Application of 19F NMR spectroscopy to the study of equilibrium dynamics of uranyl(2+)‐fluoride complexes

• One‐ and two‐dimensional magnetization‐transfer 19F NMR methods were applied in a quantitative study of the fluoride exchange for uranyl(2+)‐fluoride complexes in aqueous solution. The applicability of these techniques and the classical lineshape analysis is discussed, and the quality of the results (rate constants and relaxation rates) obtained by the three methods is compared.

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NATURVETENSKAP  -- Kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

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