Thin-film ZnO/CdS/CuIn1-xGaxSe2 solar cells : Anomalous physical properties of the CuIn1-xGaxSe2 absorber

• Thin-film ZnO/CdS/CuIn1-xGaxSe2 solar cells are manufactured with similar to 20% solar-cell conversion efficiency. The CuIn1-xGaxSe2 (CIGS) absorber exhibits rather different physical properties compared with conventional semiconductors (e.g. Si, GaAs and ZnSe). For instance, (i) the valence-band maximum in CIGS consists of cation-d-anion-p hybridized states. (ii) Cation vacancies have low formation energies and high mobility at room temperature. (iii) The most stable surface of CuIn1-xGaxSe2 is the reconstructed, and otherwise polar, (112) surface. (iv) Solar cells with absorbers containing grain-boundaries outperform cells with crystalline absorbers. In this work, the fundamental physical properties of CIGS, like the electronic structure, the defect formation energies, as well as surface properties are discussed from a theoretical perspective.

Subject headings

NATURVETENSKAP  -- Fysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences (hsv//eng)

Keyword

solar cells

photovoltaic

absorbers

CuInSe2

surface

interface

defects

grain-boundary

Publication and Content Type

ref (subject category)

art (subject category)