| 1. |
- Björk, Mats, 1960-, et al.
(författare)
-
Methane emissions from macrophyte beach wrack on Baltic seashores
- 2023
-
Ingår i: Ambio. - : Springer Nature. - 0044-7447 .- 1654-7209. ; 52:1, s. 171-181
-
Tidskriftsartikel (refereegranskat)abstract
- Beach wrack of marine macrophytes is a natural component of many beaches. To test if such wrack emits the potent greenhouse gas methane, field measurements were made at different seasons on beach wrack depositions of different ages, exposure, and distance from the water. Methane emissions varied greatly, from 0 to 176 mg CH4-C m−2 day−1, with a clear positive correlation between emission and temperature. Dry wrack had lower emissions than wet. Using temperature data from 2016 to 2020, seasonal changes in fluxes were calculated for a natural wrack accumulation area. Such calculated average emissions were close to zero during winter, but peaked in summer, with very high emissions when daily temperatures exceeded 20 °C. We conclude that waterlogged beach wrack significantly contributes to greenhouse gas emissions and that emissions might drastically increase with increasing global temperatures. When beach wrack is collected into heaps away from the water, the emissions are however close to zero.
|
|
| 2. |
- Baresel, Christian, et al.
(författare)
-
Uncertainty-Accounting Environmental Policy and Management of Water Systems
- 2007
-
Ingår i: Environmental Science & Technology. - : American Chemical Society (ACS). - 0013-936X .- 1520-5851. ; 41:10, s. 3653–3659-
-
Tidskriftsartikel (refereegranskat)abstract
- Environmental policies for water quality and ecosystemmanagement do not commonly require explicit stochasticaccounts of uncertainty and risk associated with thequantification and prediction of waterborne pollutant loadsand abatement effects. In this study, we formulate andinvestigate a possible environmental policy that does requirean explicit stochastic uncertainty account. We compareboth the environmental and economic resource allocationperformance of such an uncertainty-accounting environmentalpolicy with that of deterministic, risk-prone and riskaverseenvironmental policies under a range of differenthypothetical, yet still possible, scenarios. The comparisonindicates that a stochastic uncertainty-accountingpolicy may perform better than deterministic policies overa range of different scenarios. Even in the absence ofreliable site-specific data, reported literature values appearto be useful for such a stochastic account of uncertainty.
|
|
| 3. |
- Bagherbandi, Mohammad, et al.
(författare)
-
Moho depth uncertainties in the Vening-Meinesz Moritz inverse problem of isostasy
- 2014
-
Ingår i: Studia Geophysica et Geodaetica. - : Springer Science and Business Media LLC. - 0039-3169 .- 1573-1626. ; 58:2, s. 227-248
-
Tidskriftsartikel (refereegranskat)abstract
- We formulate an error propagation model based on solving the Vening Meinesz-Moritz (VMM) inverse problem of isostasy. The system of observation equations in the VMM model defines the relation between the isostatic gravity data and the Moho depth by means of a second-order Fredholm integral equation of the first kind. The corresponding error model (derived in a spectral domain) functionally relates the Moho depth errors with the commission errors of used gravity and topographic/bathymetric models. The error model also incorporates the non-isostatic bias which describes the disagreement, mainly of systematic nature, between the isostatic and seismic models. The error analysis is conducted at the study area of the Tibetan Plateau and Himalayas with the world largest crustal thickness. The Moho depth uncertainties due to errors of the currently available global gravity and topographic models are estimated to be typically up to 1-2 km, provided that the GOCE gravity gradient observables improved the medium-wavelength gravity spectra. The errors due to disregarding sedimentary basins can locally exceed similar to 2 km. The largest errors (which cause a systematic bias between isostatic and seismic models) are attributed to unmodeled mantle heterogeneities (including the core-mantle boundary) and other geophysical processes. These errors are mostly less than 2 km under significant orogens (Himalayas, Ural), but can reach up to similar to 10 km under the oceanic crust.
|
|
| 4. |
- Sjöberg, Lars E., et al.
