| 1. |
- Pan, Jun, et al.
(författare)
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Enhanced anti-wetted PVDF membrane for pulping RO brine treatment by vacuum membrane distillation
- 2022
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Ingår i: Desalination. - : Elsevier. - 0011-9164 .- 1873-4464. ; 526
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Tidskriftsartikel (refereegranskat)abstract
- Large amounts of lignin, hemicellulose, organic matter and inorganic salts are present in pulping and papermaking wastewater. Therefore, the treatment and discharge of pulping wastewater are important issues. We have designed and developed the world's first zero liquid discharge (ZLD) system for it based on pretreatment-membrane-evaporative crystallization integrated technologies. However, for the treatment of high salt reverse osmosis (RO) brine, there are still challenges that need to be addressed. In this work, the feasibility of using a membrane distillation crystallization (MDC) process to treat high saline RO brine was investigated. Two different coating materials, Hyflon AD 40H and perfluoropolyether (PFPE), were applied to improve the membrane surface hydrophobicity for stable and efficient performance. After modification, the water contact angle was up to 138.4o and 157.7o for Hyflon/polyvinylidene fluoride (PVDF) and PFPE/PVDF composite membranes, respectively. Moreover, the PFPE/PVDF membrane showed a higher repellency toward RO brine, which is better for the following MDC treatment. During the MDC progress using composite PFPE/PVDF membranes, the salt crystals precipitated and gradually accumulated. More importantly, the final NaCl purity can be up to 94%. Therefore, it is hopeful to improve of the existing ZLD system by MDC operation.
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| 2. |
- Redeker, Cornelia
(författare)
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Strategies of urban flood integration : Zollhafen Mainz
- 2013
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Ingår i: Resilience and urban risk management. - London : CRC Press. - 9780415621472 - 9780429216688 - 9780203072820 ; , s. 57-63
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Konferensbidrag (refereegranskat)abstract
- Converting the inner city harbour Zollhafen in Mainz (Upper Rhine) into a new living district promotes a compact european city model by contributing to a decrease in land consumption and thus run-off. As a development outside of the municipal flood defense, it demands for flood adapted construction and a "retention-neutral" development to comply with German water legislation. The Zollhafen is being developed as a model project for flood adapted building in a partnership between the Stadtwerke Mainz Corporation (the municipal utilities company) as the owner of the harbour and the Ministry for the Environment of the State of Rheinland-Pfalz. Apart from defining requirements for building in the flood plain, different strategies and instruments are being developed to trigger innovative adaptive designs and to create public spaces which raise awareness for the inherent, but, due to the height of the site, rare flood risk.
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| 3. |
- Bishop, K, et al.
(författare)
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Testing the steady-state water chemistry model predictions of pre-industrial lake pH with paleolimnological data from northern Sweden.
- 2008
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Ingår i: Sci Total Environ. - : Elsevier BV. - 0048-9697. ; 407:1, s. 723-9
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Tidskriftsartikel (refereegranskat)abstract
- Criteria are needed for distinguishing naturally acid water from that acidified by air pollution, especially in the organic-rich waters of northern Sweden. The Steady-State Water Chemistry Model (SSWC) was augmented to include organic acidity so that it could predict pre-industrial pH in organic-rich waters. The resulting model predictions of preindustrial ANC and pH were then tested against diatom predictions of pre-industrial pH and alkalinity in 58 lakes from N. Sweden (after alkalinity was converted to ANC using the CBALK method). The SSWC Model's predictions of pre-industrial lake pH in N. Sweden did not correspond well with the diatom predictions, even when accounting for the uncertainty in the diatom model. This was due to the SSWC's sensitivity to short-term fluctuations in contemporary water chemistry. Thus the SSWC Model is not suitable for judging the acidification of individual lakes in areas such as northern Sweden where the degree of chronic acidification is small, or without a good average value of contemporary water chemistry. These results should be considered when assessing the accuracy of critical loads calculated using SSWC.
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| 4. |
- Blum, Kristin M., et al.
(författare)
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Removal of 30 active pharmaceutical ingredients in surface water under long-term artificial UV irradiation
- 2017
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Ingår i: Chemosphere. - : Elsevier BV. - 0045-6535 .- 1879-1298. ; 176, s. 175-182
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Tidskriftsartikel (refereegranskat)abstract
- This study investigated the i) kinetics, and ii) proportion of photolysis of 30 relatively stable active pharmaceutical ingredients (APIs) during artificial UV irradiation for 28 d in ammonium acetate buffer, filtered and unfiltered river water. Buffer was included to control removal kinetics under stable pH conditions and without particulate matter. Dark controls were used to determine removal due to other processes than photolysis and calculate the proportion of photolysis of the total removal. The removal of each API in each matrix was determined using online solid phase extraction/liquid chromatography tandem mass spectrometry (online SPE/LC-MS/MS). Most APIs transformed during the 28 d of UV irradiation and the dark controls showed that photolysis was the major removal process for the majority of the APIs studied. The half-lives ranged from 6 h (amitriptyline) in unfiltered river water to 884 h (37 d, carbamazepine) in buffer. In unfiltered river water, the proportion of APIs with short half-lives (<48 h) was much higher (29%) than in the other matrices (4%), probably due to additional organic carbon, which could have promoted indirect photolysis. Furthermore, two APIs, memantine and fluconazole, were stable in all three matrices, while alprazolam was stable in buffer and unfiltered river water and four additional APIs were stable in buffer. Considering the relatively long-term UV-exposure, this study enabled the investigation of environmentally relevant half-lives in natural waters. Many APIs showed high persistence, which is environmentally concerning and emphasizes the importance of further studies on their environmental fate and effects.
