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Efficient molecular...
Efficient molecular ruthenium catalysts containing anionic ligands for water oxidation
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Lu, Zhongkai (författare)
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Gao, Yan (författare)
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Chen, Hong (författare)
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Liu, Zhao (författare)
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Chen, Lifang (författare)
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- Sun, Licheng (författare)
- KTH,Organisk kemi,Dalian University of Technology (DUT), China
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(creator_code:org_t)
- 2016
- 2016
- Engelska.
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Ingår i: DALTON TRANSACTIONS. - : Royal Society of Chemistry. - 1477-9226 .- 1477-9234. ; 45:46, s. 18459-18464
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Two new mononuclear Ru complexes RuII(bipa)(pic) 3 (1; H(2)bipa = 6-(1H-benzo[d] imidazol-2-yl) picolinic acid, pic = 4-picoline) and RuII(pbic)(pic) 3 (2; H(2)pbic = 2-(pyridin-2-yl)-1H-benzo[d]imidazole-7-carboxylic acid, pic = 4-picoline) based on anionic ligands were successfully synthesized, and characterized using NMR spectroscopy, mass spectrometry, and X-ray crystallography. These catalysts showed high activities and stabilities in water oxidation in homogeneous systems with a high turnover number of 2100 and a turnover frequency of 0.21 s(-1) for complex 1. The O-O band formation mechanism involved water nucleophilic attack. An active catalytic intermediate, i.e., RuIV-OH, was detected using high-resolution mass spectrometry.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
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- art (ämneskategori)
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