(författare)
-
A study on the Fennoscandian post-glacial rebound as observed by present-day uplift rates and gravity field model GOCO02S
- 2013
-
Ingår i: Acta Geodaetica et Geophysica. - : Springer Science and Business Media LLC. - 2213-5812 .- 2213-5820 .- 1217-8977 .- 1587-1037. ; 48:3, s. 317-331
-
Tidskriftsartikel (refereegranskat)abstract
- Repeated absolute gravity measurements in Fennoscandia have revealed that the on-going post-glacial rebound can be regarded as a pure viscous flow of mantle mass of density 3390 kg/m(3) towards the central part of the region caused by a gravity/uplift rate of -0.167 mu Gal/mm. Our model estimates the rebound induced rates of changes of surface gravity and geoid height to have peaks of -1.9 mu Gal/yr and 1.6 mm/yr, respectively, the former being consistent with absolute gravity observations. The correlation coefficient of the spherical harmonic representations of the geoid height and uplift rate for the spectral windows between degrees 10 and 70 is estimated to -0.99 +/- 0.006, and the maximum remaining land uplift is estimated to the order of 80 m. Both the (almost) linear increase of relaxation time with degree and the linear relation between geoid height and uplift rate support a model with mass flow in the major part of the mantle and disqualify the model with a flow in a thin channel below the crust. The mean viscosity of the flow in the central uplift region is estimated to 4x10(21) Pa s.
|
|
| 5. |
- Bagherbandi, Mohammad, et al.
(författare)
-
On the residual isostatic topography effect in the gravimetric Moho determination
- 2015
-
Ingår i: Journal of Geodynamics. - : Elsevier BV. - 0264-3707 .- 1879-1670. ; 83, s. 28-36
-
Tidskriftsartikel (refereegranskat)abstract
- In classical isostatic models, a uniform crustal density is typically assumed, while disregarding the crustal density heterogeneities. This assumption, however, yields large errors in the Moho geometry determined from gravity data, because the actual topography is not fully isostatically compensated. Moreover, the sub-crustal density structures and additional geodynamic processes contribute to the overall isostatic balance. In this study we investigate the effects of unmodelled density structures and geodynamic processes on the gravity anomaly and the Moho geometry. For this purpose, we define the residual isostatic topography as the difference between actual topography and isostatic topography, which is computed based on utilizing the Vening Meinesz-Moritz isostatic theory. We show that the isostatic gravity bias due to disagreement between the actual and isostatically compensated topography varies between -382 and 596 mGal. This gravity bias corresponds to the Moho correction term of -16 to 25 km. Numerical results reveal that the application of this Moho correction to the gravimetrically determined Moho depths significantly improves the RMS fit of our result with some published global seismic and gravimetric Moho models. We also demonstrate that the isostatic equilibrium at long-to-medium wavelengths (up to degree of about 40) is mainly controlled by a variable Moho depth, while the topographic mass balance at a higher-frequency spectrum is mainly attained by a variable crustal density.
|
|
| 6. |
- Eveborn, David, 1978-, et al.
(författare)
-
Phosphorus in soil treatment systems : accumulation and mobility
- 2014
-
Ingår i: Water Research. - : Elsevier. - 0043-1354 .- 1879-2448. ; 64, s. 42-52
-
Tidskriftsartikel (refereegranskat)abstract
- In several western countries, septic tanks with subsequent soil treatment systems (STS) are a common treatment technique for domestic wastewater in rural areas. However the suitability of STS (especially relatively close to surface waters) can be questioned since the discharge of phosphorus (P) from such effluents is not well known. In this study, six STS in Sweden (11 to 28 years old) were investigated by means of batch and column experiments on samples taken from the unsaturated subsoil beneath the distribution pipes. At all sites the wastewater had clearly influenced the soil. This was observed through decreased pH, increased amounts of oxalate extractable metals and altered P sorption properties. The amount of accumulated P in the STS (defined as the amount of total P in the STS samples minus the amount of total P in unused soil samples) were found to be between 0.32 and 0.87 kg m-3, which in most cases was just a small fraction of the estimated P load (< 30%). Column studies revealed that remarkably high P concentrations (up to 6 mg L-1) were leached from the material when deionized water was applied. However, the response to deionized water varied between the sites. The affinity for P in the soils was well correlated to the amount of oxalate-extractable aluminium (as evidenced by a strong relationship between oxalate-extractable Al and oxalate-extractable P) and generally soils with high content of oxalate extractable Al was also less vulnerable to P leakage.
