Multielectron-Transfer Templates via Consecutive Two-Electron Transformations : Iron-Sulfur Complexes Relevant to Biological Enzymes

• [FeFe] hydrogenase mimics: Two polynuclear iron-sulfur complexes (1 and 2; see figure) were prepared and structurally characterized. They are potentially effective and stable multielectron-transfer relays for mediating four- and six-electron transformations via a cascade of reversible two-electron redox steps with relatively narrow potential spans.

Ämnesord

NATURVETENSKAP  -- Kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Nyckelord

electrochemistry

electron transfer

hydrogenase

iron complexes

Publikations- och innehållstyp

ref (ämneskategori)

art (ämneskategori)