Binuclear cadmium dithiophosphate crystals: 13C, 31P, and 113Cd CP/MAS NMR studies

• 31P NMR signals for the terminal and bridging ligands of the complexes were differentiated. The experimental NMR spectra show 31P-111,113Cd and 113Cd-31 P spin-spin couplings only for the terminal ligands. The chemical shift anisotropy δ and the asymmetry parameter η were calculated for 31P and 113Cd NMR signals. It was found that the 31P chemical shifts for the terminal and bridging dithiophosphato groups differ in anisotropy character.

Ämnesord

NATURVETENSKAP  -- Kemi -- Fysikalisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Physical Chemistry (hsv//eng)

Nyckelord

Chemistry of Interfaces

Gränsytors kemi

Publikations- och innehållstyp

ref (ämneskategori)

art (ämneskategori)