|
|
| 7. |
- Gustafsson, Jon Petter, 1964-, et al.
(författare)
-
Aluminium and base cation chemistry in dynamic acidification models - need for a reappraisal?
- 2018
-
Ingår i: SOIL. - : COPERNICUS GESELLSCHAFT MBH. - 2199-3971 .- 2199-398X. ; 4:4, s. 237-250
-
Tidskriftsartikel (refereegranskat)abstract
- Long-term simulations of the water composition in acid forest soils require that accurate descriptions of aluminium and base cation chemistry are used. Both weathering rates and soil nutrient availability depend on the concentrations of Al3+, of H+, and of base cations (Ca2+, Mg2+, Na+, and K+). Assessments of the acidification status and base cation availability will depend on the model being used. Here we review in what ways different dynamic soil chemistry models describe the processes governing aluminium and base cation concentrations in the soil water. Furthermore, scenario simulations with the HD-MINTEQ model are used to illustrate the difference between model approaches. The results show that all investigated models provide the same type of response to changes in input water chemistry. Still, for base cations we show that the differences in the magnitude of the response may be considerable depending on whether a cation-exchange equation (Gaines-Thomas, Gapon) or an organic complexation model is used. The former approach, which is used in many currently used models (e.g. MAGIC, ForSAFE), causes stronger pH buffering over a relatively narrow pH range, as compared to state-of-the-art models relying on more advanced descriptions in which organic complexation is important (CHUM, HD-MIN PLQ). As for aluminium, a "fixed" gibbsite constant, as used in MAGIC, SMART/VSD, and ForSAFE, leads to slightly more pH buffering than in the more advanced models that consider both organic complexation and Al(OH)(3) (s) precipitation, but in this case the effect is small. We conclude that the descriptions of acid-base chemistry and base cation binding in models such as MAGIC, SMART/VSD, and ForSAFE are only likely to work satisfactorily in a narrow pH range. If the pH varies greatly over time, the use of modern organic complexation models is preferred over cation-exchange equations.
|
|
| 8. |
- Hoppe, Sabina, et al.
(författare)
-
Evaluation of current copper bioavailability tools for soft freshwaters in Sweden
- 2015
-
Ingår i: Ecotoxicology and Environmental Safety. - : Elsevier BV. - 0147-6513 .- 1090-2414. ; 114, s. 143-149
-
Tidskriftsartikel (refereegranskat)abstract
- The Water Framework Directive (WFD) in Europe calls for an improved aquatic ecological status. Biotic ligand models (BLM) have been suggested as a possible tool assisting in the regulatory process. The aim of this study was therefore to investigate the applicability of BLM under the WFD to set environmental quality standards (EQS), in particular regarding copper in Swedish freshwaters of which many are softer than those used for model calibration. Three different BLMs, one acute and two chronic, were applied to water chemistry data from 926 lakes and 51 rivers (1530 data entries) and evaluated with respect to their calibration range for input parameters. In addition, the predicted no-effect concentration (PNEC) for copper was calculated. From the 1530 data entries, 750 ended up outside of the BLM calibration range, when looking at the chemical parameters Ca2+, alkalinity, pH and DOC, primarily due to low carbonate alkalinity. Furthermore, the calculated Cu PNECs were higher than the suggested Swedish limit for Cu (4 µg L−1) in surface waters for 98% and 99% of the cases concerning lakes and rivers, respectively. To conclude, our findings show that water chemical characteristics outside of the calibration ranges are quite common in Sweden and that the investigated models differ in how they calculate toxicity concerning Cu under these conditions. As a consequence, additional work is required to validate the BLMs by use of bioassays with representative species of soft waters. Such results will show if these models can be used outside of their calibration ranges and also which of the models that gives the most reliable results.
|
|
| 9. |
- Tenzer, Robert, et al.
