Surface-Supported Metal-Organic Framework Thin-Film-Derived Transparent CoS 1.097 @N-Doped Carbon Film as an Efficient Counter Electrode for Bifacial Dye-Sensitized Solar Cells

• An effective design for counter electrode (CE) catalytic materials with superior catalytic activity, excellent stability, low cost, and a facile fabrication process is urgently needed for industrialization of dye-sensitized solar cells (DSSCs). Herein, we report a facile in situ method to fabricate transparent CoS 1.097 anchored on an N-doped carbon film electrode through sulfurization of a cobalt-metalloporphyrin metal-organic framework thin film on fluorine-doped tin oxide glass. The transparent film as counter electrode in bifacial DSSCs exhibited higher power conversion efficiency (9.11% and 6.64%), respectively, from front and rear irradiation than that of Pt (8.04% and 5.87%). The uniformly dispersed CoS 1.097 nanoparticles on an N-doped carbon film provide a large catalytic active area and facilitate the electron transfer, which leads to the excellent catalytic ability of the CoS 1.097 @N-doped carbon film. In addition, the in situ preparation of the uniform film with a nanosheet structure offers high electrical conductivity and unobstructed access for the diffusion of triiodide to available electroactive sites, resulting in excellent device performance with superior long-term stability over 1000 h under natural conditions.

Ämnesord

NATURVETENSKAP  -- Kemi -- Materialkemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Materials Chemistry (hsv//eng)

Nyckelord

CoS 1.097 @N-doped carbon film

counter electrode

dye-sensitized solar cells

electrocatalysis

metal-organic framework thin films

SURMOF

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