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Redox-responsive po...
Redox-responsive polymeric membranes via supermolecular host-guest interactions
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Shi, Wenbin (författare)
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Zhang, Linjun (författare)
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Deng, Jie (författare)
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Wang, Dongsheng (författare)
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Sun, Shudong (författare)
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- Zhao, Weifeng (författare)
- KTH,Fiber- och polymerteknologi,Sichuan University, China
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Zhao, Changsheng (författare)
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(creator_code:org_t)
- Elsevier BV, 2015
- 2015
- Engelska.
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Ingår i: Journal of Membrane Science. - : Elsevier BV. - 0376-7388 .- 1873-3123. ; 480, s. 139-152
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Redox-responsive materials have attracted much attention, and redox-responsive membrane is strongly desired since enormous numbers of redox reactions carry out in living systems. Herein, a novel polymeric membrane with redox-resposive hydraulic permeability is fabricated by introducing a reversible redox-responsive system based on the host guest complex between ferrocene (Fc) and beta-cyclodextrin (1 CD) into polyethersulfone (PES) membrane. As the result of reversible radox-responsive formation or deformation of the complex, the water flux for the membrane with 18.3 wt% redox-responsive materials was 270 mL/m(2) mmHg h in original state, while increased to 1022 mL/m(2) mmHg h in oxidation state and decreased to 538 mL/m(2) mmHg h in reduction state. In addition, the results of water contact angle, surface zeta potential and the gas flow/liquid displacement confirmed that the origin of the reclox-responsive hydraulic permeability were the change of the pore size and porosity for the modified membranes. The redox-responsive membranes have great potential to be utilized in the Fields of chemical detection, drug delivery, biological treatments and so On.
Ämnesord
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
Nyckelord
- Redox-responsibility
- Permeability
- Polyethersulfone membrane
- Ferrocene
- beta-cyclodextrin
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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