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Microwave synthesis...
Microwave synthesis of Y2O3:Eu3+ nanophosphors : A study on the influence of dopant concentration and calcination temperature on structural and photoluminescence properties
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- Khachatourian, Malek Adrine (författare)
- KTH,Material- och nanofysik,Iran University of Science and Technology, Iran
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Golestani-Fard, F. (författare)
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Sarpoolaky, H. (författare)
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- Vogt, Carmen (författare)
- KTH,Biomedicinsk fysik och röntgenfysik
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- Vasileva, Elena (författare)
- KTH,Optik och Fotonik, OFO
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- Mensi, Mounir (författare)
- KTH,Material- och nanofysik
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- Popov, Sergei (författare)
- KTH,Optik och Fotonik, OFO
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- Toprak, Muhammet S. (författare)
- KTH,Funktionella material, FNM
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(creator_code:org_t)
- Elsevier BV, 2016
- 2016
- Engelska.
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Ingår i: Journal of Luminescence. - : Elsevier BV. - 0022-2313 .- 1872-7883. ; 169, s. 1-8
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Red fluorescent emitting monodispersed spherical Y2O3 nanophosphors with different Eu3+ doping concentrations (0-13 mol%) are synthesized by a novel microwave assisted urea precipitation, which is recognized as a green, fast and reproducible synthesis method. The effect of Eu3+ doping and calcination temperature on the structural characteristics and luminescence properties of particles is investigated in detail. The as prepared powders have (Y,Eu)(OH)(CO3) structure which converts to Y2O3:Eu3+ from 500 °C and become crystalline at higher temperatures. The crystallite size of nanophosphors increased from 15 nm to 25 nm as the calcination temperature increased from 700 °C to 1050 °C. The efficient incorporation of Eu3+ ions in cubic Y2O3 host matrix is confirmed by the calculated X-ray Powder diffraction (XRPD) structural parameters. The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) micrographs show that the as obtained and calcined particles are spherical, monodispersed and non-agglomerated. The overall size of particles increases from 61±8 nm to 86±9 nm by increasing Eu3+ concentration from 0 mol% to 13 mol%. High resolution TEM revealed polycrystalline nature of calcined particles. The particles exhibit a strong red emission under ultraviolet (UV) excitation. The photoluminescence (PL) intensity of the peaks increases proportionally with Eu3+ concentration and the calcination temperature with no luminescence quenching phenomenon observed even for Y2O3:13%Eu3+. The fluorescent emission properties combined with the monodispersity and narrow size distribution characteristics make the Y2O3:Eu3+ heavy metal free nanophosphors applicable in fluorescence cell imaging and as fluorescence biolabels.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Nanoteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Nano-technology (hsv//eng)
Nyckelord
- Chemical synthesis
- Luminescence
- Microstructure
- Optical properties
- Phosphors
- Rare earth compounds
- Calcination
- Chemical compounds
- Crystallite size
- Electron microscopy
- Fluorescence
- Heavy metals
- High resolution transmission electron microscopy
- Light emission
- Photoluminescence
- Powder metals
- Scanning electron microscopy
- Structural properties
- Synthesis (chemical)
- Transmission electron microscopy
- Urea
- X ray powder diffraction
- Calcination temperature
- Luminescence properties
- Luminescence quenching
- Narrow size distributions
- Photoluminescence intensities
- Photoluminescence properties
- Structural characteristics
- Ultraviolet excitations
- Europium
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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