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Solid emission colo...
Solid emission color tuning of organic charge transfer cocrystals based on planar π-conjugated donors and TCNB
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- Khan, A. (författare)
- Southeast Univ, Natl Demonstrat Ctr Expt Biomed Engn Educ, State Key Lab Bioelect, Nanjing, Jiangsu, Peoples R China
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- Liu, M. (författare)
- Southeast Univ, Natl Demonstrat Ctr Expt Biomed Engn Educ, State Key Lab Bioelect, Nanjing, Jiangsu, Peoples R China
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- Usman, R. (författare)
- Southeast Univ, Natl Demonstrat Ctr Expt Biomed Engn Educ, State Key Lab Bioelect, Nanjing, Jiangsu, Peoples R China
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- He, N. (författare)
- Southeast Univ, Natl Demonstrat Ctr Expt Biomed Engn Educ, State Key Lab Bioelect, Nanjing, Jiangsu, Peoples R China; Hunan Univ Technol, Hunan Key Lab Biomed Nanomat & Devices, Econ Forest Cultivat & Utilizat Collaborat Innova, Zhuzhou, Peoples R China
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- Li, R. (författare)
- Taizhou Univ, Sch Pharmaceut Chem & Mat Engn, Taizhou, Zhejiang, Peoples R China
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- Sayed, S. M. (författare)
- Southeast Univ, Natl Demonstrat Ctr Expt Biomed Engn Educ, State Key Lab Bioelect, Nanjing, Jiangsu, Peoples R China
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- Li, S. (författare)
- Southeast Univ, Sch Mat Sci & Engn, Jiangsu Key Lab Adv Metall Mat, Nanjing, Jiangsu, Peoples R China
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- Sun, Weiwei (författare)
- Uppsala universitet,KTH,Materialvetenskap,Materialteori,KTH Royal Inst Technol, Dept Mat Sci & Engn, Stockholm, Sweden
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- Chen, H. (författare)
- Hunan Univ Technol, Hunan Key Lab Biomed Nanomat & Devices, Econ Forest Cultivat & Utilizat Collaborat Innova, Zhuzhou, Peoples R China
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- Zhang, L. (författare)
- Taizhou Univ, Sch Pharmaceut Chem & Mat Engn, Taizhou, Zhejiang, Peoples R China
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- Qiu, L. (författare)
- Taizhou Univ, Sch Pharmaceut Chem & Mat Engn, Taizhou, Zhejiang, Peoples R China
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- Tang, T. (författare)
- Taizhou Univ, Sch Pharmaceut Chem & Mat Engn, Taizhou, Zhejiang, Peoples R China
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(creator_code:org_t)
- Academic Press, 2019
- 2019
- Engelska.
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Ingår i: Journal of Solid State Chemistry. - : Academic Press. - 0022-4596 .- 1095-726X. ; 272, s. 96-101
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Ämnesord
Stäng
- Two luminescent Charge Transfer (CT) cocrystals involving planar phenanthrene derivatives namely, formyl phenanthrene (FP) and acetyl phenanthrene (AP) as donors (D) and 1,2,4,5-tetracyanobenzene (TCNB) as an acceptor (A) building block, are formed by molecular self-assembly. Detailed structural and spectroscopic measurements elucidated the mixed stack sequence DADAD in the CT cocrystals. The solid supramolecular architecture for both the cocrystals forms 2D sheet, supported by the extended network of C-H···O, and C-H···N hydrogen bonds as evidenced by the crystallographic observation. Interestingly, the two cocrystals display tunable emissions compared to the blue emissions of donor compounds, which correlate with the formation of excited CT state between the donor and acceptor motifs as a result of mixed stack orientation. The nature of the CT interactions in the two cocrystals was further explored by applying density functional theoretical (DFT) studies. Such a supramolecular cocrystal approach provides a facile platform towards the design of new luminescent two component CT complexes with desired functionalities.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
- MEDICIN OCH HÄLSOVETENSKAP -- Hälsovetenskap -- Annan hälsovetenskap (hsv//swe)
- MEDICAL AND HEALTH SCIENCES -- Health Sciences -- Other Health Sciences (hsv//eng)
Nyckelord
- Hirshfeld surface analysis
- Mixed stacking
- Phenanthrene derivatives
- Photophysical properties
- density functional calculations
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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Till lärosätets databas
- Av författaren/redakt...
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Khan, A.
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Liu, M.
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Usman, R.
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He, N.
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Li, R.
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Sayed, S. M.
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visa fler...
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Li, S.
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Sun, Weiwei
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Chen, H.
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Zhang, L.
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Qiu, L.
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Tang, T.
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visa färre...
- Om ämnet
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- NATURVETENSKAP
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NATURVETENSKAP
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och Kemi
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- MEDICIN OCH HÄLSOVETENSKAP
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MEDICIN OCH HÄLS ...
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och Hälsovetenskap
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och Annan hälsoveten ...
- Artiklar i publikationen
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Journal of Solid ...
- Av lärosätet
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Kungliga Tekniska Högskolan
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Uppsala universitet