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| 5. |
- Chalh, Ridouane, et al.
(författare)
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Automating time series analysis to predict/forecast rainfall in AGUELMAM SIDI ALI watershed in Morocco
- 2019
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Ingår i: International Journal of Innovative Technology and Exploring Engineering. - : Blue Eyes Intelligence Engineering and Sciences Engineering and Sciences Publication - BEIESP. - 2278-3075. ; 8:9, s. 3008-3014
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Tidskriftsartikel (refereegranskat)abstract
- Moroccan economy is largely based upon rainfall, use of water resources and crop productivity, for that it’s considered as an agricultural country. It’s more required and more important for any farmer to forecast rainfall prediction in order to analyze crop productivity. Predicting the atmosphere or forecasting the state of the weather is considered as challenge for scientific research. The prediction of rainfall monthly or/and seasonal time scales is the application of science and technology to invent and to schedule the agriculture strategies. Recently different research articles achieve to forecast and/or predict rainfall monthly or seasonal time scales using different techniques. The methodology followed in this work, be focused on automating time series analysis to forecast/predict precipitation daily, monthly or seasonal in Aguelmam Sidi Ali basin in Morocco for last 32 years ago from 1975 to 2007. We first have to study the rainfall data theoretically using the simplest form statistical analysis, which is the univariate analysis, as long as only one variable is involved in our case study. To get the selected and suitable model of time series to automate, we used different autocorrelation methods based on various criterion such as: Akaike Information Criterion (AIC), estimation of parameters using Yule-Walker (YW) and Maximum Likelihood Estimation (MLE). The results of our experiment show that it is possible using our system to obtain accurate rainfall prediction, with a more details and with a very fast way. It shows also that it’s possible to predict for next months or next years. To minimize the risk of floods and natural disasters within a basin in general and within the Aguelmam Sidi Ali basin in particular, accurate and timely rainfall forecasting is required.
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| 6. |
- Cuppen, Miriam, et al.
(författare)
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Dike relocation Nijmegen-lent: example of adaptive water management?
- 2009
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Konferensbidrag (refereegranskat)abstract
- Dike relocation Nijmegen-lent: example of adaptive water management? — TU Delft Research Portal Skip to main navigation Skip to search Skip to main content TU Delft Research Portal Logo Help & FAQ Home Researchers Research Units Research output Activities Datasets Press / Media Prizes Projects Search by expertise, name or affiliation Dike relocation Nijmegen-lent: example of adaptive water management? ME Cuppen, B Stalenberg, C Redeker Policy Analysis Hydraulic Structures and Flood Risk Research output: Chapter in Book/Conference proceedings/Edited volume › Conference contribution › Scientific › peer-review Overview Original language Undefined/Unknown Title of host publication Proceedings of NIG Workconference 2009 Editors Jurian Edelenbos et al. Place of Publication Leiden Publisher NIG Pages 1-22 Number of pages 22 Publication status Published - 2009 Event NIG Workconference …
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| 7. |
- de Araujo, Kleiton R., et al.
(författare)
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Carbon dioxide (CO2) concentrations and emission in the newly constructed Belo Monte hydropower complex in the Xingu River, Amazonia
- 2019
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Ingår i: Biogeosciences. - Gottingen : Copernicus Gesellschaft MBH. - 1726-4170 .- 1726-4189. ; 16:18, s. 3527-3542
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Tidskriftsartikel (refereegranskat)abstract
- The Belo Monte hydropower complex located in the Xingu River is the largest run-of-the-river (ROR) hydroelectric system in the world and has one of the highest energy production capacities among dams. Its construction received significant media attention due to its potential social and environmental impacts. It is composed of two ROR reservoirs: the Xingu Reservoir (XR) in the Xingu's main branch and the Intermediate Reservoir (IR), an artificial reservoir fed by waters diverted from the Xingu River with longer water residence time compared to XR. We aimed to evaluate spatiotemporal variations in CO2 partial pressure (pCO(2)) and CO2 fluxes (FCO2) during the first 2 years after the Xingu River impoundment under the hypothesis that each reservoir has contrasting FCO2 and pCO(2) as vegetation clearing reduces flooded area emissions. Time of the year had a significant influence on pCO(2) with the highest average values observed during the high-water season. Spatial heterogeneity throughout the entire study area was observed for pCO(2) during both low-and high-water seasons. FCO2, on the other hand, only showed significant spatial heterogeneity during the high-water period. FCO2 (0.90 +/- 0.47 and 1.08 +/- 0.62 mu mol m(2) d(-1) for XR and IR, respectively) and pCO(2) (1647 +/- 698 and 1676 +/- 323 mu atm for XR and IR, respectively) measured during the high-water season were on the same order of magnitude as previous observations in other Amazonian clearwater rivers unaffected by impoundment during the same season. In contrast, during the low-water season FCO2 (0.69 +/- 0.28 and 7.32 +/- 4.07 mu mol m(2) d(-1) for XR and IR, respectively) and pCO(2) (839 +/- 646 and 1797 +/- 354 mu atm for XR and IR, respectively) in IR were an order of magnitude higher than literature FCO2 observations in clearwater rivers with naturally flowing waters. When CO2 emissions are compared between reservoirs, IR emissions were 90% higher than values from the XR during low-water season, reinforcing the clear influence of reservoir characteristics on CO2 emissions. Based on our observations in the Belo Monte hydropower complex, CO2 emissions from ROR reservoirs to the atmosphere are in the range of natural Amazonian rivers. However, the associated reservoir (IR) may exceed natural river emission rates due to the preimpounding vegetation influence. Since many reservoirs are still planned to be constructed in the Amazon and throughout the world, it is critical to evaluate the implications of reservoir traits on FCO2 over their entire life cycle in order to improve estimates of CO2 emissions per kilowatt for hydropower projects planned for tropical rivers.
