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Tetraphenyl- and te...
Tetraphenyl- and tetratolylantimony complexes with N,N-dialkyldithiocarbamate ligands : synthesis, X-ray diffraction analysis, and 13C and 15N CP/MAS NMR studies
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- Sharutin, V. V. (författare)
- Blagoveshchensk State Pedagogical University
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- Ivanov, M. A. (författare)
- Russian Adademy of Sciences
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- Gerasimenko, A. V. (författare)
- Russian Adademy of Sciences
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- Ivanov, Alexander V. (författare)
- Luleå tekniska universitet,Industriell miljö- och processteknik
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- Pakusina, A. P. (författare)
- Blagoveshchensk State Pedagogical University
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- Antzutkin, Oleg (författare)
- Luleå tekniska universitet,Industriell miljö- och processteknik
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Forsling, Willis (författare)
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- Gröbner, Gerhard (författare)
- Umeå universitet,Umeå university
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(creator_code:org_t)
- 2006
- 2006
- Engelska.
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Ingår i: Russian journal of coordination chemistry. - 1070-3284 .- 1608-3318. ; 32:3:6, s. 87-396
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Ämnesord
Stäng
- Crystalline tetraphenylantimony and tetratolylantimony complexes with N,N-dialkyldithiocarbamate ligands [Sb(C6H5)4(S2CNR2)] (R = CH3, C2H5, and C3H7 and R2 = (CH2)6) were synthesized by ligand exchange reactions and studied by 13C and 15N CP/MAS NMR spectroscopy. X-ray diffraction analysis revealed that the complex [Sb(n-CH3-C6H4)4{S2CN(C3H7)2}] exists as the single molecular form, while [Sb(C6H5)4{S2CN(CH2)6}] exists as two molecular conformers. The 13C and 15N signals were assigned to the positions of the atoms in the isomeric structures [Sb(C6H5)4{S2CN(CH2)6}] in terms of different degrees of double bonding in the formally single =N-C(S)S-bond.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Nyckelord
- Chemistry of Interfaces
- Gränsytors kemi
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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