Self-assembly of a heteropolyoxopalladate nanocube : [PdII 13AsV 8O34(OH)6] 8-

• (Chemical Equation Presented) Not like the others: A molecular palladium oxide cluster was formed by self-assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [Pd II 13AsV 8O34(OH) 6]8- has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four-coordinate square-planar geometry, in marked contrast to all other known discrete polyoxometalates.

Ämnesord

NATURVETENSKAP  -- Kemi -- Annan kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)

Nyckelord

Electrochemistry

Nanoclusters

Oxidation catalysis

Palladium

Polyoxometalates

Arsenic

Chemical reactions

Palladium compounds

Self assembly

Vanadium compounds

Chemical equations

Cubic shapes

Edge lengths

Mild reaction conditions

Palladium oxides

Planar geometries

arsenic acid derivative

nanoparticle

palladium oxide

tungsten derivative

tungstoarsenate

article

chemistry

conformation

particle size

Arsenates

Molecular Conformation

Nanoparticles

Tungsten Compounds

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