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Engineering Lattice...
Engineering Lattice Oxygen Activation of Iridium Clusters Stabilized on Amorphous Bimetal Borides Array for Oxygen Evolution Reaction
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- Wang, C. (författare)
- State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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- Zhai, P. (författare)
- State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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- Xia, M. (författare)
- State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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- Wu, Y. (författare)
- State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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- Zhang, B. (författare)
- State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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- Li, Z. (författare)
- State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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- Ran, L. (författare)
- State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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- Gao, J. (författare)
- State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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- Zhang, X. (författare)
- State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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- Fan, Z. (författare)
- State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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- Sun, Licheng, 1962- (författare)
- KTH,Organisk kemi,State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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- Hou, J. (författare)
- State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P. R. China
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State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, 2, Linggong Road, Dalian, 116024 P R. China Organisk kemi (creator_code:org_t)
- 2021-11-17
- 2021
- Engelska.
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Ingår i: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 60:52, s. 27126-27134
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Developing robust oxygen evolution reaction (OER) catalysts requires significant advances in material design and in-depth understanding for water electrolysis. Herein, we report iridium clusters stabilized surface reconstructed oxyhydroxides on amorphous metal borides array, achieving an ultralow overpotential of 178 mV at 10 mA cm−2 for OER in alkaline medium. The coupling of iridium clusters induced the formation of high valence cobalt species and Ir–O–Co bridge between iridium and oxyhydroxides at the atomic scale, engineering lattice oxygen activation and non-concerted proton-electron transfer to trigger multiple active sites for intrinsic pH-dependent OER activity. The lattice oxygen oxidation mechanism (LOM) was confirmed by in situ 18O isotope labeling mass spectrometry and chemical recognition of negative peroxo-like species. Theoretical simulations reveal that the OER performance on this catalyst is intrinsically dominated by LOM pathway, facilitating the reaction kinetics. This work not only paves an avenue for the rational design of electrocatalysts, but also serves the fundamental insights into the lattice oxygen participation for promising OER application.
Ämnesord
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Nyckelord
- electrocatalytic water splitting
- iridium clusters
- lattice oxygen oxidation mechanism
- metal borides
- oxygen evolution reaction
- Alkalinity
- Chemical activation
- Cobalt compounds
- Iridium compounds
- Mass spectrometry
- Oxygen
- Reaction kinetics
- Electrocatalytic
- Lattice oxygen
- Metal boride
- Oxidation mechanisms
- Oxygen activations
- Water splitting
- ]+ catalyst
- Electrocatalysts
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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Till lärosätets databas
- Av författaren/redakt...
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Wang, C.
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Zhai, P.
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Xia, M.
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Wu, Y.
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Zhang, B.
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Li, Z.
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Ran, L.
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Gao, J.
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Zhang, X.
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Fan, Z.
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Sun, Licheng, 19 ...
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Hou, J.
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