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Hydrogen generation...
Hydrogen generation from dimethyl ether for fuel cell auxiliary power units
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- Nilsson, Marita (författare)
- KTH,Kemiteknik
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- Pettersson, Lars J. (författare)
- KTH,Kemisk teknologi
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Lindström, Bard (författare)
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(creator_code:org_t)
- 2006-07-29
- 2006
- Engelska.
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Ingår i: Energy & Fuels. - : American Chemical Society (ACS). - 0887-0624 .- 1520-5029. ; 20:5, s. 2164-2169
- Relaterad länk:
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https://urn.kb.se/re...
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visa fler...
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https://doi.org/10.1...
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visa färre...
Abstract
Ämnesord
Stäng
- Copper-based catalysts have been evaluated for the combined partial oxidation and steam reforming of dimethyl ether (DME) in a reformer designed to produce hydrogen for a full-scale heavy-duty truck auxiliary power unit. The experiments were conducted using gas mixtures similar to realistic operating conditions. A Pd-promoted CuZn catalyst was found to be highly selective for hydrogen production from DME at O-2/DME = 0.25 and H2O/ DME = 2.5. The catalysts were characterized using Brunauer-Emmett-Teller surface area measurement, X-ray diffraction, and temperature-programmed reduction. The copper surface area was determined by pulse chemisorption of nitrous oxide. In addition to the reforming catalyst evaluation, a startup sequence was tested, where DME was catalytically ignited and combusted over platinum or iron oxide catalysts.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering (hsv//eng)
Nyckelord
- copper surface-area
- partial oxidation
- methanol
- catalysts
- decomposition
- dme
- hydrolysis
- pd/zno
- oxide
- Chemical engineering
- Kemiteknik
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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