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| 8. |
- Essalhi, Mohamed, et al.
(författare)
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10 - Thermo-osmosis
- 2021. - 1
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Ingår i: Osmosis Engineering. - : Elsevier. - 9780128210161 ; , s. 279-312
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Bokkapitel (övrigt vetenskapligt/konstnärligt)abstract
- The existence of nonisothermal transport of liquids through a gelatin membrane was first described by Lippmann in 1907, and 5 years later, it was investigated by Aubert in more detail using membranes of gelatin pig’s bladder, parchment paper and viscose. In this phenomenon, there is no liquid/vapor phase transition and it is known as thermo-osmosis (TO) or thermal osmosis (TO). Lippmann also observed TO in air, obviously without prior knowledge of the work of Feddersen and Reynolds. However, at that time the lack of theory on irreversible processes prevented the progress towards understanding this phenomenon.
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| 9. |
- Essalhi, Mohamed, et al.
(författare)
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Improvement of nanostructured electrospun membranes for desalination by membrane distillation technology
- 2021
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Ingår i: Desalination. - : Elsevier. - 0011-9164 .- 1873-4464. ; 510
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Tidskriftsartikel (refereegranskat)abstract
- A systematic study is carried out to determine the optimum electrospinning preparation condition to prepare an adequate electrospun nanofibrous membrane (ENM) for direct contact membrane distillation (DCMD). A structural properties investigation of ENM was carried out because of the significant impact of its architectural structure, nanofiber diameter, inter-fiber space and ENM thickness, on DCMD performance. The morphology, hydrophobicity, mechanical properties, crystallinity and DCMD desalination were investigated. A long-term DCMD experiment (100h) was carried out using 30 g/L NaCl aqueous solution, both in the feed and permeate side of the optimum ENM membrane to evaluate its potential to produce drinkable water in case of lack of distilled water, for instance in a remote area, emergency situation, and/or portable system. In this case, drinkable water could be produced after 28 h with a permeate flux of 57.5 kg/m2.h and a salt rejection factor greater than 99.9%. Another long-term DCMD experiment (65 h) was conducted using 30 g/L NaCl aquesous solution as feed but at a higher temperature and distilled water as permeate to evaluate the desalination stability, wettability and scaling of the optimum ENM. A permeate flux of 58.5 kg/m2.h was obtained with a salt rejection factor greater than 99.9%.
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| 10. |
- Hörsing, Maritha, et al.
(författare)
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Sorption of 71 Pharmaceuticals to Powder Activated Carbon for Improved Wastewater Treatment
- 2022
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Ingår i: Clean Technologies. - : MDPI. - 2571-8797. ; 4:2, s. 296-308
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Tidskriftsartikel (refereegranskat)abstract
- In this study, sorption distribution coefficients were determined for 71 pharmaceuticals, aiming to describe their sorption behavior to powder activated carbon (PAC). The data are expected to be applied when designing and upgrading wastewater treatment plants (WWTP) for improved removal of pharmaceuticals by applying sorption to PAC as an additional removal technique. Sorption isotherms were determined for the pharmaceuticals over a concentration interval covering a wide range from 0.08 to 10 µg/L using PAC at a concentration of 10 mg/L. The best fitted sorption isotherms were used to calculate the distribution coefficients (Kd) and these were applied to estimate that the PAC doses needed to achieve a target concentration of 10 ng/L in the effluent. A target concentration was used since neither discharge limit values nor environmental quality standards in general have been defined for these compounds. Using a %-removal approach does not guarantee achievement of concentrations low enough to protect the water ecosystems. Some of the pharmaceuticals will be reduced by the addition of small amounts of PAC. Examples are atenolol, carbamazepine, citalopram, codeine, fluoxetine and ibuprofen. For others, e.g., oxazepam, an alternative treatment has to be considered since the requested dose is too high to be realistic for a target concentration of 10 ng/L.
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