A model for mass transport in the electrolyte membrane of a DMFC

• A steady state model for multicomponent mass transport was derived for the direct methanol fuel cell membrane. Data for development and validation of the model was taken both from experiments and literature. The experimental data was collected in a polarisation cell, where mass transport of methanol across the electrolyte membrane was measured through a potentiostatic method. The results from modelling and experiments showed good agreement. The model was capable of describing the non-linear response in mass transport to increased methanol feed concentration. The model also accurately described the change in membrane conductivity with methanol concentration. From the model transport equations, it was also possible to derive some characteristic transport parameters, namely the electro osmotic drag of both water and methanol, diffusive drag of water and methanol, and effective, concentration dependent, diffusion coefficients for methanol and water.

Ämnesord

TEKNIK OCH TEKNOLOGIER  -- Kemiteknik (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Chemical Engineering (hsv//eng)

Nyckelord

direct methanol fuel cell

modelling

mass transport

methanol crossover

electrolyte membrane

methanol fuel-cell

proton-exchange membranes

open-circuit voltage

nafion membranes

diffusion-coefficient

ionomeric membranes

electroosmotic drag

water-uptake

performance

crossover

Chemical engineering

Kemiteknik

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