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Electronic structur...
Electronic structure of thin film iron-tetracyanoethylene : Fe(TCNE)x
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- Bhatt, Pramod (författare)
- Linköpings universitet,Ytors Fysik och Kemi,Tekniska högskolan
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- Carlegrim, Elin (författare)
- Linköpings universitet,Ytors Fysik och Kemi,Tekniska högskolan
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- Kanciurzewska, A (författare)
- Adam Mickiewicz University Poznan
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- de Jong, M. P. (författare)
- University of Twente
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- Fahlman, Mats (författare)
- Linköpings universitet,Ytors Fysik och Kemi,Tekniska högskolan
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(creator_code:org_t)
- 2009-04-01
- 2009
- Engelska.
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Ingår i: Applied Physics A. - : Springer Science and Business Media LLC. - 0947-8396 .- 1432-0630. ; 95:1, s. 131-138
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Thin film iron-tetracyanoethylene Fe(TCNE) x , x∼2, as determined by photoelectron spectroscopy, was grown in situ under ultra-high vacuum conditions using a recently developed physical vapor deposition-based technique for fabrication of oxygen- and precursor-free organic-based molecular magnets. Photoelectron spectroscopy results show no spurious trace elements in the films, and the iron is of Fe2+ valency. The highest occupied molecular orbital of Fe(TCNE) x is located at ∼1.7 eV vs. Fermi level and is derived mainly from the TCNE− singly occupied molecular orbital according to photoelectron spectroscopy and resonant photoelectron spectroscopy results. The Fe(3d)-derived states appear at higher binding energy, ∼4.5 eV, which is in contrast to V(TCNE)2 where the highest occupied molecular orbital is mainly derived from V(3d) states. Fitting ligand field multiplet and charge transfer multiplet calculations to the Fe L-edge near edge X-ray absorption fine structure spectrum yields a high-spin Fe2+ (3d6) configuration with a crystal field parameter 10Dq∼0.6 eV for the Fe(TCNE) x system. We propose that the significantly weaker Fe-TCNE ligand interaction as compared to the room temperature magnet V(TCNE)2 (10Dq∼2.3 eV) is a strongly contributing factor to the substantially lower magnetic ordering temperature (T C ) seen for Fe(TCNE) x -type magnets.
Nyckelord
- NATURAL SCIENCES
- NATURVETENSKAP
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