| 1. |
- Bobrowski, Nicole, et al.
(författare)
-
Multi-component gas emission measurements of the active lava lake of Nyiragongo, DR Congo
- 2017
-
Ingår i: Journal of African Earth Sciences. - : Elsevier BV. - 1879-1956 .- 1464-343X. ; 134, s. 856-865
-
Tidskriftsartikel (refereegranskat)abstract
- Between 2007 and 2011 four measurement campaigns (June 2007, July 2010, June 2011, and December 2011) were carried out at the crater rim of Nyiragongo volcano, DR Congo. Nyiragongo is one of the most active volcanoes in Africa. The ground-based remote sensing technique Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS), which uses scattered sunlight, the in-situ Multi-Component Gas Analyzer System (Multi-GAS) and alkaline impregnated filter were simultaneously applied during all field trips. The bromine monoxide to sulfur dioxide (BrO/SO2) and carbon dioxide to sulfur dioxide (CO2/SO2) molar ratios were determined, among other ratios. During the different field trips variations of the level of the lava lake up to several tens of meters were observed during intervals of the order of minutes up to days and also between the years. The measured gas ratios presented covariations with the lava lake level changes. BrO/SO2 ratios and CO2/SO2 ratios showed similar behavior. Annual CO2/SO2 and BrO/SO2 average values are generally positively correlated. In June 2011 increased BrO/SO2 as well as increased CO2/SO2 ratios have been observed before a sudden decrease of the lava lake. Overall the Cl/S ratio, determined by filter-pack sampling, shows an increasing trend with time, which is accompanied by a decreasing sulfur dioxide flux, the later measured nearly continuously by automated MAX-DOAS instruments since 2004. Mean gas emission fluxes of CO2, Cl and ‘minimum-BrO’ fluxes are calculated using their ratio to SO2. The first two show an increase with time, in contrast to the SO2 fluxes. A simple conceptual model is proposed which can explain in particular the June 2011 data, but as well our entire data set. The proposed model takes up the idea of convective magma cells inside the conduit and the possible temporary interruption of part of the cycling. We propose than two alternatives to explain the observed gas emission variation: 1. It is assumed that the diffuse and fumarolic degassing could have significant influence on measured gas composition. The measured gas composition might rather represent a gas mixture of plume, diffuse and fumarolic degassing than only representing the volcanic plume. 2. It is proposed that the interruption of the convection has taken place in the upper part of the conduit and deep degassing of CO2 and bromine initially continues while mixing already with gas emissions from an ageing source, which is characterized by an already diminishing sulfur content. These complex process but as well as the gas mixing of different sources, could explain general features of our dataset, but can unfortunately neither be confirmed nor disproven by the data available today.
|
|
| 2. |
- Weis, Franz A., et al.
(författare)
-
Magmatic water contents determined through clinopyroxene : Examples from the Western Canary Islands, Spain
- 2015
-
Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 16:7, s. 2127-2146
-
Tidskriftsartikel (refereegranskat)abstract
- Water is a key parameter in magma genesis, magma evolution, and resulting eruption styles, because it controls the density, the viscosity, as well as the melting and crystallization behavior of a melt. The parental water content of a magma is usually measured through melt inclusions in minerals such as olivine, a method which may be hampered, however, by the lack of melt inclusions suitable for analysis, or postentrapment changes in their water content. An alternative way to reconstruct the water content of a magma is to use nominally anhydrous minerals (NAMs), such as pyroxene, which take up low concentrations of hydrogen as a function of the magma's water content. During magma degassing and eruption, however, NAMs may dehydrate. We therefore tested a method to reconstruct the water contents of dehydrated clinopyroxene phenocrysts from the Western Canary islands (n=28) through rehydration experiments followed by infrared and Mossbauer spectroscopy. Employing currently available crystal/melt partitioning data, the results of the experiments were used to calculate parental water contents of 0.710.07 to 1.490.15 wt % H2O for Western Canary magmas during clinopyroxene crystallization at upper mantle conditions. This H2O range is in agreement with calculated water contents using plagioclase-liquid-hygrometry, and with previously published data for mafic lavas from the Canary Islands and comparable ocean island systems elsewhere. Utilizing NAMs in combination with hydrogen treatment can therefore serve as a proxy for pre-eruptive H2O contents, which we anticipate becoming a useful method applicable to mafic rocks where pyroxene is the main phenocryst phase.
|
|
| 3. |
- Barnes, Paul W., et al.
