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Synthesis, characterization and optical power limiting behaviour of phenylazo- and 4-nitrophenylazo-tetrahydroxytetrathiacalix[4]arene

Desroches, C (författare)
Univ Lyon 1, CNRS, UMR 5615, Lab Multimat & Interfaces, F-69622 Villeurbanne, France Swedish Def Res Agcy FOI, Div Sensor Technol, SE-58111 Linkoping, Sweden Univ Lyon 1, CNRS, UMR 5078, Lab Synth & Reconnaissance & Org Mol & Biomol, F-69622 Villeurbanne, France
Parola, S (författare)
Univ Lyon 1, CNRS, UMR 5615, Lab Multimat & Interfaces, F-69622 Villeurbanne, France Swedish Def Res Agcy FOI, Div Sensor Technol, SE-58111 Linkoping, Sweden Univ Lyon 1, CNRS, UMR 5078, Lab Synth & Reconnaissance & Org Mol & Biomol, F-69622 Villeurbanne, France
Vocanson, F (författare)
Univ Lyon 1, CNRS, UMR 5615, Lab Multimat & Interfaces, F-69622 Villeurbanne, France Swedish Def Res Agcy FOI, Div Sensor Technol, SE-58111 Linkoping, Sweden Univ Lyon 1, CNRS, UMR 5078, Lab Synth & Reconnaissance & Org Mol & Biomol, F-69622 Villeurbanne, France
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Ehlinger, N (författare)
Univ Lyon 1, CNRS, UMR 5615, Lab Multimat & Interfaces, F-69622 Villeurbanne, France Swedish Def Res Agcy FOI, Div Sensor Technol, SE-58111 Linkoping, Sweden Univ Lyon 1, CNRS, UMR 5078, Lab Synth & Reconnaissance & Org Mol & Biomol, F-69622 Villeurbanne, France
Miele, P (författare)
Univ Lyon 1, CNRS, UMR 5615, Lab Multimat & Interfaces, F-69622 Villeurbanne, France Swedish Def Res Agcy FOI, Div Sensor Technol, SE-58111 Linkoping, Sweden Univ Lyon 1, CNRS, UMR 5078, Lab Synth & Reconnaissance & Org Mol & Biomol, F-69622 Villeurbanne, France
Lamartine, R (författare)
Univ Lyon 1, CNRS, UMR 5615, Lab Multimat & Interfaces, F-69622 Villeurbanne, France Swedish Def Res Agcy FOI, Div Sensor Technol, SE-58111 Linkoping, Sweden Univ Lyon 1, CNRS, UMR 5078, Lab Synth & Reconnaissance & Org Mol & Biomol, F-69622 Villeurbanne, France
Bouix, J (författare)
Univ Lyon 1, CNRS, UMR 5615, Lab Multimat & Interfaces, F-69622 Villeurbanne, France Swedish Def Res Agcy FOI, Div Sensor Technol, SE-58111 Linkoping, Sweden Univ Lyon 1, CNRS, UMR 5078, Lab Synth & Reconnaissance & Org Mol & Biomol, F-69622 Villeurbanne, France
Eriksson, A (författare)
Lindgren, M (författare)
Lopes, C (författare)
Univ Lyon 1, CNRS, UMR 5615, Lab Multimat & Interfaces, F-69622 Villeurbanne, France Swedish Def Res Agcy FOI, Div Sensor Technol, SE-58111 Linkoping, Sweden Univ Lyon 1, CNRS, UMR 5078, Lab Synth & Reconnaissance & Org Mol & Biomol, F-69622 Villeurbanne, France
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 (creator_code:org_t)
2001
2001
Engelska.
Ingår i: Journal of Materials Chemistry. - 0959-9428 .- 1364-5501. ; 11:12, s. 3014-3017
Relaterad länk:
https://urn.kb.se/re...
  • Tidskriftsartikel (refereegranskat)
Abstract Ämnesord
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  • p-Tetrakis(4-nitrophenylazo) tetrahydroxytetrathiacalix[4] arene and p-tetrakis(phenylazo) tetrahydroxytetrathiacalix[4] arene were prepared and fully characterized using H-1 and C-13 NMR, mass spectroscopy, thermogravimetric analysis and differential scanning calorimetry. The solid-state structure of p-tetrakis(4-nitrophenylazo) tetrahydroxytetrathiacalix[4] arene was investigated by single crystal X-ray diffraction. It crystallized in the triclinic system (space group: P (1) over bar). z-Scan experiments were performed on the p-tetrakis(4-nitrophenylazo) tetrahydroxytetrathiacalix[ 4] arene showing non linear absorption due to two photon absorption with a TPA cross-section of about 50 x 10(-50) cm(4) s per photon. Optical power limiting measurements on the p-tetrakis( phenylazo) tetrahydroxytetrathiacalix[ 4] arene at 532 nm (48% linear transmission) was found to limit the energy to similar to9 muJ.

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