor environmental quality on-board the ship. This empirical study poses a first example on how environmental policy-making impacts not only the primary target at a global level, but also brings unexpected localized benefits at workplace level. The study emphasizes the need of further investigations on the impact of new marine fuels and technologies on the indoor air environments on board.
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