(författare)
-
Ozone depletion, ultraviolet radiation, climate change and prospects for a sustainable future
- 2019
-
Ingår i: Nature Sustainability. - : Springer Science and Business Media LLC. - 2398-9629. ; 2:7, s. 569-579
-
Forskningsöversikt (refereegranskat)abstract
- © 2019, Springer Nature Limited. Changes in stratospheric ozone and climate over the past 40-plus years have altered the solar ultraviolet (UV) radiation conditions at the Earth’s surface. Ozone depletion has also contributed to climate change across the Southern Hemisphere. These changes are interacting in complex ways to affect human health, food and water security, and ecosystem services. Many adverse effects of high UV exposure have been avoided thanks to the Montreal Protocol with its Amendments and Adjustments, which have effectively controlled the production and use of ozone-depleting substances. This international treaty has also played an important role in mitigating climate change. Climate change is modifying UV exposure and affecting how people and ecosystems respond to UV; these effects will become more pronounced in the future. The interactions between stratospheric ozone, climate and UV radiation will therefore shift over time; however, the Montreal Protocol will continue to have far-reaching benefits for human well-being and environmental sustainability.
|
|
| 4. |
- Aldenhoff, Wiebke, 1985, et al.
(författare)
-
Comparison of ice/water classification in Fram Strait from C- and L-band SAR imagery
- 2018
-
Ingår i: Annals of Glaciology. - : Cambridge University Press (CUP). - 0260-3055 .- 1727-5644. ; 59:76pt2, s. 112-123
-
Tidskriftsartikel (refereegranskat)abstract
- In this paper an algorithm for ice/water classification of C- and L-band dual polarization synthetic aperture radar data is presented. A comparison of the two different frequencies is made in order to investigate the potential to improve classification results with multi-frequency data. The algorithm is based on backscatter intensities in co- and cross-polarization and autocorrelation as a texture feature. The mapping between image features and ice/water classification is made with a neural network. Accurate ice/water maps for both frequencies are produced by the algorithm and the results of two frequencies generally agree very well. Differences are found in the marginal ice zone, where the time difference between acquisitions causes motion of the ice pack. C-band reliably reproduces the outline of the ice edge, while L-band has its strengths for thin ice/calm water areas within the icepack. The classification shows good agreement with ice/water maps derived from met.no ice-charts and radiometer data from AMSR-2. Variations are found in the marginal ice zone where the generalization of the ice charts and lower accuracy of ice concentration from radiometer data introduce deviations. Usage of high-resolution dual frequency data could be beneficial for improving ice cover information for navigation and modelling.
|
|
| 5. |
- Kylander, Malin E., et al.
