| 1. |
- Ahrens, Lutz, et al.
(författare)
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Analysis of per- and polyfluoroalkyl substances (PFASs) and phenolic compounds in Swedish rivers over four different seasons
- 2018
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Rapport (övrigt vetenskapligt/konstnärligt)abstract
- Per- and polyfluoroalkyl substances (PFASs) and phenolic compounds are emerging organic pollutants characterized by their persistency, bioaccumulation and toxicity potential. In this study, 28 PFASs and 10 phenolic compounds were investigated in 10 Swedish rivers over four different seasons (October 2016, January 2017, April 2017 and July 2017). The objective was to investigate the levels, composition profiles, sesonal trends and fluxes for both compound classes. In total, 7 out of 28 PFASs and 9 out of 10 phenolic compounds were detected in surface water from the 10 rivers. The average concentration in all samples was 3.2 ng L-1 for ∑28PFASs (median 2.4 ng L-1, n = 40), while 230 ng L-1 for the sum of the phenolic compounds (median 0 ng L-1, n = 38). Highest average ∑28PFAS concentrations were found in Rönneån with 10 ng L-1 (median 11 ng L-1), followed by Norrström with 9.0 ng L-1 (median 9.1 ng L-1), whereas no PFASs were detected in Umeå älv and Ångermanälven. On the other hand, highest average of the sum of the phenolic compound concentrations were found in Nyköpingsån with 1500 ng L-1 (median 57 ng L-1), while for the other rivers the average ranged between 50 ng L-1 and 140 ng L-1, except for Emån where TBP was only detected in one sample with 0.33 ng L-1. This indicates that PFASs and phenolic compounds origin from different sources. The dominant PFASs were perfluorobutane sulfonic acid (PFBS, 38 % of the ∑28PFASs), perfluorooctanoic acid (PFOA, 21 %), and perfluorooctane sulfonic acid (PFOS (branched), 8.9 %), while the dominant phenolic compounds were 4nonylphenol (4-NP, 67 %), 4-tert-nonylphenol-diethoxylate (4-NP-EO2, 20 %), and 2,4,6tribromophenol (TBP, 10 %). The concentrations of PFASs and phenolic compounds were relatively constant during the four investigated seasons which indicates a relatively steady input of these two compound classes into the river systems. The daily fluxes of Σ28PFAS was estimated to be in total 220 g d-1 (81 kg year-1), whereas the daily fluxes of phenolic compounds was estimated to be 16000 g d-1 (5700 kg year-1) for all 10 investigated rivers. The Annual Average Environmental Quality Standard (AA-EQS) of the EU Water Framework Directive (WFD) was exceeded in 33% (n = 13) of the surface water samples for the sum of linear and branched PFOS and in 13% (n = 5) of the surface water samples for 4NP. This indicates that there is a potential risk for the aquatic environment. The AA-EQS of 4-octylphenol (4-OP) and pentachlorophenol (PCP) was not exceeded in any surface water sample.
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| 2. |
- Gobelius, Laura, et al.
(författare)
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Calibration and application of passive sampling for per- and polyfluoroalkyl substances in a drinking water treatment plant
- 2019
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Ingår i: Journal of Hazardous Materials. - : Elsevier BV. - 0304-3894 .- 1873-3336. ; 362, s. 230-237
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Tidskriftsartikel (refereegranskat)abstract
- The aim of this study was to calibrate and apply polar organic chemical integrative samplers (POCIS) to examine 26 per- and polyfluoroalkyl substances (PFASs) in a drinking water treatment plant (DWTP). As a first step, the sampling rates (R-s) of 14 PFASs were determined in a laboratory calibration study for POCIS-WAX (weak-anion exchange) and POCIS-HLB (hydrophilic-lipophilic balance) (each with a surface area per mass of sorbent ratio of 227 cm(2) g(-1)). While most PFASs were still in the linear uptake phase during the 28-day calibration study, R-s ranged from 0.003 to 0.10 L d(-1) for POCIS-WAX and 0.00052 to 0.13 for POCIS-HLB. It is important to note that POCIS-WAX had higher R-s, for short-chain perfluoroalkyl carboxylates (PFCAs) with a perfluorocarbon chain length of C3-C6 and perfluorobutane sulfonate (PFBS) compared with POCIS-HLB. Furthermore, R-s was significantly positively correlated with the sorbent-water partition coefficient (K-pw) for POCIS-WAX and POCIS-HLB (p < 0.0001). Use of POCIS-WAX and POCIS-HLB in the DWTP showed good agreement with composite water sampling. No removal of PFASs was observed in the full-scale DWTP. Overall, this is the first study of PFAS monitoring in a DWTP using two types of POCIS. The results demonstrate high suitability for future applications.
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| 3. |
- Kikuchi, Johannes, et al.
(författare)
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Analysis of per- and polyfluoroalkyl substances (PFASs) in soil from Swedish background sites
- 2018
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Rapport (övrigt vetenskapligt/konstnärligt)abstract
- Per- and polyfluoroalkyl substances (PFASs) are persistent organic pollutants with bioaccumulative and toxic potential. This study investigated the levels, composition profiles and geographical distribution of 28 PFASs in 31 soil samples from Swedish background areas. In total, 15 of the 28 analysed PFASs were detected, with an average concentration of 2.4 ng g-1 dw (median of 1.9 ng g-1 dw, n = 31). The dominant PFASs in the soil samples were perfluorooctane sulfonic acid (PFOS) (20 % of the ∑28PFASs), perfluorooctane sulfonamidoacetic acid (FOSAA, 15 %), 6:2 fluorotelomer sulfonic acid (6:2 FTSA, 14 %) and perfluorobutane sulfonic acid (PFBS, 13 %). Perfluorooctane sulfonic acid (PFOS) had also the highest detection frequency of the studied PFASs (77 %) in the soil samples with a median concentration of 0.30 ng g-1 dw. However, the guideline value for PFOS in soil for sensitive land use from the Swedish Geotechnical Institute (SGI) (3 ng g-1 dw) was not exceeded in any sample. However, assuming the same toxicity for all PFASs, the ∑28PFAS concentrations exceeded the guideline value (3 ng g-1 dw) in 9 out of 31 samples (29 %). PFOS and perfluoroundecanoic acid (PFUnDA) concentrations showed higher concentrations towards the south (significant negative correlation with latitude; p < 0.05), while FOSAA showed an opposite trend (p < 0.05). Furthermore, PFBS showed higher concentrations towards the west (significant negative correlation with longitude; p < 0.05). The proportion of PFOS (%) decreased significantly with latitude (i.e. towards the south), while the proportion of FOSAA (%) increased with latitude (p < 0.05). Furthermore, the concentrations of FOSAA, PFBS and perfluorotridecanoic acid (PFTriDA) showed a significant positive correlation with total organic carbon (TOC) (p < 0.05). The concentrations of FOSAA correlated significantly positive with both PFTriDA and PFBS (p < 0.05). Overall, PFASs were ubiquitously detected in Swedish background soil samples and showed distinguish geographical distribution. However, more data are needed regarding the pathways and sources of PFASs in soil and identifying potential hot spots.
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