Effects of biological treatment on the chemical structure of dissolved lignin-related substances in effluent from thermomechanical pulping

• Effluent from a TMP-based pulp and paper mill was collected at the inlet and outlet of the mill's biological treatment plant and fractionated by sorption on XAD-8 resin and MTBE precipitation. Fractionation indicated that the refractory dissolved organic material in biologically treated effluent was mainly composed of lignin-related substances. Characterisation of the lignin-related substances by chromatographic and spectrometric methods confirmed the similarities of the isolated material and milled wood lignin. Fractionation and characterisation of alkali-extracted material from solids (biosludge) in biologically treated effluent found evidence of lignin-related material. Results indicated that biological treatment had altered the chemical structure and molar-mass distribution of dissolved lignin-related substances.

Nyckelord

wastewater treatment

biodegradability

thermomechanical pulping

lignin

COD

chromatography

spectrometry

thermally assisted hydrolysis

paper-mill

waste-water

self-diffusion

spectrometry

pyrolysis

removal

wood

Publikations- och innehållstyp

ref (ämneskategori)

art (ämneskategori)