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Electrocatalytic wa...
Electrocatalytic water oxidation by a macrocyclic Cu(II) complex in neutral phosphate buffer
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Yu, Fengshou (författare)
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Li, Fei (författare)
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Hu, Jixiang (författare)
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Bai, Lichen (författare)
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Zhu, Yong (författare)
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- Sun, Licheng, 1962- (författare)
- KTH,Kemi
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(creator_code:org_t)
- 2016
- 2016
- Engelska.
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Ingår i: Chemical Communications. - : Royal Society of Chemistry. - 1359-7345 .- 1364-548X. ; 52:68, s. 10377-10380
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- A single-site copper complex, [Cu(TMC)(H2O)](NO3)(2) (1, TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), was found to be the most active copper-based catalyst towards electrocatalytic water oxidation in neutral aqueous solution. Complex 1 leads to a cathodic shift of approximately 200 mV in potential to reach a current density of 1 mA cm(-2) in comparison with that of the previously reported dinuclear copper complex under the same conditions. Upon immobilization of complex 1 on carbon cloth, it shows greatly improved activity than other copper-based WOCs including CuOx and Cu2+.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
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- art (ämneskategori)
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