Development of Bi-Langmuir model on the sorption of cadmium onto waste foundry sand : Effects of initial pH and temperature

• The present study develops the sorption model for simulating the effects of pH and temperature on the uptake of cadmium from contaminated water using waste foundry sand (WFS) by allowing the variation of the maximum adsorption capacity and affinity constant. The presence of two acidic functional groups with the same or different affinity is the basis in the derivation of the two models; Model 1 and Model 2 respectively. The developed Bi-Langmuir model with different affinity (Model 2) has a remarkable ability in the description of process under consideration with coefficient of determination > 0.9838 and sum of squared error < 0.08514. This result is proved by FTIR test where the weak acids responsible of cadmium ions removal using WFS sorbent can be represented by surface silanol (O-H) functional groups.

Ämnesord

TEKNIK OCH TEKNOLOGIER  -- Samhällsbyggnadsteknik -- Geoteknik (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Civil Engineering -- Geotechnical Engineering (hsv//eng)

Nyckelord

Cadmium

Foundry sand

Modified langmuir model

Simulation

Sorption

Soil Mechanics

Geoteknik

Publikations- och innehållstyp

ref (ämneskategori)

art (ämneskategori)