The structural determination of endohedral metallofullerene Gd@C-82 by XANES

• Although the Gd ion in Gd@C-82 has been shown to lie above the C-C bond on the C-2 axis as an anomalous structure from the MEM/Rietveld analysis, the present XANES study reveals that it lies above the hexagon on the C-2 axis as a normal structure, and Gd oscillates around its equilibrium position with an amplitude increasing with temperature increase.

Ämnesord

NATURVETENSKAP  -- Kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Nyckelord

ABSORPTION FINE-STRUCTURE; POWDER DIFFRACTION; CAGE; CLUSTER; LA; DIMETALLOFULLERENE; SC-2-AT-C-84; EU-AT-C-82; MOTION; C-82

Chemistry

Kemi

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