(författare)
-
Analysis of the Refined CRUST1.0 Crustal Model and its Gravity Field
- 2015
-
Ingår i: Surveys in geophysics. - : Springer Science and Business Media LLC. - 0169-3298 .- 1573-0956. ; 36:1, s. 139-165
-
Forskningsöversikt (refereegranskat)abstract
- The global crustal model CRUST1.0 (refined using additional global datasets of the solid topography, polar ice sheets and geoid) is used in this study to estimate the average densities of major crustal structures. We further use this refined model to compile the gravity field quantities generated by the Earth's crustal structures and to investigate their spatial and spectral characteristics and their correlation with the crustal geometry in context of the gravimetric Moho determination. The analysis shows that the average crustal density is 2,830 kg/m(3), while it decreases to 2,490 kg/m(3) when including the seawater. The average density of the oceanic crust (without the seawater) is 2,860 kg/m(3), and the average continental crustal density (including the continental shelves) is 2,790 kg/m(3). The correlation analysis reveals that the gravity field corrected for major known anomalous crustal density structures has a maximum (absolute) correlation with the Moho geometry. The Moho signature in these gravity data is seen mainly at the long-to-medium wavelengths. At higher frequencies, the Moho signature is weakening due to a noise in gravity data, which is mainly attributed to crustal model uncertainties. The Moho determination thus requires a combination of gravity and seismic data. In global studies, gravimetric methods can help improving seismic results, because (1) large parts of the world are not yet sufficiently covered by seismic surveys and (2) global gravity models have a relatively high accuracy and resolution. In regional and local studies, the gravimetric Moho determination requires either a detailed crustal density model or seismic data (for a combined gravity and seismic data inversion). We also demonstrate that the Earth's long-wavelength gravity spectrum comprises not only the gravitational signal of deep mantle heterogeneities (including the core-mantle boundary zone), but also shallow crustal structures. Consequently, the application of spectral filtering in the gravimetric Moho determination will remove not only the gravitational signal of (unknown) mantle heterogeneities, but also the Moho signature at the long-wavelength gravity spectrum.
|
|
| 10. |
- Berger, Tobias, et al.
(författare)
-
The impact of fluoride on Al abundance and speciation in boreal streams
- 2015
-
Ingår i: Chemical Geology. - : Elsevier. - 0009-2541 .- 1872-6836. ; 409, s. 118-124
-
Tidskriftsartikel (refereegranskat)abstract
- The impact of fluoride on the abundance and speciation of aluminium (Al) was investigated in three boreal streams characterised by overall high concentrations of fluoride and dissolved organic matter. Stream-water sampling was carried out several times a year for at least 4 years, and a chemical equilibrium model (Visual MINTEQ) was applied in order to model the proportion of colloidal and organically/inorganically complexed Al in the waters. The Al concentrations in filtered (0.45 μm) water samples were inversely correlated with pH, and reached values up to approximately 1. mg/L during low pH conditions (pH < 6.0). In a stream with high fluoride concentrations, as compared to a similar stream with only moderately elevated fluoride concentrations, the Al concentrations were consistently elevated. For the stream with high concentrations of fluoride and Al, the model predicted both high concentrations and proportions of Al-fluoride complexation. This prediction indicates that high fluoride levels contribute to raise both the Al abundance and the ratio of inorganic to organic Al complexation in stream water. In contrast, for another stream with high fluoride concentrations and consistently high (near neutral) pH, there was no evidence of fluoride affecting Al concentration or complexation. These results show that it is important to focus future studies on the role of high levels of dissolved fluoride on both the speciation and the toxicity of Al in stream water.
|
|
