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  • Angenendt, Knut, et al. (författare)
  • Ionic liquid structures from large DFT calculations using mindless configurations
  • 2010
  • Ingår i: Journal of Physical Chemistry C. - 1932-7447. ; 114, s. 20577-20582
  • Tidskriftsartikel (refereegranskat)abstract
    • Three different popular imidazolium based ionic liquids (ILs); EMI-BF4, EMI-PF6, and EMI-TFSI, have been modeled by DFT calculations (B3LYP/6-311+G*) using large, up to 130 atom cluster models, for a better understanding of the structure and ion ion interactions in these ILs and ILs in general. Particular emphasis has been put on the role of appropriate starting structures and how the present large models differ from the ion-pair models of ILs generally used. The system size normalized ion ion interaction energies are shown to converge rapidly, and conformational equilibria and higher order properties like IR spectra are shown to be valuable as quality criteria. The explicit inclusion of an IL environment by the large cluster approach is also compared to using an implicit, continuum, strategy via SCRF C-PCM calculations.
  • Bengtsson, Lars, 1963- (författare)
  • Avancerad Elektrisk Mätteknik
  • 1996
  • Bok (övrigt vetenskapligt)abstract
    • Boken är avsedd för fortsättnigskurser i elektrisk mätteknik på högskolenivå. Den lämpar sig också väl som kompletteringslitteratur för kurser i signalbehandling. Innehållet är framför allt koncentrerat till analog och digital frekvensanalys, brusreducerande mätmetoder och AD/DA-omvandlingsmetoder. Ett kapitel tar upp signalbehandling och sambanden mellan analys i tid och rum. Fouriertransformen och faltningsintegralen gås igenom i detalj. Boken avslutas dels med ett kapitel om snabba förlopp i transmissionsledningar, dels med ett kapitel om GPIB-bussen. I appendix finns även en beskrivning av RS-232-kommunikation.
  • Bengtsson, Lars, 1963- (författare)
  • Electrical Measurement Systems and Methods
  • 2014
  • Bok (övrigt vetenskapligt)abstract
    • This book treats a wide range of aspects on electrical measurement systems and the methods used to acquire data from electronic systems. That includes sensors and sensor design, amplifiers such as differential and charge amplifiers, ADCs and DACs, digital oscilloscopes, cable theory and probes, noise and noise coupling, common and normal mode signals. This first part (chapters 1-8) doesn’t require any advanced mathematics and is aimed towards undergraduates. The second part (chapters 9-17) is on an advanced level (master level) and treats transform theory (Fourier, Laplace, z) and how to handle signals in frequency space. We cover the sampling theorem (Nyquist), resolution bandwidth, frequency spectrum distortions like aliasing and leakage and how to apply windows in a frequency spectrum. We also cover systems and signal processing in time-space, including convolution and correlation, filter theory and filter design (both analog and digital). The last chapters concern the statistical aspects on measurement systems and signals, like point and interval estimations, curve fitting and uncertainty estimations according to the GUM method.
  • Carini, Giovanni, et al. (författare)
  • Hypersonic attenuation in cesium borate glasses: Relaxation and anharmonicity
  • 2009
  • Ingår i: MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING. 15th International Conference on Internal Friction and Mechanical Spectroscopy (ICIFMS-15). Perugia, ITALY. JUL 20-25, 2008. - 0921-5093. ; 521-22, s. 247-250
  • Konferensbidrag (refereegranskat)abstract
    • The internal friction and the sound velocity in a cesium borate glass (Cs(2)O)(0.14)(B(2)O(3))(0.86) were measured at ultrasonic and hypersonic frequencies by Brillouin scattering measurements over the temperature range between 15 and 300 K. The analysis of the experimental results show that, in addition to thermally activated local motions of structural defects, the vibrational anharmonicity contributes substantially to the temperatures dependences of both the hypersonic loss and velocity. It has been also proved that above 150 K the vibrational anharmonicity appears to be governed by the Akhiezer mechanism of phonon viscosity.
  • Cherednichenko, Sergey, 1970-, et al. (författare)
  • Online Detection of H2O and CO in the Humid Raw Gas from the Gasifier Using Terahertz Spectroscopy
  • 2013
  • Ingår i: ICPS, 13 International Conference on Polygeneration Strategies, Sept.5-13, Vienna, Austria. - 978-3-950275483 ; s. 51-58
  • Konferensbidrag (refereegranskat)abstract
    • The integration of a gasifier with a complex multistage synthesis process, such as SNG synthesis, demands a fast monitoring of the gasifier performance. However, despite the availability of standard analyzers for determination of dry gas composition, there are still many practical difficulties remaining in the online measurement of tar and steam in the raw gas. For the detection of steam concentration, electromagnetic waves at terahertz frequencies (102-104 GHz) are promising with regard to development of a robust online measurement device for industrial application. The main reason for the high potential is the low risk for interference with the wide range of other molecules and that the transmission of electromagnetic waves at THz frequencies is rather low sensitive to deposits and particulate matter in the course of the beam compared to the conventional and well established wavelengths like infrared. In the present work, a THz gas spectrometer was designed and constructed to check the feasibility of applying this measurement technique at industrial scale. For this purpose, continuous flows of raw gas with various water and CO contents from the Chalmers gasifier as well as a flue gas with known water content from the biomass combustor were introduced to the spectrometer set-up. H2O and CO compositions in each stream were determined in an online manner. The results confirmed the possibility of applying strong rotational water lines at 448 and 380 GHz to develop reliable devices for online measurement of water vapor with excellent error interval. However, some difficulties were encountered for simultaneous detection CO concentration with water within the frequency range studied in this work (300-500 GHz).
  • Cherednichenko, Sergey, 1970-, et al. (författare)
  • Terahertz Gas Spectrometer
  • 2014
  • Ingår i: Swedish Microwave Days March 11-12, 2014, Gothenburg, Sweden.
  • Konferensbidrag (refereegranskat)abstract
    • We present a 300-500GHz gas spectrometer built for and practically tested at the 2–4-MW indirect gasifier at the Chalmers Power Center. The primary goal is precise online measurements of H2O vapor and CO concentrations in the producer gas. Experimentally obtained H2O vapor concentration resolution was about 1% at the conditions of 50% VMR and 400 deg.C.
  • Chernikova, Dina, 1982-, et al. (författare)
  • Testing a direct method for evaluating the concentration of boron in a fuel pool using scintillation detectors, and a 252Cf and an 241Am-Be source
  • 2013
  • Ingår i: Proceeding of ESARDA meeting 2013.
  • Konferensbidrag (refereegranskat)abstract
    • The present investigations are aimed at the development and testing of a direct non-destructive method for evaluating the concentration of boron in a fuel pool using scintillation detectors. The method uses a modified ratio between two gamma lines with energy of 480 keV and 2.23 MeV. These lines belong to the capture of a thermal neutron in boron and hydrogen, respectively. The relation between them can reveal the concentration of boron in the fuel pond. The method proposed was tested in a laboratory experiment with a 252Cf and an 241Am-Be source. EJ-309 liquid scintillation detectors were used for measurements of gamma spectra. The concentration of boron in water varied from 1550 ppm to 4200 ppm. The optimization and test studies were performed via MCNPX simulations. The results of these tests are provided in the present paper and they show that the boron content in water can be determined through using the characteristics of gamma lines with energy of 480 keV and 2.23 MeV.
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