(författare)
-
Potentials and problems of building detailed dust records using peat archives : An example from Store Mosse (the "Great Bog"), Sweden
- 2016
-
Ingår i: Geochimica et Cosmochimica Acta. - : Elsevier BV. - 0016-7037 .- 1872-9533 .- 0046-564X. ; 190, s. 156-174
-
Tidskriftsartikel (refereegranskat)abstract
- Mineral dust deposition is a process often overlooked in northern mid-latitudes, despite its potential effects on ecosystems. These areas are often peat-rich, providing ample material for the reconstruction of past changes in atmospheric deposition. The highly organic (up to 99% in some cases) matrix of atmospherically fed mires, however, makes studying the actual dust particles (grain size, mineralogy) challenging. Here we explore some of the potentials and problems of using geochemical data from conservative, lithogenic elements (Al, Ga, Rb, Sc, Y, Zr, Th, Ti and REE) to build detailed dust records by using an example from the 8900-yr peat sequence from Store Mosse (the "Great Bog"), which is the largest mire complex in the boreo-nemoral region of southern Sweden. The four dust events recorded at this site were elementally distinct, suggesting different dominant mineral hosts. The oldest and longest event (6385-5300 cal yr BP) sees a clear signal of clay input but with increasing contributions of mica, feldspar and middle-REE- rich phosphate minerals over time. These clays are likely transported from a long-distance source (< 100 km). While dust deposition was reduced during the second event (5300-4370 cal yr BP), this is the most distinct in terms of its source character with [Eu/Eu*] UCC revealing the input of plagioclase feldspar from a local source, possibly active during this stormier period. The third (2380- 2200 cal yr BP) and fourth (1275-1080 cal yr BP) events are much shorter in duration and the presence of clays and heavy minerals is inferred. Elemental mass accumulation rates reflect these changes in mineralogy where the relative importance of the four dust events varies by element. The broad changes in major mineral hosts, grain size, source location and approximated net dust deposition rates observed in the earlier dust events of longer duration agree well with paleoclimatic changes observed in northern Europe. The two most recent dust events are much shorter in duration, which in combination with evidence of their local and regional character, may explain why they have not been seen elsewhere.
|
|
| 6. |
- Ranta, E., et al.
(författare)
-
Fluid-rock reactions in the 1.3Ga siderite carbonatite of the GrOnnedal-ika alkaline complex, Southwest Greenland
- 2018
-
Ingår i: Contributions to Mineralogy and Petrology. - : Springer Science and Business Media LLC. - 0010-7999 .- 1432-0967. ; 173:10
-
Tidskriftsartikel (refereegranskat)abstract
- Petrogenetic studies of carbonatites are challenging, because carbonatite mineral assemblages and mineral chemistry typically reflect both variable pressure-temperature conditions during crystallization and fluid-rock interaction caused by magmatic-hydrothermal fluids. However, this complexity results in recognizable alteration textures and trace-element signatures in the mineral archive that can be used to reconstruct the magmatic evolution and fluid-rock interaction history of carbonatites. We present new LA-ICP-MS trace-element data for magnetite, calcite, siderite, and ankerite-dolomite-kutnohorite from the iron-rich carbonatites of the 1.3Ga GrOnnedal-ika alkaline complex, Southwest Greenland. We use these data, in combination with detailed cathodoluminescence imaging, to identify magmatic and secondary geochemical fingerprints preserved in these minerals. The chemical and textural gradients show that a 55m-thick basaltic dike that crosscuts the carbonatite intrusion has acted as the pathway for hydrothermal fluids enriched in F and CO2, which have caused mobilization of the LREEs, Nb, Ta, Ba, Sr, Mn, and P. These fluids reacted with and altered the composition of the surrounding carbonatites up to a distance of 40m from the dike contact and caused formation of magnetite through oxidation of siderite. Our results can be used for discrimination between primary magmatic minerals and later alteration-related assemblages in carbonatites in general, which can lead to a better understanding of how these rare rocks are formed. Our data provide evidence that siderite-bearing ferrocarbonatites can form during late stages of calciocarbonatitic magma evolution.
