Sökning: id:"swepub:oai:DiVA.org:kth-26818" >
Domino Carbopallada...
Domino Carbopalladation-Carbonylation : Generating Quaternary Stereocenters while Controlling beta-Hydride Elimination
-
- Seashore-Ludlow, Brinton (författare)
- KTH,Organisk kemi
-
Somfai, Peter (författare)
-
(creator_code:org_t)
- 2010-08-05
- 2010
- Engelska.
-
Ingår i: Organic Letters. - : American Chemical Society (ACS). - 1523-7060 .- 1523-7052. ; 12:17, s. 3732-3735
- Relaterad länk:
-
https://urn.kb.se/re...
-
visa fler...
-
https://doi.org/10.1...
-
visa färre...
Abstract
Ämnesord
Stäng
- A domino carbopalladation-carbonylation sequence for substrates possessing beta-hydrogens is explored. This allows for the construction of complex architectures with vicinal stereocenters in a concise and rapid fashion via the stereocontrolled formation of two carbon carbon bonds. An integral aspect of this domino reaction is the ability to control beta-hydride elimination of the organopalladium intermediate and instead form the carbonylation product.
Ämnesord
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Nyckelord
- Organic chemistry
- Organisk kemi
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
Hitta via bibliotek
Till lärosätets databas