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Electrochemical and...
Electrochemical and Spectroscopic Study of Homo- and Hetero-Dimetallic Phthalocyanines as Catalysts for the Oxygen Reduction Reaction in Acidic Media
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- Wang, Xiaojiang (author)
- Zhejiang Univ, Zhejiang Prov Key Lab Adv Chem Engn Mfg Technol, Coll Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China.
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- Liu, Yang (author)
- Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China.
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- Wang, Ying (author)
- KTH,Teoretisk kemi och biologi
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- Ren, Rong (author)
- Zhejiang Univ, Zhejiang Prov Key Lab Adv Chem Engn Mfg Technol, Coll Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China.
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- Chen, Hengquan (author)
- Zhejiang Univ, Zhejiang Prov Key Lab Adv Chem Engn Mfg Technol, Coll Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China.
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- Jiang, Zheng (author)
- Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China.
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- He, Qinggang (author)
- Zhejiang Univ, Zhejiang Prov Key Lab Adv Chem Engn Mfg Technol, Coll Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China.
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Zhejiang Univ, Zhejiang Prov Key Lab Adv Chem Engn Mfg Technol, Coll Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China. (creator_code:org_t)
- 2018-09-19
- 2018
- English.
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In: ChemElectroChem. - : WILEY-V C H VERLAG GMBH. - 2196-0216. ; 5:22, s. 3478-3485
- Related links:
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Abstract
Subject headings
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- Metallophthalocyanines (MPc, M=Fe or Co) have been investigated extensively as a typical type of transition metal macrocyclic catalysts for the oxygen reduction reaction (ORR). However, the understanding about ORR catalyzed by binuclear even heterodimetallic phthalocyanines in acidic condition is still not sufficient. Herein we synthesized two homodimetallicphthalocyanine (FePc-PcFe and CoPc-PcCo) and a heterodimetallic phthalocyanine (FePc-PcCo). The electrocatalytic activity of as-synthesized compounds were characterized by cyclic voltammetry (CV) and rotating disk electrode (RDE). Generally, the binuclear metallophthalocyanines show higher activity than their monomeric analogues including FePc and CoPc. Also, the Fe compounds exhibit better catalytic performance than the Co phthalocyanines. However, interestingly the heterodimetallic phthalocyanine FePc-PcCo shows similar half-wave potential and ORR activity with FePc-PcFe, rather than CoPc-PcCo. This may be explained by XPS and XAS, which reveal a similar square-planar structure existed in FePc-PcCo and FePc-PcFe and a non-planar structure in CoPc-PcCo. Furthermore, the increasing of the ORR activity among those five catalysts is well in agreement with the descending LUMO energies in DFT calculations. A lower LUMO energy indicates a favorable adsorption of O-2, which in turn affects the ORR performance.
Subject headings
- NATURVETENSKAP -- Kemi -- Teoretisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)
Keyword
- density functional calculations
- electrochemistry
- heterodimetallic phthalocyanines
- oxygen reduction reaction
- X-ray absorption spectroscopy
Publication and Content Type
- ref (subject category)
- art (subject category)
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