|
|
| 7. |
- Sopher, Daniel
(författare)
-
Characterization of the structure, stratigraphy and CO2 storage potential of the Swedish sector of the Baltic and Hanö Bay basins using seismic reflection methods
- 2016
-
Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- An extensive multi-channel seismic dataset acquired between 1970 and 1990 by Oljeprospektering AB (OPAB) has recently been made available by the Geological Survey of Sweden (SGU). This thesis summarizes four papers, which utilize this largely unpublished dataset to improve our understanding of the geology and CO2 storage capacity of the Baltic and Hanö Bay basins in southern Sweden.A range of new processing workflows were developed, which typically provide an improvement in the final stacked seismic image, when compared to the result obtained with the original processing. A method was developed to convert scanned images of seismic sections into SEGY files, which allows large amounts of the OPAB dataset to be imported and interpreted using modern software. A new method for joint imaging of multiples and primaries was developed, which is shown to provide an improvement in signal to noise for some of the seismic lines within the OPAB dataset. For the first time, five interpreted regional seismic profiles detailing the entire sedimentary sequence within these basins, are presented. Depth structure maps detailing the Outer Hanö Bay area and the deeper parts of the Baltic Basin were also generated. Although the overall structure and stratigraphy of the basins inferred from the reprocessed OPAB dataset are consistent with previous studies, some new observations have been made, which improve the understanding of the tectonic history of these basins and provide insight into how the depositional environments have changed throughout time. The effective CO2 storage potential within structural and stratigraphic traps is assessed for the Cambrian Viklau, När and Faludden sandstone reservoirs. A probabilistic methodology is utilized, which allows a robust assessment of the storage capacity as well as the associated uncertainty. The most favourable storage option in the Swedish sector of the Baltic Basin is assessed to be the Faludden stratigraphic trap, which is estimated to have a mid case (P50) storage capacity of 3390 Mt in the deeper part of the basin, where CO2 can be stored in a supercritical phase.
|
|
| 8. |
- Hobiger, Thomas, 1978, et al.
(författare)
-
Software-Defined Radio Direct Correlation GNSS Reflectometry by Means of GLONASS
- 2016
-
Ingår i: IEEE Journal of Selected Topics in Applied Earth Observations and Remote Sensing. - 2151-1535 .- 1939-1404. ; 9:10, s. 4834-4842
-
Tidskriftsartikel (refereegranskat)abstract
- Ground-based GNSS reflectometry (GNSS-R)systems can be realized by different means. The concept ofcorrelation between direct and reflected GNSS signals is basicallypossible with all GNSS systems. However, using signals fromthe Russian GLONASS system simplifies the signal processingso that software-defined radio (SDR) components can be usedat replace expensive hardware solutions. This paper discusseshow such a solution, called GLONASS-R, can be realized usingentirely off-the-shelf components. Field tests with such a systemdemonstrate the capability to monitor sea surface heights with aprecision of 3 cm or better even with a sampling rate of 1.5 Hz.The flexibility of a SDR and the simple concept of GLONASS-Rallow build such a system with low costs and adapt it to the needsof any ground-based GNSS-R problem.
|
|
| 9. |
- Lages, J., et al.
(författare)
-
Volcanic Gas Emissions Along the Colombian Arc Segment of the Northern Volcanic Zone (CAS-NVZ): Implications for volcano monitoring and volatile budget of the Andean Volcanic Belt
- 2019
-
Ingår i: Geochemistry, Geophysics, Geosystems. - 1525-2027. ; 20:11, s. 5057-5081
-
Tidskriftsartikel (refereegranskat)abstract
- Studying spatial and temporal trends in volcanic gas compositions and fluxes is crucial both to volcano monitoring and to constrain the origin and recycling efficiency of volatiles at active convergent margins. New volcanic gas compositions and volatile fluxes are here reported for Nevado del Ruiz, Galeras, and Purace, three of the most persistently degassing volcanoes located in the Colombian Arc Segment of the Northern Volcanic Zone. At Nevado del Ruiz, from 2014 to 2017, plume emissions showed an average molar CO2/S-T ratio of 3.9 +/- 1.6 (S-T is total sulfur, S). Contemporary, fumarolic chemistry at Galeras progressively shifted toward low-temperature, S-depleted fumarolic gas discharges with an average CO2/S-T ratio in excess of 10 (6.0-46.0, 2014-2017). This shift in volcanic gas compositions was accompanied by a concurrent decrease in SO2 emissions, confirmed on 21 March 2017 by high-resolution ultraviolet camera-based SO2 fluxes of similar to 2.5 kg/s (similar to 213 t/day). For comparison, SO2 emissions remained high at Nevado del Ruiz (weighted average of 8 kg/s) between 2014 and 2017, while Purace maintained rather low emission levels (<1 kg/s of SO2, CO2/SO2 approximate to 14). We here estimate carbon dioxide fluxes for Nevado del Ruiz, Galeras, and Purace of similar to 23, 30, and 1 kg/s, respectively. These, combined with recent CO2 flux estimates for Nevado del Huila of similar to 10 kg/s (similar to 860 t/day), imply that this arc segment contributes about 50% to the total subaerial CO2 budget of the Andean Volcanic Belt. Furthermore, our work highlights the northward increase in carbon-rich sediment input into the mantle wedge via slab fluids and melts that is reflected in magmatic CO2/S-T values far higher than those reported for Southern Volcanic Zone and Central Volcanic Zone volcanoes. We estimate that about 20% (similar to 1.3 Mt C/year) of the C being subducted (similar to 6.19 Mt C/year) gets resurfaced through subaerial volcanic gas emissions in Colombia (Nevado del Ruiz similar to 0.7 Mt C/year). As global volcanic volatile fluxes continue to be quantified and refined, the contribution from this arc segment should not be underestimated.
|
|
| 10. |
- Salas Romero, Silvia
(författare)
-
Multidisciplinary Near-Surface Investigation of a Quick-Clay Landslide Prone Area in Southwest Sweden
- 2019
-
Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Quick-clay landslides are considered one of the most important geohazards in Sweden, Norway, and Canada. The deposits involved are glacial and postglacial clays and silty clays, which are very sensitive to increased stress that may collapse their structure and cause liquefaction.A multidisciplinary approach was adopted in this study of quick clays in an area of southwest Sweden that is prone to landslides. It was mainly based on geophysical methods, but was complemented and validated with geotechnical, geological, and hydrological data. Downhole geophysics, land and river reflection seismics, radio magnetotellurics, P-wave refraction tomography, magnetics, and multichannel analysis of surface waves comprised the main geophysical methods used in this research. Laboratory measurements of core samples, such as grain size analysis, mineral magnetic properties, fossil content, X-ray fluorescence, cation exchange capacity, X-ray powder diffraction, electrical conductivity, and pH were also taken. Hydrological modelling was used to obtain information on the properties of groundwater within a coarse-grained layer, given the importance of this information in the formation of quick clays.The evaluation of the physico-chemical properties of the coarse-grained layer revealed high values of magnetic susceptibility, probably as a result of fluvial sorting, which tends to accumulate denser minerals such as magnetite. Potential quick clays were visually observed above this layer, and their presence was also confirmed by geotechnical data acquired in previous studies. Marine fossils identified within the coarse-grained layer confirmed the glaciomarine origin of the clays. Geophysical results revealed the presence of large-scale structures, an undulating fractured bedrock and a coarse-grained layer sandwiched between clay deposits, with leached sediments on top and unleached sediments below. This layer, important for the development of quick clays in the area, was 3D modelled in a regional context. Magnetic data also revealed that the coarse-grained layer together with quick clays, have the potential to act as a sliding prone layer. Multichannel analysis of surface waves helped to geotechnically characterize the area. Although the results could not reach the deeper layers, it did yield information about the shallower layers of clay, silt and sand. The VS30 values indicated the presence of soft soils, as well as soft clays/silts with high plasticity index and high water content.This PhD is expected to improve the current knowledge of quick-clay landslides and how they are preconditioned. Climate change will probably affect the study area in the near future, most likely increasing landslide risk, therefore, research should continue and advance to new levels. Application of other geophysical methods such as borehole or geophysical monitoring, and induced polarization, could provide more information about the formation of quick clays and associated landslides.
|
|
