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In search of fully ...
In search of fully uncomplexed cyclodextrin in the presence of micellar aggregates
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- Cabaleiro-Lago, Celia (författare)
- Spanien
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- Garcia-Rio, L. (författare)
- Spanien
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- Herves, P. (författare)
- Spanien
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visa fler...
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- Mejuto, J. C. (författare)
- Spanien
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- Perez-Juste, J. (författare)
- Spanien
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visa färre...
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(creator_code:org_t)
- Univ Vigo, Fac Quim, Dept Quim Fis, Vigo 36310, Spain. Univ Santiago, Fac Quim, Dept Quim Fis, Santiago 15782, Spain. AMER CHEMICAL SOC, 2006
- 2006
- Engelska.
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Ingår i: Journal of Physical Chemistry B. - Univ Vigo, Fac Quim, Dept Quim Fis, Vigo 36310, Spain. Univ Santiago, Fac Quim, Dept Quim Fis, Santiago 15782, Spain. : AMER CHEMICAL SOC. - 1520-6106 .- 1520-5207. ; 110:32, s. 15831-15838
- Relaterad länk:
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https://doi.org/10.1...
Abstract
Ämnesord
Stäng
- The chemical behavior of beta-cyclodextrin/nonionic surfactant mixed systems has been investigated using the basic hydrolysis of N-methyl-N-nitroso-p-toluenesulfonamide as a chemical probe. The experimental results prove that at the cmc, there are significant quantities of uncomplexed beta-CD in equilibrium with the micellar aggregates. In contrast to the expected situation, the percentage of uncomplexed beta-CD in equilibrium with the micellar system increases on increasing the hydrophobicity of the surfactant molecule. This behavior is due to the existence of two simultaneous processes: complexation of surfactant monomers by cyclodextrin and the process of self-assembly to form micellar aggregates. The autoaggregation of surfactant monomers is expected to be more important than the complexation process in this mixed system. Varying the hydrophobicity of the surfactant monomer enabled us to determine that the percentages of uncomplexed cyclodextrin in equilibrium with the micellar system were in the range of 5-95%.
Ämnesord
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- Sodium dodecyl-sulfate
- surfactant inclusion complexes
- Beta-cyclodextrin
- basix hydrolysis
- binding constants
- dodecyl trimethylammonium bromide
- thermodynamic properties
- Alpha-cyclodextrins
- gemini surfactant
- aqueous-solutions
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)