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Multi-functional Ni...
Multi-functional NiS2/FeS2/N-doped carbon nanorods derived from metal-organic frameworks with fast reaction kinetics for high performance overall water splitting and lithium-ion batteries
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- Wang, Shangdai (författare)
- Shanghai Univ, Peoples R China
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- Ning, Ping (författare)
- Shanghai Univ, Peoples R China
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- Huang, Shoushuang (författare)
- Shanghai Univ, Peoples R China
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- Wang, Wenwen (författare)
- Shanghai Univ, Peoples R China
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- Fei, Siming (författare)
- Shanghai Univ, Peoples R China
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- He, Qingquan (författare)
- Shanghai Univ, Peoples R China
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- Zai, Jiantao (författare)
- Shanghai Jiao Tong Univ, Peoples R China
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- Jiang, Yong (författare)
- Shanghai Univ, Peoples R China
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- Hu, Zhang-Jun (författare)
- Linköpings universitet,Molekylär ytfysik och nanovetenskap,Tekniska fakulteten,Shanghai Univ, Peoples R China
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- Qian, Xuefeng (författare)
- Shanghai Jiao Tong Univ, Peoples R China
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- Chen, Zhiwen (författare)
- Shanghai Univ, Peoples R China
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(creator_code:org_t)
- ELSEVIER, 2019
- 2019
- Engelska.
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Ingår i: Journal of Power Sources. - : ELSEVIER. - 0378-7753 .- 1873-2755. ; 436
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- The development of cost-effective, highly efficient and robust multi-functional electrode materials can dramatically reduce the overall cost of electrochemical devices. We here report the controlled synthesis of NiS2/FeS2 nanoparticles encapsulated in N-doped carbon nanorods (NiS2/FeS2/NC) through carbonization and sulfurization of Fe/Ni-based bimetallic metal-organic frameworks. Benefiting from both structural and compositional characteristics, the resulting NiS2/FeS2/NC nanorods possess abundant active sites, high electrical conductivity and rapid mass transfer, thereby delivering 10 and 20 mA cm(-2) at overpotential of 172 mV and 231 mV towards the hydrogen evolution reaction and oxygen evolution reaction with robust stability in 1.0 M KOH solution, respectively. When employed as a bifunctional electrocatalyst for overall water splitting, it requires only 1.58 V to deliver a current density of 10 mA cm(-2) in 1.0 M KOH, outperforming that of the commercial Pt/C parallel to RuO2. Additionally, lithium-ion batteries tests also show high reversible capacity (718 mA h g(-1) at 100 mA g(-1)) and excellent cycling stability and rate performance. The work in this paper not only provides a promising strategy for designing efficient multi-functional electrode materials with similar morphology and structure, but also can be extended to the synthesis of other mixed metal sulfides for energy conversion and storage.
Ämnesord
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Nyckelord
- Metal-organic frameworks; Sulfide; Water splitting; Lithium-ion batteries; Energy storage
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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Till lärosätets databas
- Av författaren/redakt...
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Wang, Shangdai
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Ning, Ping
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Huang, Shoushuan ...
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Wang, Wenwen
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Fei, Siming
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He, Qingquan
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visa fler...
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Zai, Jiantao
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Jiang, Yong
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Hu, Zhang-Jun
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Qian, Xuefeng
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Chen, Zhiwen
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visa färre...
- Om ämnet
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- NATURVETENSKAP
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NATURVETENSKAP
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och Kemi
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och Materialkemi
- Artiklar i publikationen
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Journal of Power ...
- Av lärosätet
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Linköpings universitet