• Anisotropic deformation of colloidal particles was investigated under ion irradiation with 4 MeV Cu ions. In this study, 0.5 mu m-diameter colloidal silica particles, 0.5 mu m-diameter Au-silica core-shell particles, and 15 nm-diameter Au colloids embedding in a planar Si/SiO2 matrix were irradiated with 4 MeV Cu ions at room temperature and normal incidence. In colloidal silica particles, ion beam irradiation causes dramatic anisotropic deformation; silica expands perpendicular to the beam and contracts parallel, whereas Au cores elongate. Au colloids in a planar SiO2 matrix were anisotropically transformed from spherical colloids to elongated nanorods by irradiating them with 4 MeV Cu ions. The degree of anisotropy varied with ion flux. Upon irradiating the embedded Au colloids, dark-field light scattering experiments revealed a distinct color shift to yellow, which indicates a shift in surface plasmon resonance. A surface plasmon resonance measurement reveals the plasmon resonance bands are split along the arrays of Au colloids. Our measurements have revealed resonance shifts that extend into the near-infrared spectrum by as much as 50 nm.

Ämnesord

NATURVETENSKAP  -- Fysik -- Fusion, plasma och rymdfysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences -- Fusion, Plasma and Space Physics (hsv//eng)

Nyckelord

silica dispersion; stober method; silica- au core-shell; au colloids; anisotropic deformation; localized surface plasmons

Publikations- och innehållstyp

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