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Photocatalytic Wate...
Photocatalytic Water Oxidation by Molecular Assemblies Based on Cobalt Catalysts
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Zhou, Xu (författare)
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Li, Fei (författare)
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Li, Hua (författare)
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Zhang, Biaobiao (författare)
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Yu, Fengshou (författare)
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- Sun, Licheng (författare)
- KTH,Organisk kemi
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(creator_code:org_t)
- 2014-08-08
- 2014
- Engelska.
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Ingår i: ChemSusChem. - : Wiley. - 1864-5631 .- 1864-564X. ; 7:9, s. 2453-2456
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Chromophore-catalyst molecular assemblies towards visible light-driven water oxidation were synthesized by covalent integration of a light-harvesting complex [Ru(bpy)(3)](2+) (bpy= 2,2'-bipyridine) and a Co4O4 cubane water oxidation catalyst. The two components were assembled either in linear or macrocyclic configurations. In the presence of the sacrificial reagent, the Ru-Co metallocycle exhibits remarkable photocatalytic activity for oxygen evolution, which is one order of magnitude higher than that of a multicomponent system and exceeds that of a linear assembly by a factor of five, offering access to highly active photocatalyst through molecular design.
Ämnesord
- NATURVETENSKAP -- Kemi -- Annan kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)
Nyckelord
- cobalt
- cubanes
- homogeneous catalysis
- photocatalysis
- water splitting
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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