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Composites of Silk ...
Composites of Silk Nanofibrils and Metal-Organic Framework Nanosheets for Fluorescence-Based Sensing and UV Shielding
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- Hu, Yanlei (författare)
- KTH,Glykovetenskap,Wallenberg Wood Science Center,Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Key Lab of Biomass-Based Green Fuel & Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China;
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- Tan, Fangchang (författare)
- KTH,Glykovetenskap,Albanova VinnExcellence Center for Protein Technology, ProNova
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- Wang, Shennan, Dr. 1992- (författare)
- KTH,Glykovetenskap
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- Berglund, Lars, 1956- (författare)
- KTH,Wallenberg Wood Science Center,Fiber- och polymerteknologi
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- Fan, Yimin (författare)
- Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Key Lab of Biomass-Based Green Fuel & Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
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- Zhou, Qi (författare)
- KTH,Glykovetenskap
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(creator_code:org_t)
- 2023-03-27
- 2023
- Engelska.
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Ingår i: ACS Applied Nano Materials. - : American Chemical Society. - 2574-0970. ; 6:7, s. 6046-6055
- Relaterad länk:
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https://doi.org/10.1...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Silk fibroin, a widely used natural biopolymer, presents remarkable flexibility and biodegradability, making it of great interest as a polymer matrix for functional composite materials. Herein, composites of silk nanofibrils and metal-organic framework (MOF) nanosheets were successfully fabricated by a coincubation and coassembly process. Under heat incubation, silk fibroin self-assembled into one-dimensional nanofibrils, while MOF nanosheets simultaneously covered or wrapped on the silk nanofibrils in a water suspension. Transparent composite membranes were obtained from their water suspensions by the solution casting method. The regenerated silk nanofibrils formed a network structure, and the integrated MOF nanosheets (0.1 to 3.0 wt %) endowed the composites with aggregation-induced emission luminogen (AIEgen)-based fluorescence. The fluorescence intensity of the composites was significantly enhanced owing to the interfacial interactions between silk nanofibrils and MOF nanosheets. The composite membranes also offer excellent UV shielding while maintaining optical transparency in the visible spectrum. This work provides an efficient pathway to fabricate luminescent silk protein-based composites for functional materials such as fluorescence sensing and anticounterfeiting.
Ämnesord
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Kompositmaterial och -teknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Composite Science and Engineering (hsv//eng)
- NATURVETENSKAP -- Biologi -- Biokemi och molekylärbiologi (hsv//swe)
- NATURAL SCIENCES -- Biological Sciences -- Biochemistry and Molecular Biology (hsv//eng)
Nyckelord
- aggregation-induced emission
- composite
- metal−organic framework nanosheet
- silk nanofibril
- UV shielding
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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