Development of bioplastics based on agricultural side-stream products : Film extrusion of Crambe abyssinica/wheat gluten blends for packaging purposes

• The purpose of this work was to add economic value to crambe meal, the protein-rich byproduct from the industrial extraction of Crambe abyssinica seed oil, by using it as a potential feedstock for oilseed meal-based plastics. The feasibility to produce continuous, flexible plastic films of glycerol-plasticized crambe meal blended with wheat gluten (WG) to improve extrudate properties and urea as a protein denaturant using extrusion was investigated. The effect of process parameters and blend composition were studied with regard to the extrusion performance and the film properties. Tensile properties and oxygen permeability were determined, and the film morphology was analyzed with scanning electron microscopy. A die temperature between 125 and 130°C resulted in films with the most homogeneous surfaces and highest tensile strength and extensibility. The use of compression molding after extrusion improved the surface quality and film strength and lowered the oxygen permeability. A decrease in the plasticizer content (from 30 to 20 wt %) improved the extrudability and showed the highest tensile strength, whereas the extensibility was essentially unaffected. The importance of the presence of WG was shown by the fact that strength and extensibility decreased when the crambe content was increased from 60 to 80 wt %. It was shown that crambe-based biopolymer blends could be extruded as continuous flexible plastic films that exhibited promising mechanical and oxygen barrier properties. The operational window was, however, found to be narrow. The results provide a first basis to further develop the process and the blend toward industrial applications, for example, as packaging materials.

Ämnesord

TEKNIK OCH TEKNOLOGIER  -- Kemiteknik -- Polymerteknologi (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Chemical Engineering -- Polymer Technologies (hsv//eng)

TEKNIK OCH TEKNOLOGIER  -- Materialteknik (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Materials Engineering (hsv//eng)

LANTBRUKSVETENSKAPER  -- Lantbruksvetenskap, skogsbruk och fiske -- Jordbruksvetenskap (hsv//swe)

AGRICULTURAL SCIENCES  -- Agriculture, Forestry and Fisheries -- Agricultural Science (hsv//eng)

Nyckelord

Biopolymers and renewable polymers

Blends

Extrusion

Molding

Packaging

Biomolecules

Biopolymers

Blending

Compression molding

Extrusion molding

Oils and fats

Oxygen

Oxygen permeable membranes

Packaging materials

Plastic films

Polymer blends

Proteins

Reinforced plastics

Scanning electron microscopy

Urea

Homogeneous surfaces

Industrial extraction

Operational windows

Oxygen barrier properties

Oxygen permeability

Potential feedstock

Process parameters

Protein denaturant

Tensile strength

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