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Spray-coated nanoce...
Spray-coated nanocellulose based separator/electrode assembly
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- Kim, Hyeyun, 1986- (författare)
- KTH,Wallenberg Wood Science Center
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- Moser, Carl, 1987- (författare)
- KTH,Träkemi och massateknologi
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- Mattinen, Ulriika (författare)
- KTH,Tillämpad elektrokemi,Åbo Akademi
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visa fler...
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- Henriksson, Gunnar (författare)
- KTH,Fiber- och polymerteknologi
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- Lindström, Rakel, 1973- (författare)
- KTH,Tillämpad elektrokemi
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- Lindbergh, Göran, 1959- (författare)
- KTH,Tillämpad elektrokemi
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- Cornell, Ann M., 1962- (författare)
- KTH,Tillämpad elektrokemi,Wallenberg Wood Science Center
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visa färre...
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(creator_code:org_t)
- Engelska.
- Relaterad länk:
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https://urn.kb.se/re...
Abstract
Ämnesord
Stäng
- A separator-electrode assembly (SEA) made of wood-based cellulose nanofibers (CNF) and Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) was fabricated by a facile spray-coating process. CNF building blocks were prepared by homogenizing enzymatically pretreated cellulose fibers dispersed in a non-hazardous solvent, 2-propanol (IPA). The porous composite separator was made by spray-coating thin layers CNF-IPA, followed by a PVDF-HFP spray coating, on a lithium ion battery electrode. A CNF substrate was crucial for making a highly porous and thermally stable separator and PVDF-HFP coating enhanced its mechanical stability. The SEA maintained dimensional integrity when subjected to high temperature and when used in lithium ion batteries. A CNF-LiNi1/3Co1/3Mn1/3O2 (NMC) SEA showed excellent electrochemical stability, especially at fast charging/discharging rate, whereas a graphite counterpart showed poor electrochemical performance, resulting in cell failure. A SiO2 layer overcoated on the top of CNF-NMC SEA enabled its application for a proof-of-concept lithium metal battery and for a high energy‐density LiNi0.6Co0.2Mn0.2O2 (NMC622) lithium‐ion battery with excellent electrochemical stability and performances. The utilization of biodegradable materials and non-hazardous solvents such as IPA and acetone makes the development of the CNF based SEA attractive, as an eco-friendly lithium ion battery manufacturing process.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering (hsv//eng)
Nyckelord
- Energy Technology
- Energiteknik
Publikations- och innehållstyp
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- Av författaren/redakt...
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Kim, Hyeyun, 198 ...
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Moser, Carl, 198 ...
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Mattinen, Ulriik ...
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Henriksson, Gunn ...
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Lindström, Rakel ...
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Lindbergh, Göran ...
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visa fler...
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Cornell, Ann M., ...
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visa färre...
- Om ämnet
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- TEKNIK OCH TEKNOLOGIER
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TEKNIK OCH TEKNO ...
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och Kemiteknik
- Av lärosätet
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Kungliga Tekniska Högskolan